Suspension concentrate or suspoemulsion formulations comprising sulfur and selected terpenes

Abstract

The present invention relates to suspension concentrate or suspoemulsion formulations comprising sulfur, selected terpenes, polyalkoxylated arylalkylphenols, sulphosuccinates, and alkyl naphthalene sulfonates and methods for protecting plants using such formulations.

Description

2504171Suspension concentrate or suspoemulsion formulations comprising sulfur and selected terpenes.Field of the InventionThe present invention relates to suspension concentrates or suspoemulsion formulations comprising sulfur and selected terpenes and methods for protecting plants using such formulations.Background of the InventionCrop plants are under constant threat by plant pathogens and plant pests. Thus, there is a constant need to develop a broad toolkit of alternative pesticides to protect crop plants and to improve on the shortcomings of existing pesticides. One interest is to develop pesticides based on natural compounds, which show the same performance and ease of application as comparable pesticides based on synthetic compounds.One of the oldest natural occurring fungicides, which is still widely used, is elemental sulfur. It is considered to have a very low impact on the environment and is one of the few compounds allowed as pesticide in organic agriculture. Sulfur is mainly used to protect fruits, vegetables and grapevines against phytopathogenic fungi, mites and insects, like aphids. Sulfur fungicides are generally formulated as wettable powders or water dispersible granules. Sulfur wettable powder formulations are dusty and pose a risk to the user, mostly because of eye irritation, inhalation risk and skin irritation. Granular formulations are less dusty, but more expensive in production. An improved formulation type are suspension concentrates. However, water-based suspension concentrates of sulfur frequently show sedimentation during storage which is difficult to re-sus-pend and tends to form a supernatant serum. Sulfur particles formed during storage may block spray nozzles. Another problem of water-based suspension concentrates is low pourability and high viscosity, which reduces the ease of application for the user of these formulations. Variants of water-based suspension concentrates comprising different kinds of fatty acid or terpene-based plant oils have been described in W003 / 086073, which describes a composition to control grapevine powdery mildew (Uncinula necator), comprising sulfur and a 40% soybean oil in water emulsion.Sulfur has limited applications in crops like wheat, barley, rye, triticale, oat, sugar and fodder beets. While sulfur protects these crops well against powdery mildews, like Blumeria graminis (also known as Erysiphe graminis), it requires high application rates of 6 to 8 kg of sulfur per hectare (ha) per treatment. Even at these high rates, sulfur shows insufficient effects against other phytopathogenic fungi of these crops. Accordingly, there is a need in the art to improve the protective effects of sulfur-based fungicides against other phytopathogenic fungi of these crops and / or to identify ways to apply sulfur in these crops which allow for a lower application rate per hectare and year.Another type of compounds which have been used as natural fungicides are terpenes. Terpenes are a diverse group of natural compounds and are parts of many plant essential oils. Their basic structure can be visualized as the result of linking isoprene (C5H8) units "head to tail" to form chains and rings. They are further classified depending on the amount of isoprene units used fortheir basic structure. Examples for these subgroups are monoterpenes, sesquiterpenes and diterpenes. Monoterpenes comprise two isoprene units and CI0HI6in their basic structure, sesquiterpenes comprise three and diterpenes four isoprene units.2504172W02022 / 101613 describes a bio-fungicide composition comprising microencapsulated essential oils or isolated terpenes.Despite the fact, that sulfur and terpenes have been used as pesticides since a long time, it is less known about their combined effects and the conditions to achieve positive effects or to overcome technical hurdles arising from their combination. WO2019 / 207112 describes a fungicidal mixture of limonene, cinnamaldehyde and one or more terpinenes, which can be used to replace other fungicides and thereby reduce the amount of other fungicides, like sulfur and copper, in spray regimes to protect plants. It describes that using the particular terpene mixture in spray regimes has the potential to reduce the total amount of sulfur in a spray regime from 100 to 120 kg to 10 to 12 kg per season.WO2016 / 004326 discloses a seed, soil, or plant treatment composition, comprising one or more essential oils and one or more emulsifiers, wherein the one or more essential oils are present as an emulsion and the average particle size of the one or more essential oils in the emulsion is less than about 25 microns. WO2016 / 004326 also describes that this plant treatment composition can be combined with several pesticides, including fungicides, such as sulfur.While these documents describe effects of sulfur and terpenes for protecting plants against fungal attack, they do not describe, how these compounds can be used together, without reducing the effectiveness of sulfur against fungal or insect pests and or to avoid enhanced phytotoxicity effects based on the combination of these compounds. These documents do also not describe for which fungal plant pathogens the combination of sulfur and terpenes selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol provides synergistic antifungal effects.WO2024 / 175584 claims an agrochemical composition comprising an inorganic compound (e.g. sulfur) and orange oil in a weight ratio of 30:1 to 60:1 and describes that it is uses precipitated silica on which the orange oil is absorbed. These type of formulations are generally described as pickering emulsions in which particles are used to stabilize the emulsion and to replace surfactants.Combinations of sulfur and terpenes have been produced. FR2599592 describes an antifungal composition (Heliosulfre®), comprising suspended micronized sulfur in in an emulsion of pine oil and water and one or more surfactants. One liter of this suspension concentrate comprises typically 60 to 170 g of pine oil; 25 to 70 g of surfactants; 400 to 1000 g of micronized or finely ground sulfur. A combination of nanoparticulated sulfur with essential orange oil has been described as Oro Solve®. Cesar et al. 2019, “"Nanoparticulated Sulfur and Essential Orange Oil (Oro Solve®) Increases Efficiency of Euschistus heros Control", Egypt. Acad. J. Biolog. Sci., 12(6): 111-120, describes that Oro Solve® is composed of orange essential oil + 45% nanoparticulate elemental sulfur, giving a concentration of 585 g per liter.However, Oro Solve® has not been commercially successful and discontinued, which points to a general problem in the art, which is the difficulty to create stable formulations comprising particulate sulfur and mineral or plant oils, e.g., see paragraph

[0007] of EP2904903, lines 33 to 55 in the right column of US6835719 and paragraphs

[0006] to

[0017] of US2014 / 0044765, these problems include stability of the formulation itself, reduced effectiveness of sulfur against fungal or insect pests, enhanced phytotoxicity and degradation of organic oils. For these reasons many labels of sulfur products advise not to use them as a tank mix with oil comprising products and to avoid applying sulfur and oil independently during a time frame of 30 days on plants. In addition to the well-known problems of liquid sulfur comprising formulations are low storage stability,2504173due to sedimentation, crystal growth and phase separation, further problems can be expected for combinations of sulfur with terpenes, as they are prone to oxidation, while sulfur promotes oxidation of other compounds.It has also be considered, that high concentrations of sulfur usually lead to high viscosity and poor pourability of the formulations, which, especially when combined with sedimentation of sulfur, can cause severe problems during preparation and application of the spraying suspension and can cause uneven application of the active compounds on the crop and blocking of valves and spray nozzles of the crop protection sprayer One additional problem is that terpenes usually have a high vapor pressure, so that a combined action of terpenes and sulfur on the respective plant pathogen or pest may be too short lived to provide any additional positive effect for plant protection.Description of the inventionDescribed herein are suspension concentrate or suspoemulsion formulations comprising sulfur and selected terpenes, in combination with polyalkoxylated arylalkylphenols, sulphosuccinates, alkyl naphthalene sulfonates and optionally propoxylated and / or ethoxylated Guerbet alcohol alkoxylates, carrier oils and further components.Agrochemical suspoemulsions are also known as "SE" type agro formulations. The suspoemulsion usually comprises a continuous aqueous phase, a dispersed oil phase, and a suspended solid phase. The oil phase usually forms droplets within the aqueous phase. The oil phase usually comprises the water-immiscible active ingredient. The oil phase usually comprises at least one pesticide, which may be dissolved in a water-immiscible solvent. The solid phase usually consists of solid particles within the aqueous phase. The solid phase may comprise at least one pesticidal substance, which is suspended in a continuous aqueous phase. A further pesticidal substance is dissolved in the water-immiscible solvent. Preferably, the further pesticidal substance is present at least in the dispersed oil phase of the suspoemulsion. The first pesticidal substance is suspended in the continuous aqueous phase. Preferably, the first pesticidal substance is present at least in the solid phase of the suspoemulsion.Agrochemical suspension concentrates (also known as "SC" type formulations) typically relates to compositions, which comprise solid particles, which are homogenously dispersed in a continuous aqueous phase. Agrochemical suspension concentrate is usually preformed in the commercial product and is conventionally diluted with a carrier, such as water, when making up the spray mixture (also called the tank mix). The continuous aqueous phase of the suspension concentrate is usually free of other dispersed phases beside the pesticide particles.The suspoemulsion and suspension concentrate formulations, preferably suspoemulsion formulations, comprise a) sulfur b) at least one terpene, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, in a weight / weight ratio of sulfur to the combined amount of limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, between 25 to 1 and 1 to 1 or between 20 to 1 and 12 to 1 , c) one or more carrier oils and d) optionally further components.Preferred suspoemulsion and suspension concentrate formulations, preferably suspoemulsion formulations, comprise a) sulfur b) limonene in a weight / weight ratio of sulfur to the amount of2504174limonene between 25 to 1 and 1 to 1 or between 20 to 1 and 12 to 1 , c) one or more carrier oils and d) optionally further components.Preferably the suspoemulsion and suspension concentrate formulations, preferably suspoemul-sion formulations, do not comprise silica, like precipitated silica, to absorb the terpenes onto silica in a ratio ranging from 10:1 to 1:1.Preferably the oil phase has an average oil droplet size of less than 25 microns, less than 15 microns, less than 10 microns or less than 5 microns.The suspoemulsion or suspension concentrate formulations usually have a pH from 4.5 to 8.5, preferably form 6.5. to 7.5.The suspoemulsion or suspension concentrate formulations described herein are selected based on their good storage stability. Preferably, they show no or a low amount of sulfur particle growth.Preferably after two weeks of storage at 40°C, the change of the value for the percentage of sulfur particles larger than 2 micrometer, the D50, the D90 and / or the D[4;3] value should not be larger than plus or minus 15%, preferably plus or minus 10%, more preferred plus or minus 5%. Preferably after two weeks of storage at 50°C, the change of the value for the percentage of sulfur particles larger than 2 micrometer, the D50, the D90 and / or the D[4;3] value should not be larger than plus or minus 15%, preferably plus or minus 10%, more preferred plus or minus 5%. Preferably after two weeks of storage at 12 hour cycling temperatures between minus 10°C and plus 10°C, the change of the value for the percentage of sulfur particles larger than 2 micrometer, the D50, the D90 and / or the D[4;3] value should not be larger than plus or minus 25%, preferably plus or minus 20%, more preferred plus or minus 15%, even more preferred plus or minus 10%.Sulfur:The sulfur comprised in the compositions can be elemental sulfur. Elemental sulfur can occur in several different allotropic forms, such as plastic (amorphous) sulfur, monoclinic sulfur, rhombic sulfur composed of ring molecules. The most common form is a ring structure of 8 atoms (S8) usually accompanied by smaller rings of 7 (S7) or 6 (S6) atoms. Elemental sulfur can be mined from fossil-based sulfur deposits of salt domes or from volcanic emissions but is most frequently produced as byproduct of desulfurization of natural gas and petroleum. The most important process for desulfurization is the Claus process, which includes an oxidation step of hydrogen sulfide (H2S) to sulfur dioxide (SO2) and a catalyzed reaction of H2S with SO2to form elemental sulfur (S°) (Schreiner, B. 302008. Chemie in unsererZeit 42: 378). Another form of elemental sulfur is flowers of sulfur, which is a very fine, bright yellow sulfur powder that is produced by sublimation and deposition of sulfur.A further source of elemental sulfur is the oxidation of hydrogen sulphide, e.g. from gas streams, by microorganisms, which produce small particles of elemental sulfur. This type of sulfur is called “biosulfur” and is distinguished from chemically produced sulfur by having a lower density compared to orthorhombic sulfur. Biosulfur particles have also hydrophilic properties whereas orthorhombic sulfur is known to be hydrophobic.The sulfur used in the invention can either be chemically produced sulfur, preferably orthorhombic sulfur, or can be biosulfur.2504175The particle diameter of sulfur is important for the efficacy of the product as a pesticide on crops. The particulate sulfur has preferably a D5o particle size diameter of less than 100 micrometers, preferably less than 50 micrometer, more preferred less than 10 micrometer and even more preferred less than 8 micrometer, most preferred less than 3 micrometer. The Dio particle size diameter and the D90particle size diameter is usually 1 micrometer for DiOand 80 micrometer for D9O, preferably 1 micrometer for Dio and 50 micrometer for D90, more preferred 1 micrometer for Dio and 30 micrometer for D90, even more preferred 1 micrometer for Dio and 20 micrometer for D90, and most preferred 1 micrometer for Dio and 10 micrometer for D90. Particles with a diameter between 1 and 8 microns are optimal, particles with a larger diameter are much less toxic for fungi and particles smaller than 1 micron can easily cause phytotoxic effects like chlorosis and necrosis (Emmett et al., 2003. "Sulphur formulations, particle size and activity - a review" in "Strategic Use of Sulphur in Integrated Pest and Disease Management (IPM) Programs for Grapevines". Accordingly, in a very preferred embodiment, the sulfur has a diameter particle size with an Dio value of 1 micrometer and a D90value of 8 micrometer and even more preferred with an D59value of less than 3 micrometer.The D[4;3] value of the particles is preferably between 1 and 8 micrometer, more preferred between 1 and 4 micrometer.The average diameter particle size of biosulfur particles is usually smaller. Biosulfur particles of less than 1 micrometer average diameter are also less phytotoxic than orthorhombic sulfur particles of a similar size. Preferably, the D59of diameter particle sizes for biosulfur is less than 10 micrometer, more preferred less than 9 micrometer, more preferred less than 8 micrometer, more preferred less than 7 micrometer, more preferred less than 6 micrometer, less than 5 micrometer, less than 4 micrometer, less than 3 micrometer, more preferred less than 2.5 micrometer, more preferred less than 2 micrometer, more preferred less than 1 micrometer, most preferred less than 0.8 micrometer. Preferably the biosulfur has a Dio of 0.1 micrometer and D90of 8 micrometer average diameter particle size.The Dio, D5O, D90and D[4;3] value are commonly used in the art to describe the size distribution of particles. Methods for determining these values are known in the art and include, for example, the actual size and morphology of the particles using a camera system, and the use of laser diffraction and dynamic light scattering. A preferred method employs laser diffraction, for example by the use of an ANALYSETTE 22 MicroTec plus particle size analyser. Methods available in the art, such as milling, can be used to adapt the average particle size of the sulfur particles to the distribution of particle sizes intended.The suspoemulsion or suspension concentrate formulations comprise, in a rising degree of preference, between 400 and 800 gram / liter, between 550 and 700 gram / liter, or between 600 and 700 gram / liter of elemental sulfur particles.Selected Terpenes:The suspoemulsion or suspension concentrate formulations of the invention comprise at least one terpene, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol. A reference to the name of terpene also includes a reference to the naturally occurring enantiomers of the respective terpene, e.g. a reference to limonene will comprise a reference to D-Limonene, which is the (R)-enantiomer, and L-limonene, which is the (S)-enantio-mer.2504176The selected terpenes can be chemically synthesized or isolated from essential plant oils. Methods to synthesize the selected terpenes are well known in the art. However, the selected terpenes can also be isolated e.g. via centrifugal separation or steam distillation from plant essential oils.The skilled person knows which essential plant oil comprises one or more of limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol. Examples for suitable essential plant oils are: orange oil, tangerine oil, grapefruit oil, lemon oil, mandarin oil, which comprise high amounts of D-limonene. Thyme oil, which usually comprises thymol with 23% to 60%, y-terpinene with 18% to 50%, p-cymene with 8% to 44% and carvacrol with 2% to 8%. Oregano oil comprises high amounts of thymol and carvacrol. Pinene can be isolated from pine oil. P-cy-mene can be found in the oils of cumin and thyme. Eugenol can be isolated from cinnamon oil. Geraniol is a component of citronella oil, rose oil and palmarosa oil.The content of a given terpene in a certain essential oil can vary and will depend on the source of the plant material, such as genotype of the plant, environmental conditions during growth of the plant, harvesting conditions of the plant material, method of extraction and other factors. In one embodiment of the invention the limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol or carvacrol, has been isolated from an essential plant oil or is provided as part of an essential plant oil. In case it is provided as part of an essential plant oil, the amount of the limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol or carvacrol or if more than one of limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol or carvacrol is present, the combined sum of limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol in the final mixture and not the amount of the respective essential oil will be decisive for the amount of the selected terpenes in the methods to control phytopathogenic fungi.The mixtures used in the described methods may comprise only one of limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol or carvacrol, for example only limonene, preferably D-limonene, but may also comprise more than one of the selected terpenes.Preferred mixtures of the selected terpenes are:a) mixtures of limonene, preferably D-limonene, with at least one of a-terpinene, p-cymene, carvacrol, eugenol, geraniol and thymol-b) mixtures of limonene, preferably D-limonene, with at least one of a-terpinene, p-cymene and carvacrol.c) mixtures of limonene, preferably D-limonene, with at least one of eugenol, geraniol and thymol.Preferably the weight / weight ratio between limonene, preferably D-limonene, and one terpene selected from terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol is between 75 to 1 and 1 to 1 , or between 50 to 1 and 1 to 1 , or between 25 to 1 and 1 to 1 , or between 10 to 1 and 1 to 1 , or between 8 to 1 to 1 to 1 , or between 5 to 1 and 1 to 1 , or between 2 to 1 and 1 to 1.Preferably the weight / weight ratio between limonene, preferably D-limonene, and the combined amount of the one or more of terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol is between 75 to 1 and 1 to 1 , or between 50 to 1 and 1 to 1 , or between 25 to 1 and 1 to 1 , or between 10 to 1 and 1 to 1 , or between 8 to 1 to 1 to 1 , or between 5 to 1 and 1 to 1 , or between 2 to 1 and 1 to 1.Further preferred mixtures of the selected terpenes are:2504177a) mixtures of a-terpinene, p-cymene and limonene.b) mixtures of at least two of eugenol, geraniol and thymol.The terpenes, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol may be accompanied by other terpenes, in particular if at least one of limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol is provided as part of an essential plant oil.Preferably, the weight / weight ratio between the combined amounts of the terpenes, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, and the combined amounts of other terpenes is between 75 to 1 and 1 to 1, or between 50 to 1 and 1 to 1 , or between 25 to 1 and 1 to 1 , or between 10 to 1 and 1 to 1 , or between 8 to 1 to 1 to 1 , or between 5 to 1 and 1 to 1 , or between 2 to 1 and 1 to 1.In one embodiment, the weight / weight ratio between limonene, preferably D-limonene, and the combined amount of terpenes other than, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, is between 75 to 1 and 1 to 1 , or between 50 to 1 and 1 to 1 , or between 25 to 1 and 1 to 1 , or be-tween 10 to 1 and 1 to 1 , or between 8 to 1 to 1 to 1 , or between 5 to 1 and 1 to 1 , or between 2 to 1 and 1 to 1.In one embodiment, the weight / weight ratio between limonene, preferably D-limonene, and the combined amount of terpenes including terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, is between 75 to 1 and 1 to 1 , or between 50 to 1 and 1 to 1 , or between 25 to 1 and 1 to 1 , or between 10 to 1 and 1 to 1 , or between 8 to 1 to 1 to 1 , or between 5 to 1 and 1 to 1 , or between 2 to 1 and 1 to 1 and preferably more than 90 to 1 or higher, 100 to 1 or higher, 300 to 1 or higher, 500 to 1 or higher or 1000 to 1 or higher.The combined amount of all terpenes, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, is preferably between 10 and 70 gram / liter, or between 20 and 70 gram / liter.In one embodiment the amount of limonene, preferably D-limonene, is between 10 and 70 gram / liter, or between 20 and 70 gram / liter, preferred amounts of limonene are between 20 and 60 grams / liter.In a preferred embodiment, the limonene is provided in the form of orange oil or other citrus oils comprising a high amount of limonene.Peferably the weight / weight ratio ofa) the amount of sulfur to the combined amounts of the terpenes, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, is between 30 to 1 and 10 to 1 , or between 25 to 1 and 10 to 1 , or between 25 to 1 and 12 to 1 , or between 24 to 1 and 8 to 1 , or between 24 to 1 and 10 to 1 , or between 24 to 1 and 12 to 1 , orb) the amount of sulfur to the amount of limonene, preferably D-limonene, is between 30 to 1 and 10 to 1 , or between 25 to 1 and 10 to 1 , or between 25 to 1 and 12 to 1 , or between 24 to 1 and 8 to 1 , or between 24 to 1 and 10 to 1 , or between 24 to 1 and 12 to 1.Polyalkoxylated arylalkylphenols:The suspoemulsion or suspension concentrate formulations comprise at least one polyalkoxylated, arylalkylphenol. The HLB of the polyalkoxylated, arylalkylphenol is preferably 12 to 15,2504178more preferred 12 to 13. HLB means Hydrophilic-Lipophilic Balance which is well known in the field of surfactant.The polyalkoxylated arylalkylphenol is preferably polyethoxylated, having an average degree of ethoxylation between 10 and 80, more preferred between 16 to 40. Even more preferred are tristyrylphenolethoxylates with an EO of 15 or 16, such as 2,4,6-tris(l-phenylethyl)phenol (tristyrylphenol).Preferred commercially available polyalkoxylated arylalkylphenols are Soprophor BSU' (2,4,6-tris(l-phenylethyl)phenol), ‘Soprophor S25’, Soprophor TS / 10 and Soprophor 769 / P.Preferred are also sulphates and phosphates of polyalkoxylated arylalkylphenol. These sulphates and phosphates may be in their acid forms, or as salts, such as the ammonium salt or amine salt such as the triethanolamine salt.The suspoemulsion or suspension concentrate formulations comprise between 5 to 30 grams / li-ter of one or more polyalkoxylated arylalkylphenols. In cases where more than one polyalkoxylated arylalkylphenol is used the amount of each of these is combined, so that the total amount of the polyalkoxylated arylalkylphenols is between 5 to 30 gram / liter. Preferably, the total amount is between 8 to 28 grams / liter, more preferred between 16 and 25 grams / liter even more preferred between 23 and 25 grams / liter.Sulphosuccinates:The suspoemulsion or suspension concentrate formulations comprise one or more sulphosuccinates.Suitable sulphosuccinates are: disodium monooctylsulfosuccinate, disodium lauryl sulfosuccinate, disodium isodecyl sulfosuccinate, disodium tridecyl sulfosuccinate, diammonium lauryl sulfosuccinate, disodium laureth sulfosuccinate, disodium decyl-PEG-4 sulfosuccinate, disodium laureth-5 sulfosuccinate, disodium laurimide (MEA) sulfosuccinate, disodium cocamide MIPA sulfosuccinate, disodium oleamido MIPA sulfosuccinate, disodium oleylamido PEG-2 sulfosuccinate, disodium cocamido MEA sulfosuccinate, diammonium lauramido MEA sulfosuccinate, sodium dioctyl sulfosuccinate, sodium bistridecyl sulfosuccinate, sodium dihexyl sulfosuccinate, sodium dicyclohexyl sulfosuccinate, sodium diamyl sulfosuccinate or sodium diisobutyl sulfosuccinate.Preferably at least one sulphosuccinate is bis(2-ethylhexyl) sulfosuccinate, preferably a salt of bis(2-ethylhexyl) sulfosuccinate, more preferred it is sodium bis(2-ethylhexyl) sulfosuccinate, Preferred commercially available sulphosuccinate are Lutensit A-BO (sodium bis(2-ethylhexyl) sulfosuccinate), Empimin OT 50 and Empimin EM 5685.The suspoemulsion or suspension concentrate formulations comprise between 20 to 40 grams / liter of one or more sulphosuccinates. In cases where more than one sulphosuccinate is used, the amount of each of these is combined, so that the total amount of the sulphosuccinates is between 20 to 40 grams / liter. Preferred between 21 to 37 grams / liter, even more preferred 21 to 33 grams / liter.Alkyl naphthalene sulfonates:The suspoemulsion or suspension concentrate formulations comprise one or more alkyl naphthalene sulfonate. Suitable alkyl naphthalene sulfonates are: 1 -Naphthalenesulfonic acid Dibutylnaphthalinsulfonate, Diisopropylnaphthalinsulfonate. A preferred alkyl naphthalene sulfonate is 1 -Naphthalenesulfonic acid, more preferred the sodium salt of 1 -Naphthalenesulfonic acid.2504179Preferred commercially available naphthalene sulfonates are Morwet D-425 (1 -Naphthalenesulfonic acid) Tersperse 2020 Supragil MNS 88 E, Surfom WG 8168, Oparyl DT 505The suspoemulsion or suspension concentrate formulations comprise between 10 to 60 grams / liter of one or more alkyl naphthalene sulfonate. In cases where more than one alkyl naphthalene sulfonate is used, the amount of each of these is combined, so that the total amount of the alkyl naphthalene sulfonates is between 10 to 60 grams / liter. Preferred between 21 to 55 grams / liter. In some embodiments it is between 50 to 60 grams / liter. In some embodiments it is between 10 to 50 grams / liter.In cases where the total amount of alkyl naphthalene sulfonates is below 50 grams per liter, the suspoemulsion or suspension concentrate formulations comprise at least one carrier oil, wherein the combined amounts of all carrier oils is between 10 to 100 gram / liter, preferably between 10 to 60 grams / liter, more preferred between 20 to 60 grams / liter.Propoxylated and / or ethoxylated Guerbet alcohol alkoxylates:The suspoemulsion or suspension concentrate formulations can optionally comprise one or more propoxylated and / or ethoxylated Guerbet alcohols. Preferred are Guerbet C10-(PO)a(EO)b, wherein is a is 1 to 4 and b is 6 to 10, like the commercially available Lutensol® XL series comprising for example Lutensol® XL-40, Lutensol® XL-50, Lutensol'.© XL-60, Lutensol® XL-70, Lutensol® XL-79, Lutensol® XL-80, Lutensol® XL-89, Lutensol® XL-90, Lutensol® XL-99, Lutensol® XL-100, and Lutensol® XL- 140;Also preferred are Guerbet C10-(EO)a, wherein a is 6 to 10, like the commercially available Lutensol® XP series comprising for example Lutensol® XP-40, Lutensol® XP-50, Lutensol® XP-60, Lutensol® XP-70, Lutensol® XP-79, Lutensol® XP-80, Lutensol® XP-89, Lutensol® XP-90, Lutensol® XP-99, Lutensol:© XP-100.More preferred is Lutensol® XP-80.In cases where the suspoemulsion or suspension concentrate formulations comprise one or more one or more propoxylated and / or ethoxylated Guerbet alcohols, the suspoemulsion or suspension concentrate formulations comprise between 10 to 60 grams / liter total amount of all propoxylated and / or ethoxylated Guerbet alcohols present. Preferably, the total amount is between 14 to 50 grams / liter. More preferred between 25 to 50 grams / liter.Carrier oils:Suitable carrier oils should have a low solubility in water. Preferably the solubility at 20°C is less than 1 gram / liter, preferably less than 0.1 gram / liter. They may comprise only one type of carrier oil or a mixture of at least two carrier oils. The carrier oils are preferably selected from one or more of the following groups.One preferred group of carrier oils are terpenes, which are liquid at 20°C and are not limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol or carvacrol.Another preferred group of carrier oils comprises plant oils and alkyl esters of such plant oils. Preferably the ester is selected from methyl, ethyl, propyl, isopropyl and butyl esters. The plant oil is preferably selected from soybean oil, rape oil, sunflower oil, peanut oil, linseed oil, cottonseed oil, corn oil, castor oil, neem oil, olive oil. Preferred mixtures of alkyl esters are C6 to C10 fatty acid methylester, C8 to C10 fatty acid methyl ester and C16 to C18 fatty acid methyl ester. Preferred alkyl ester of single fatty acids are methyl oleate, methyl octanaoate, methyl decanoate, metyl linolenate, ethyl hexanoate, ethyl octanoate, ethyl decanoate, isopropyl myristate,25041710isopropyl palmitate, isopropyl stearate, myristyl myristate and butyl stearate. In one embodiment the carrier oil is or comprises ethoxylated castor oil. In one embodiment the carrier oil is or comprises methyl oleate. In one embodiment the carrier oil is or comprises isopropyl myristate. In one embodiment the carrier oil is or comprises soybean oil, rape oil, sunflower oil, peanut oil, linseed oil, cottonseed oil, corn oil or castor oil. In one embodiment the carrier oil is or comprises rape oil and / or sunflower oil.A further group of carrier oil comprises C11 to C14 alkyl acetate, and decyl acetate, isobornyl acetate and 2-ethylhexyl acetate.A further group comprises C12 - C20 fatty alcohols, octanol, decyl alcohol, tridecanol, 2-ethylhexanol, oleyl alcohol, cetyl alcohol and lauryl alcohol.A further group comprises dibutyl adipate, diisobutyl adipate, diisopropyl adipate, diethylhexyladipate, diisodecyl adipate, didisotridecyl adipate, diethylhexyl sebacate, dibutyl sebacate. A further group comprises ethyl cinnamate and propyl cinnamate.A further group comprises benzyl benzoate, benzyl acetate, benzyl butyl ester, isopropyl benzoate, butyl benzoate, pentyl benzoate, hexyl benzoate, heptyl benzoate, octyl benzoate, nonyl benzoate, decyl benzoate, propylene glycol dibenzoate, dipropylene glycol dibenzoate, A further group comprises tall oil fatty acids, oleic acid, palmitic acid, 2-ethylhexyl octanoate, coco caprylate, texanoldiiosbutyrate, 1 ,2-cyclohexanedicarbolixylic acid diisononylester, di-n-butylcarbonate, alkyl naphthalenes, dioctyl ether.Another group comprises aromatic solvent napthat (Solvesso grades), decane, petroleum, cyclohexane, methyl cyclohexane, kerosine, tris-(2-ethylhexyl)phosphate, tris-(2-butoxyethyl)phos-phate, 2-ethylhexyllactate, tributylcitrate, acetyltributylcitrate, tris-(ethylhexyl)trimellitate, dimethyl octanaminde, dimethyldecanamide, dimethyldodecanamide and mineral oil, preferably a dewaxed mineral oil (CAS No. 64742-56-9). In one embodiment the carrier oil is or comprises dewaxed mineral oil (CAS No. 64742-56-9).In one embodiment the carrier oil comprises a mixture of at least two of methyl oleate, isopropyl myristate, rape oil and sunflower oil, or a mixture of at least two of methyl oleate, rape oil and sunflower oil.In embodiments in which the suspoemulsion or suspension concentrate formulations comprise one or more carrier oils, they comprise a total amount of 10 to 100 grams / liter of all carrier oils present. Preferably the total amount is between 20 to 60 grams / liter.In one preferred embodiment, the ratio between the weight / weight ratio of the combined amount of all carrier oils to the combined amount of all terpenes, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, is between 2:1 to 1 to 2. In a further preferred embodiment, the ratio between the weight / weight ratio of the combined amount of all carrier oils to the combined amount of limonene, preferably D-limonene, is between 2:1 to 1 to 2.Further components:The suspoemulsion or suspension concentrate formulations may comprise further components, such as auxiliaries known to be suitable for agrochemical formulations.Examples for suitable auxiliaries are liquid carriers, solid carriers or fillers, surfactants, dispersants, emulsifiers, wetters, adjuvants, solubilizers, penetration enhancers, protective colloids, adhesion agents, antioxidants, thickeners, humectants, repellents, attractants, feeding25041711stimulants, compatibilizers, bactericides, anti-freezing agents, anti-foaming agents, colorants, tackifiers and binders.The liquid carrier is preferably waterSuitable solid carriers or fillers are mineral earths, e.g. silicates, silica gels, talc, kaolins, limestone, lime, chalk, clays, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate, magnesium oxide; polysaccharide powders, e.g. cellulose, starch; fertilizers, e.g. ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas; products of vegetable origin, e.g. cereal meal, tree bark meal, wood meal, nutshell meal, and mixtures thereof.Suitable surfactants are surface-active compounds, such as anionic, cationic, nonionic and amphoteric surfactants, block polymers, polyelectrolytes, and mixtures thereof. Such surfactants can be used as emusifier, dispersant, solubilizer, wetter, penetration enhancer, protective colloid, or adjuvant. Examples of surfactants are listed in McCutcheon’s, Vol.1: Emulsifiers & Detergents, McCutcheon’s Directories, Glen Rock, USA, 2008 (International Ed. or North American Ed.).Suitable anionic surfactants are alkali, alkaline earth or ammonium salts of sulfonates, sulfates, phosphates, carboxylates, and mixtures thereof. Examples of sulfonates are alkylarylsulfonates, diphenylsulfonates, alpha-olefin sulfonates, lignine sulfonates, sulfonates of fatty acids and oils, sulfonates of ethoxylated alkylphenols, sulfonates of alkoxylated arylphenols, sulfonates of condensed naphthalenes, sulfonates of dodecyl- and tridecylbenzenes, sulfonates of naphthalenes and alkylnaphthalenes, sulfosuccinates or sulfosuccinamates. Examples of sulfates are sulfates of fatty acids and oils, of ethoxylated alkylphenols, of alcohols, of ethoxylated alcohols, or of fatty acid esters. Examples of phosphates are phosphate esters. Examples of carboxylates are alkyl carboxylates,Suitable nonionic surfactants are alkoxylates, N-subsituted fatty acid amides, amine oxides, esters, sugar-based surfactants, polymeric surfactants, and mixtures thereof. Examples of alkoxylates are compounds such as alcohols, amines, amides, fatty acids or fatty acid esters which have been alkoxylated with 1 to 50 equivalents ethylene oxide and / or propylene oxide and / or butylene oxide may be employed for the alkoxylation, preferably ethylene oxide. Examples of N-subsititued fatty acid amides are fatty acid glucamides or fatty acid alkanolamides. Examples of esters are fatty acid esters, glycerol esters or monoglycerides. Examples of sugar-based surfactants are sorbitans, ethoxylated sorbitans, sucrose and glucose esters or alkyl- polyglucosides. Examples of polymeric surfactants are home- or copolymers of vinylpyrrolidone, vinylalcohols, or vinylacetate.Suitable cationic surfactants are quaternary surfactants, for example quaternary ammonium compounds with one or two hydrophobic groups, or salts of long-chain primary amines. Suitable amphoteric surfactants are alkylbetains and imidazolines. Suitable block polymers are block polymers of the A-B or A-B-A type comprising blocks of polyethylene oxide and polypropylene oxide, or of the A-B-C type comprising alkanol, polyethylene oxide and polypropylene oxide. Suitable polyelectrolytes are polyacids or polybases. Examples of polyacids are alkali salts of polyacrylic acid or polyacid comb polymers. Examples of polybases are polyvinylamines or polyethyleneamines.Suitable thickeners are polysaccharides (e.g. xanthan gum, carboxymethylcellulose), anorganic clays (organically modified or unmodified), polycarboxylates, and silicates.Suitable bactericides are bronopol and isothiazolinone derivatives such as alkylisothiazolinones and benzisothiazolinones.25041712Suitable anti-freezing agents are ethylene glycol, propylene glycol, urea and glycerin.Suitable anti-foaming agents are silicones, long chain alcohols, and salts of fatty acids.Suitable tackifiers or binders are polyvinylpyrrolidons, polyvinylacetates, polyvinyl alcohols, polyacrylates, biological or synthetic waxes, and cellulose ethers.Antoxidants are a preferred suspension concentrate or suspoemulsion formulations, if it is intended to enhance their antioxidant capacity above the level provided by the other components, e.g. provided by terpenes which are liquid at 20°C and / or the carrier oils. Such additional antioxidants are preferably selected from tocopherols, e.g. vanillin, a-tocopherol, ascorbic acid, ascorbate, carotenoids, e.g. beta-carotene, n-propyl gallate, butylated hydroxytoluene (BHT), bu-tylated hydroxyanisole (BHA), tert-Butylhydroquinone (TBHQ).More preferred are: n-propyl gallate, ascorbic acid, sodium sulfite, tocopherol-acetate and butylated hydroxyanisole (BHA).The antioxidant capacity can be measured by methods known in the art, for example methods discussed in Munteanu and Apetrei, Int. J. Mol. Sci.; Analytical Methods Used in Determining Antioxidant Activity: A Review; 2021, 22, 3380. https: / / doi.org / 10.3390 / ijms22073380.Preferably the suspoemulsion or suspension concentrate formulations comprise from 20 to 0,5, or from 15 to 1 , or from 10 to 1 , or from 8 to 1 , or from 5 to 1 , gram / liter of one or more antioxidants, which are not terpenes which are liquid at 20°C as pure substance or carrier oils. In one embodiment the antioxidant is vanillin.In one embodiment the suspension concentrate or suspoemulsion formulations comprise a) to f) a) 50 to 20 gram / liter of one or more antifreeze (e.g. 1 ,2-Propylene glycol) andb) 50 to 1 , or 50 to 20 gram / liter of one or more anionic surfactants (e.g. Wettol NT 1 CAS 211565-27-4 or Wettol EM 1 , CAS 26264-06-2 ) andc) 100 to 1 , or 10 to 1 gram / liter of one or more nonionic surfactants (e.g. Agnique SPO 40 and Wettol EM 31, CAS 61791-12-6) andd) 5 to 3 gram / liter of one or more biocides (e.g. Acticide MV and Acticide B 20) ande) 10 to 1 gram / liter of one or more antifoams (e.g. SRE-PFL).CAS Numbers are defined by the Chemical Abstracts Service (CAS).Exemplary, but not limiting examples of suspoemulsion or suspension concentrate formulations compriseIn one embodiment, the suspoemulsion or suspension concentrate formulations comprise: a) 400 to 800 grams / liter of sulfurb) 10 to 70 grams / liter of one or more terpenes, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol,c) 5 to 30 grams / liter of one or more polyalkoxylated arylalkylphenols (Soprophor BSU) d) 20 to 40 grams / liter of one or more sulphosuccinates (Lutensit A-BO)e) 10 to 60 grams / liter of one or more alkyl naphthalene sulfonates (Morwet D-425) f) optionally 10 to 60 grams / liter of one or more propoxylated and / or ethoxylated Guerbet alcohol alkoxylatesg) optionally 10 to 100 grams / liter of one or more carrier oils andg) optionally further components,25041713with the proviso, that if the suspension concentrate or suspoemulsion formulation comprises less than 50 grams / liter of one or more alkyl naphthalene sulfonates it comprises 10 to 100 grams / liter of one or more carrier oils.In one embodiment, the suspoemulsion or suspension concentrate formulations comprise: a) 500 to 700 grams / liter of sulfurb) 20 to 70 grams / liter of one or more terpenes, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol,c) 5 to 25 grams / liter of one or more polyalkoxylated arylalkylphenols,d) 20 to 40 grams / liter of one or more sulphosuccinates,e) 50 to 60 grams / liter of one or more alkyl naphthalene sulfonates,f) optionally 10 to 60 grams / liter of one or more propoxylated and / or ethoxylated Guerbet alcohol alkoxylatesg) optionally 20 to 80 grams / liter of one or more carrier oils andg) optionally further components,In one embodiment, the suspoemulsion or suspension concentrate formulations comprise: a) 500 to 700 grams / liter of sulfurb) 20 to 70 grams / liter of one or more terpenes, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol,c) 5 to 25 grams / liter of one or more polyalkoxylated arylalkylphenols,d) 20 to 40 grams / liter of one or more sulphosuccinates,e) 10 to 50 grams / liter of one or more alkyl naphthalene sulfonates,f) 10 to 60 grams / liter of one or more propoxylated and / or ethoxylated Guerbet alcohol alkoxylatesg) 20 to 80 grams / liter of one or more carrier oils andg) optionally further components,In one embodiment, the suspoemulsion or suspension concentrate formulations comprise: a) 500 to 700 grams / liter of sulfurb) 20 to 70 grams / liter of one or more terpenes, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol,c) 5 to 25 grams / liter of one or more polyalkoxylated arylalkylphenols,d) 20 to 40 grams / liter of one or more sulphosuccinates,e) 20 to 50 grams / liter of one or more alkyl naphthalene sulfonates,f) 10 to 60 grams / liter of one or more propoxylated and / or ethoxylated Guerbet alcohol alkoxylatesg) 20 to 80 grams / liter of one or more carrier oils andg) optionally further components,The suspension concentrate or suspoemulsion formulations of the invention usually have a good pourability, a low viscosity and a low phytotoxicity.The pourability of the suspension concentrate or suspoemulsion formulations, can be determined according to CIPAC Method MT 148 - Pourability of suspension concentrates.25041714COLLABORATIVE INTERNATIONAL PESTICIDES ANALYTICAL COUNCIL (CIPAC) is an international, non-profit-oriented organization for the promotion of uniform methods for the analysis of pesticides and physico-chemical test methods for pesticide formulations.The amount of product that remains in the packaging after emptying is preferably below 15%, more preferred below 10%, most preferred below 5%.The viscosity of the suspoemulsion can be measured using a rheometer. Atypical value for the viscosity of such a suspoemulsion is below 300 mPas at 100 s1, more preferred less than 250 mPas at 100 s1, more preferably less than 200 mPas at 100 s1, even more preferred less than 150 mPas at 100 s1or even less than 100 mPas at 100 s1.The invention furthermore relates to a spraying suspension obtainable by mixing water and the suspension concentrate or suspoemulsion according to the invention. The spraying suspension normally arises spontaneously upon mixing. The mixing weight / weight ratio of water to concentrate can be in the range of from 1000 to 1 up to 1 to 1 , preferably 400 to 1 up to 3 to 1 , more preferred 200 to 1 up to 3 to 1. The spraying suspension is preferably characterized by having a weight / weight ratio of sulfur to the combined amounts of all terpenes, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, between 24 to 1 and 12 to 1 , or between 20 to 1 and 12 to 1. Preferably limonene is selected.Methods to prepare:The suspension concentrate or suspoemulsion formulations of the invention can be produced using methods known in the art, such as described by Mollet and Grubemann, Formulation technology, Wiley VCH, Weinheim, 2001 ; or Knowles, New developments in crop protection product formulation, Agrow Reports DS243, T&F Informa, London, 2005.One method to prepare suspension concentrate or suspoemulsion formulations of the invention is performed by milling crystalline sulfur in water with suitable wetting agents and dispersants with a bead mill as known to those skilled in the art. The resulting Suspension is stabilized by addition of further additives like antifreeze agents, antifoam, biocides, thickeners and optionally further additives like buffer salts. To such a suspension the one or more terpenes, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, preferably limonene, are added by an emulsion process. The one or more selected terpenes, preferably limonene, can be emulsified as such into the suspension concentrate, if the dispersants and wetting agents that are used for preparing the sulfur suspension are also suited to emulsify the one or more selected terpenes. Otherwise, further emulsifiers specific to be used with the one or more selected terpenes, are added to the one or more selected terpenes to form an oil phase, which is then added to the sulfur suspension using shear energy and thus emulsifying the oil phase comprising the one or more selected terpenes into the sulfur suspension.Customary mixing devices which, if appropriate, can be heated may be used for preparing the mixtures. For the preliminary milling step, it is possible to use, for example, mills which operate on the rotor-stator principle, such as Ultraturax homogenizers, for example from IKA, or toothed colloid mills, for example from Puck. Apparatus which can be used for the fine-grinding step can be, for example, batchwise-operating bead mills, for example from Drais, or continuously-operating bead mills, for example from Bachofen. Depending on the properties of the components employed, and on process-engineering and safety aspects and economic reasons, the preparation process can be adapted and, if appropriate, a pre-grinding step or else a fine-grinding step can be dispensed with.25041715In an aspect, the present disclosure provides a process for preparing a suspoemulsion comprising;(i) preparing a suspension concentrate (SC) phase comprising sulfur and one or more alkyl naphthalene sulfonates dispersed in water,(ii) preparing an emulsifyable phase (EC) comprising one or more terpenes, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol and one or more polyalkoxylated arylalkylphenols and one or more sulphosuccinates, both pre-emulsified in water, and(iii) combining the SC phase with the emulsion phase to produce the suspoemulsion.In another aspect, the present disclosure provides a process for preparing a suspoemulsion comprising;(i) preparing a suspension concentrate (SC) phase comprising sulfur and one or more alkyl naphthalene sulfonates dispersed in water;(ii) preparing an oil in water emulsion (EW) phase or an emulsion concentrate (EC) phase comprising orange oil and one or more polyalkoxylated arylalkylphenols and one or more sulphosuccinates, both pre-emulsified in water,(iii) combining the SC phase with the EW phase or the EC phase to produce the suspoemulsion.In another aspect, the present disclosure provides a process for preparing a suspoemulsion comprising;(i) preparing a suspension concentrate (SC) phase comprising sulfur and one or more alkyl naphthalene sulfonates,(ii) preparing an oil in water emulsion (EW) phase or an emulsion concentrate (EC) phase comprising limonene and one or more polyalkoxylated arylalkylphenols and one or more sulphosuccinates, both pre-emulsified in water,(iii) combining the SC phase with the EW phase or the EC phase to produce the suspoemulsion.Steps (i) and (II) can be performed at the same time or step (II) before step (I) before they are combined in step (III).Method for controlling phytopathogenic fungi using the suspension concentrate or suspoemulsion described herein:The invention comprises a method for controlling phytopathogenic fungi comprising contacting the fungi, the plant, or the plant parts to be protected against fungal attack with a fungicidal effective amount of a spraying suspension obtained by mixing water and the suspension concentrate or suspoemulsion described herein. Accordingly, the invention comprises a method for controlling phytopathogenic fungi, comprising the steps of a) identifying a plant or a plurality of plants infected or in danger of being infected with at least one fungus and b) contacting the fungi, the plant, or the plant parts to be protected against fungal attack with a fungicidally effective amount of a spraying suspension obtained by mixing water and the suspension concentrate or suspoemulsion described herein.25041716The suspension concentrates or suspoemulsions and the spraying suspensions prepared therefrom, respectively, are suitable as fungicides effective against a broad spectrum of phyto-pathogenic fungi, including soil-borne fungi, in particular from the classes of Plasmodiophoro-mycetes, Peronosporomycetes (syn. Oomycetes), Chytridiomycetes, Zygomycetes, Ascomy-cetes, Basidiomycetes, and Deuteromycetes (syn. Fungi imperfecti). They can be used in crop protection as foliar fungicides, fungicides for seed dressing, and soil fungicides.The suspension concentrates or suspoemulsions and the spraying suspensions prepared therefrom are preferably useful in the control of phytopathogenic fungi on various cultivated plants, such as cereals, e.g. wheat, rye, barley, triticale, oats, or rice; beet, e.g. sugar beet or fodder beet; fruits, e.g. pomes (apples, pears, etc.), stone fruits (e.g. plums, peaches, almonds, cherries), or soft fruits, also called berries (strawberries, raspberries, blackberries, gooseberries, etc.); leguminous plants, e.g. lentils, peas, alfalfa, or soybeans; oil plants, e.g. oilseed rape, mustard, olives, sunflowers, coconut, cocoa beans, castor oil plants, oil palms, ground nuts, or soybeans; cucurbits, e.g. squashes, cucumber, or melons; fiber plants, e.g. cotton, flax, hemp, or jute; citrus fruits, e.g. oranges, lemons, grapefruits, or mandarins; vegetables, e.g. spinach, lettuce, asparagus, cabbages, carrots, onions, tomatoes, potatoes, cucurbits, or paprika; laura-ceous plants, e.g. avocados, cinnamon, or camphor; energy and raw material plants, e.g. corn, soybean, oilseed rape, sugar cane, or oil palm; corn; tobacco; nuts; coffee; tea; bananas; vines (table grapes and grape juice grape vines); hop; turf; sweet leaf (also called Stevia); natural rubber plants; or ornamental and forestry plants, e.g. flowers, shrubs, broad-leaved trees, or evergreens (conifers, eucalypts, etc.); on the plant propagation material, such as seeds; and on the crop material of these plants.More preferably, the suspension concentrates or suspoemulsions and the spraying suspensions prepared therefrom, respectively are used for controlling fungi on field crops, such as potatoes, sugar beets, tobacco, wheat, rye, barley, oats, rice, corn, cotton, soybeans, oilseed rape, legumes, sunflowers, coffee or sugar cane; fruits; vines; ornamentals; or vegetables, such as apples, peaches, pears, cherries, cucumbers, tomatoes, beans or squashes.The term "plant propagation material" is to be understood to denote all the generative parts of the plant, such as seeds; and vegetative plant materials, such as cuttings and tubers (e.g. potatoes), which can be used for the multiplication of the plant. This includes seeds, roots, fruits, tubers, bulbs, rhizomes, shoots, sprouts and other parts of plants; including seedlings and young plants to be transplanted after germination or after emergence from soil.Preferably, treatment of plant propagation materials with the suspension concentrates or suspoemulsions and the spraying suspensions prepared therefrom, respectively, is used for controlling fungi on cereals, such as wheat, rye, barley and oats; rice, corn, cotton, sunflower, rape seed, soybeans and fruits and fruit trees like apples, pears and peaches.According to the invention all of the above cultivated plants are understood to comprise all species, subspecies, variants, varieties and / or hybrids which belong to the respective cultivated plants, including but not limited to winter and spring varieties, in particular in cereals such as wheat and barley, as well as oilseed rape, e.g. winter wheat, spring wheat, winter barley etc, further including dwarf, semi-dwarf and full-dwarf varieties and / or hybrids with reduced height and thicker and shorter stems, e.g. short stature corn (also called ‘smart corn’), semi-dwarf wheat and dwarf rice.Corn is also known as Indian corn or maize (Zea mays) which comprises all kinds of corn such as field corn and sweet corn. According to the invention all maize or corn subspeciesand / or varieties are comprised, in particular flour corn (Zea mays var. amy / acea), popcorn (Zea mays var. everta), dent corn (Zea mays var. indentata), flint corn (Zea mays var. indurata), sweet corn (Zea mays var. saccharata and var. rugosa), waxy corn (Zea mays var. ceratina), amylomaize (high amylose Zea mays varieties), pod corn or wild maize (Zea mays var. tunicata) and striped maize (Zea mays var. japonica).Most soybean cultivars are classifiable into indeterminate and determinate growth habit, whereas Glycine soja, the wild progenitor of soybean, is indeterminate (PNAS 2010, 107 (19) 8563-8568). The indeterminate growth habit (Maturity Group, MG 00 to MG 4.9) is characterized by a continuation of vegetative growth after flowering begins whereas determinate soybean varieties (MG 5 to MG 8) characteristically have finished most of their vegetative growth when flowering begins. According to the invention all soybean cultivars or varieties are comprised, in particular indeterminate and determinate cultivars or varieties.The term "cultivated plants" is to be understood as including plants which have been modified by mutagenesis or genetic engineering to provide a new trait to a plant or to modify an already present trait. Mutagenesis includes random mutagenesis using X-rays or mutagenic chemicals, but also targeted mutagenesis to create mutations at a specific locus of a plant genome. Targeted mutagenesis frequently uses oligonucleotides or proteins like CRISPR / Cas, zinc-finger nucleases, TALENs or meganucleases. Genetic engineering usually uses recombinant DNA techniques to create modifications in a plant genome which under natural circumstances cannot readily be obtained by cross breeding, mutagenesis or natural recombination. Typically, one or more genes are integrated into the genome of a plant to add a trait or improve or modify a trait. These integrated genes are also referred to as transgenes, while plant comprising such transgenes are referred to as transgenic plants. The process of plant transformation usually produces several transformation events, which differ in the genomic locus in which a transgene has been integrated. Plants comprising a specific transgene on a specific genomic locus are usually described as comprising a specific “event”, which is referred to by a specific event name. Traits which have been introduced in plants or have been modified include herbicide tolerance, insect resistance, increased yield and tolerance to abiotic conditions, like drought. Herbicide tolerance has been created by using mutagenesis and genetic engineering. Plants which have been rendered tolerant to acetolactate synthase (ALS) inhibitor herbicides by mutagenesis and breeding are e.g. available under the name Clearfield®. Herbicide tolerance to glyphosate, glufosinate, 2,4-D, dicamba, oxynil herbicides, like bromoxynil and ioxynil, sulfonylurea herbicides, ALS inhibitors and 4-hydroxyphenylpyruvate dioxygenase (HPPD) inhibitors, like isoxaflutole and mesotrione, has been created via the use of transgenes.Transgenes to provide herbicide tolerance traits comprise: for tolerance to glyphosate: cp4 epsps, epsps grg23ace5, mepsps, 2mepsps, gat4601, gat4621, goxv247; for tolerance to glufosinate: pat and bar, for tolerance to 2,4-D: aad-1, aad-12; for tolerance to dicamba: dmo; for tolerance to oxynil herbicies: bxn; for tolerance to sulfonylurea herbicides: zm-hra, csr1-2, gm-hra, S4-HrA; for tolerance to ALS inhibitors: csr1-2; and for tolerance to HPPD inhibitors: hppdPF, W336, avhppd-03.Transgenic corn events comprising herbicide tolerance genes include, but are not limited to, DAS40278, MON801, MON802, MON809, MON810, MON832, MON87411, MON87419, MON87427, MON88017, MON89034, NK603, GA21, MZHG0JG, HCEM485, VCO-01981-5, 676, 678, 680, 33121, 4114, 59122, 98140, Bt10, Bt176, CBH-351, DBT418, DLL25, MS3, MS6, MZIR098, T25, TC1507 and TC6275. Transgenic soybean events comprising herbicidetolerance genes include, but are not limited to, GTS 40-3-2, MON87705, MON87708, MON87712, MON87769, MON89788, A2704-12, A2704-21 , A5547-127, A5547-35, DP356043, DAS44406-6, DAS68416-4, DAS-81419-2, GU262, SYHT0H2, W62, W98, FG72 and CV127. Transgenic cotton events comprising herbicide tolerance genes include, but are not limited to, 19-51a, 31707, 42317, 81910, 281-24-236, 3006-210-23, BXN10211, BXN10215, BXN10222, BXN10224, MON1445, MON1698, MON88701, MON88913, GHB119, GHB614, LLCotton25, T303-3 and T304-40. Transgenic canola events comprising herbicide tolerance genes are for example, but not excluding others, MON88302, HCR-1, HCN10, HCN28, HCN92, MS1, MS8, PHYU, PHY23, PHY35, PHY36, RF1, RF2 and RF3.Transgenes to provide insect resistance preferably are toxin genes of Bacillus spp. and synthetic variants thereof, like cry1A, crylAb, cry1Ab-Ac, crylAc, cry1A.1O5, cry1F, cry1Fa2, cry2Ab2, cry2Ae, mcry3A, ecry3.1Ab, cry3Bb1, cry34Ab1, cry35Ab1, cry9C, vip3A(a), vip3Aa20. In addition, transgenes of plant origin, such as genes coding for protease inhibitors, like CpTI and pin 11 , can be used. A further approach uses transgenes such as dvsnf? to produce double-stranded RNA in plants.Transgenic corn events comprising genes for insecticidal proteins or double stranded RNA include, but are not limited to, Bt10, Bt11 , Bt176, MON801, MON802, MON809, MON810, MON863, MON87411, MON88017, MON89034, 33121, 4114, 5307, 59122, TC1507, TC6275, CBH-351, MIR162, DBT418 and MZIR098. Transgenic soybean events comprising genes for insecticidal proteins include, but are not limited to, MON87701, MON87751 and DAS-81419. Transgenic cotton events comprising genes for insecticidal proteins include, but are not limited to, SGK321, MON531, MON757, MON1076, MON15985, 31707, 31803, 31807, 31808, 42317, BNLA-601, Eventl , COT67B, COT102, T303-3, T304-40, GFM Cry1A, GK12, MLS 9124, 281-24-236, 3006-210-23, GHB119 and SGK321.Cultivated plants with increased yield have been created by using the transgene athb17 (e.g. corn event MON87403), or bbx32 (e.g. soybean event MON87712).Cultivated plants comprising a modified oil content have been created by using the transgenes: gm-fad2-1, Pj.D6D, Nc.Fad3, fad2-1A and fatb1-A (e.g. soybean events 260-05, MON87705 and MON87769).Tolerance to abiotic conditions, such as drought, has been created by using the transgene cspB (corn event MON87460) and Hahb-4 (soybean event IND-00410-5).Traits are frequently combined by combining genes in a transformation event or by combining different events during the breeding process resulting in a cultivated plant with stacked traits. Preferred combinations of traits are combinations of herbicide tolerance traits to different groups of herbicides, combinations of insect tolerance to different kind of insects, in particular tolerance to lepidopteran and coleopteran insects, combinations of herbicide tolerance with one or several types of insect resistance, combinations of herbicide tolerance with increased yield as well as combinations of herbicide tolerance and tolerance to abiotic conditions.Plants comprising singular or stacked traits as well as the genes and events providing these traits are well known in the art. For example, detailed information as to the mutagenized or integrated genes and the respective events are available from websites of the organizations “International Service for the Acquisition of Agri-biotech Applications (ISAAA)” (http: / / www.isaaa.org / gmapprovaldatabase) and the “Center for Environmental Risk Assessment (CERA)” (http: / / cera-gmc.org / GMCropDatabase). Further information on specific events and methods to detect them can be found for canola events MS1 , MS8, RF3, GT73,19MON88302, KK179 in W001 / 031042, W001 / 041558, W001 / 041558, W002 / 036831, WO11 / 153186, W013 / 003558; for cotton events MON1445, MON15985, MON531 (MON15985), LLCotton25, MON88913, COT102, 281-24-236, 3006-210-23, COT67B, GHB614, T304-40, GHB119, MON88701 , 81910 in WO02 / 034946, W002 / 100163, W002 / 100163, W003 / 013224, WO04 / 072235, WO04 / 039986, WO05 / 103266, WO05 / 103266, WO06 / 128573, W007 / 017186, W008 / 122406, W008 / 151780, WO12 / 134808, WO13 / 112527; for corn events GA21, MON810, DLL25, TC1507, MON863, MIR604, LY038, MON88017, 3272, 59122, NK603, MIR162, MON89034, 98140, 32138, MON87460, 5307, 4114, MON87427, DAS40278, MON87411 , 33121 , MON87403, MON87419 in W098 / 044140, US02 / 102582, US03 / 126634, WO04 / 099447, WG04 / 011601 , WO05 / 103301 , W005 / 061720, W005 / 059103, WO06 / 098952, WO06 / 039376, US2007 / 292854, WO07 / 142840, WO07 / 140256, WO08 / 112019, W009 / 103049, WO09 / 111263, W010 / 077816, W011 / 084621 , W011 / 062904, WO11 / 022469, WO13 / 169923, WO14 / 116854, WO15 / 053998, WO15 / 142571 ; for potato events E12, F10, J3, J55, V11, X17, Y9 in WO14 / 178910, WO14 / 178913, WO14 / 178941, WO14 / 179276, WO16 / 183445, WO17 / 062831 , W017 / 062825; for rice events LLRICE06, LLRICE601, LLRICE62 in WO00 / 026345, WO00 / 026356, WO00 / 026345; and for soybean events H7-1, MON89788, A2704-12, A5547-127, DP305423, DP356043, MON87701, MON87769, CV127, MON87705, DAS68416-4, MON87708, MON87712, SYHT0H2, DAS81419, DAS81419 x DAS44406-6, MON87751 in WO04 / 074492, WO06 / 130436, WO06 / 108674, WO06 / 108675, WO08 / 054747, W008 / 002872, WO09 / 064652, WO09 / 102873, W010 / 080829, WO10 / 037016, W011 / 066384, W011 / 034704, W012 / 051199, W012 / 082548, WO13 / 016527, WO13 / 016516, WO14 / 201235.The use the suspension concentrates or suspoemulsions and the spraying suspensions prepared therefrom, respectively, on cultivated plants may result in effects which are specific to a cultivated plant comprising a certain transgene or event. These effects might involve changes in growth behavior or changed resistance to biotic or abiotic stress factors. Such effects may in particular comprise enhanced yield, enhanced resistance or tolerance to insects, nematodes, fungal, bacterial, mycoplasma, viral or viroid pathogens as well as early vigor, early or delayed ripening, cold or heat tolerance as well as changed amino acid or fatty acid spectrum or content.The suspension concentrates or suspoemulsions and the spraying suspensions prepared therefrom, respectively, are particularly suitable for controlling the following causal agents of plant diseases:Albugo spp. (white rust) on ornamentals, vegetables (e.g. A. Candida) and sunflowers (e.g. A. tragopogonis): Alternaria spp. (Alternaria leaf spot) on vegetables (e.g. A. dauci or A. porn), oilseed rape (A. brassicicola or brassicae), sugar beets (A. tenuis), fruits (e.g. A. grandis), rice, soybeans, potatoes and tomatoes (e.g. A. solani, A. grandis or A. alternata), tomatoes (e.g. A. solani or A. alternata) and wheat (e.g. A. triticina)- Aphanomyces spp. on sugar beets and vegetables; Ascochyta spp. on cereals and vegetables, e.g. A. tritici (anthracnose) on wheat and A. hordei on barley; Aureobasidium zeae (syn. Kapatiella zeae) on corn; Bipolaris and Drechslera spp. (teleomorph: Cochliobolus spp.), e.g. Southern leaf blight (D. maydis) or Northern leaf blight (B. zeicola) on corn, e.g. spot blotch (B. sorokiniana) on cereals and e.g. B. oryzae on rice and turfs; Blumeria (formerly Erysiphe) graminis (powdery mildew) on cereals (e.g. on wheat or barley); Botrytis cinerea (teleomorph: Botryotinia fuckeliana'. grey mold) on fruits and berries (e.g. strawberries), vegetables (e.g. lettuce, carrots, celery and cabbages); B. squamosa or B.25041720aim on onion family), oilseed rape, ornamentals (e.g. B eliptica), vines, forestry plants and wheat; Bremia lactucae (downy mildew) on lettuce; Ceratocystis (syn. Ophiostoma) spp. (rot or wilt) on broad-leaved trees and evergreens, e.g. C. ulmi (Dutch elm disease) on elms; Cerco-spora spp. (Cercospora leaf spots) on corn (e.g. Gray leaf spot: C. zeae-maydis), rice, sugar beets (e.g. C. betico / a), sugar cane, vegetables, coffee, soybeans (e.g. C. sojina or C. kikuchii) and rice; Cladobotryum (syn. Dactylium) spp. (e.g. C. mycophilum (formerly Dactylium den-droides, teleomorph: Nectria albertinii, Nectria rosella syn. Hypomyces rosellus) on mushrooms; Cladosporium spp. on tomatoes (e.g. C. fulvunr. leaf mold) and cereals, e.g. C. herbarum (black ear) on wheat; Claviceps purpurea (ergot) on cereals; Cochliobolus (anamorph: Helminthosporium of Bipolaris) spp. (leaf spots) on corn (C. carbonum), cereals (e.g. C. sativus, anamorph: B. sorokiniana) and rice (e.g. C. miyabeanus, anamorph: H. oryzae); Colletotrichum (teleomorph: Glomerella) spp. (anthracnose) on cotton (e.g. C. gossypii), corn (e.g. C. gramini-cola: Anthracnose stalk rot), soft fruits, potatoes (e.g. C. coccodes: black dot), beans (e.g. C. lindemuthianum), soybeans (e.g. C. truncatum or C. gloeosporioides), vegetables (e.g. C. lage-narium or C. capsici), fruits (e.g. C. acutatum), coffee (e.g. C. coffeanum or C. kahawae) and C. gloeosporioides on various crops; Corticium spp., e.g. C. sasakii (sheath blight) on rice; Coryne-spora cassiicola (leaf spots) on soybeans, cotton and ornamentals; Cycloconium spp., e.g. C. oleaginum on olive trees; Cylindrocarpon spp. (e.g. fruit tree canker or young vine decline, teleomorph: Nectria or Neonectria spp.) on fruit trees, vines (e.g. C. liriodendri, teleomorph: Neonectria liriodendrr'. Black Foot Disease) and ornamentals; Dematophora (teleomorph: Rosel-linia) necatrix (root and stem rot) on soybeans; Diaporthe spp., e.g. D. phaseolorum (damping off) on soybeans; Drechslera (syn. Helminthosporium, teleomorph: Pyrenophora) spp. on corn, cereals, such as barley (e.g. D. teres, net blotch) and wheat (e.g. D. tritici-repentis tan spot), rice and turf; Esca (dieback, apoplexy) on vines, caused by Formitiporia (syn. Phellinus) punctata, F. mediterranea, Phaeomoniella chlamydospora (formerly Phaeoacremonium chlamydo-sporum), Phaeoacremonium aleophilum and / or Botryosphaeria obtusa: Elsinoe spp. on pome fruits (E. pyri), soft fruits (E. veneta anthracnose) and vines (E. ampelina'. anthracnose); En-tyloma oryzae (leaf smut) on rice; Epicoccum spp. (black mold) on wheat; Erysiphe spp. (powdery mildew) on sugar beets (E. betae), vegetables (e.g. E. p / s / ), such as cucurbits (e.g. E. cichoracearum), cabbages, oilseed rape (e.g. E. cruciferarum); Eutypa lata (Eutypa canker or dieback, anamorph: Cytosporina lata, syn. Libertella blepharis) on fruit trees, vines and ornamental woods; Exserohilum (syn. Helminthosporium) spp. on corn (e.g. E. turcicum); Fusarium (teleomorph: Gibberella) spp. (wilt, root or stem rot) on various plants, such as F. graminearum or F. culmorum (root rot, scab or head blight) on cereals (e.g. wheat or barley), F. oxysporum on tomatoes, F. solani (f. sp. glycines now syn. F. virguliforme ) and F. tucumaniae and F. brasili-ense each causing sudden death syndrome on soybeans, and F. verticillioides on corn;Gaeumannomyces graminis (take-all) on cereals (e.g. wheat or barley) and corn; Gibberella spp. on cereals (e.g. G. zeae) and rice (e.g. G. fujikuror'. Bakanae disease); Glomerella cingu-lata on vines, pome fruits and other plants and G. gossypii on cotton; Grainstaining complex on rice; Guignardia bidwellii (black rot) on vines; Gymnosporangium spp. on rosaceous plants and junipers, e.g. G. sabinae (rust) on pears; Helminthosporium spp. (syn. Drechslera, teleomorph: Cochliobolus) on corn, cereals, potatoes and rice; Hemileia spp., e.g. H. vastatrix (coffee leaf rust) on coffee; Isariopsis clavispora (syn. Cladosporium vitis) on vines; Macrophomina phaseolina (syn. phaseoli) (root and stem rot) on soybeans and cotton; Microdochium (syn. Fusarium) nivale (pink snow mold) on cereals (e.g. wheat or barley); Microsphaera diffusa25041721(powdery mildew) on soybeans; Monilinia spp., e.g. M. laxa, M. fructicola and M. fructigena (syn. Monilia spp.: bloom and twig blight, brown rot) on stone fruits and other rosaceous plants; Mycosphaerella spp. on cereals, bananas, soft fruits and ground nuts, such as e.g. M. gramini-cola (anamorph: Zymoseptoria tritici formerly Septoria tritici: Septoria blotch) on wheat or M. fi-jiensis (syn. Pseudocercospora fijiensis black Sigatoka disease) and M. musicola on bananas, M. arachidicola (syn. M. arachidis or Cercospora arachidis), M. berkeleyi on peanuts, M. pis! on peas and M. brassiciola on brassicas; Peronospora spp. (downy mildew) on cabbage (e.g. P. brassicae), oilseed rape (e.g. P. parasitica), onions (e.g. P. destructor), tobacco (P. tabacina) and soybeans (e.g. P. manshurica)- Phakopsora pachyrhizi and P. meibomiae (soybean rust) on soybeans; Phialophora spp. e.g. on vines (e.g. P. tracheiphila and P. tetraspora) and soybeans (e.g. P. gregata stem rot); Phoma lingam (syn. Leptosphaeria biglobosa and L. macu-lans'. root and stem rot) on oilseed rape and cabbage, P. betae (root rot, leaf spot and damping-off) on sugar beets and P. zeae-maydis (syn. Phyllostica zeae) on corn; Phomopsis spp. on sunflowers, vines (e.g. P. viticola’. can and leaf spot) and soybeans (e.g. stem rot: P. phaseoli, teleomorph: Diaporthe phaseolorum) Physoderma maydis (brown spots) on corn; Phytophthora spp. (wilt, root, leaf, fruit and stem root) on various plants, such as paprika and cucurbits (e.g. P. capsici), soybeans (e.g. P. megasperma, syn. P. sojae), potatoes and tomatoes (e.g. P. in-festans'. late blight) and broad-leaved trees (e.g. P. ramorunr. sudden oak death); Plasmodi-ophora brassicae (club root) on cabbage, oilseed rape, radish and other plants; Plasmopara spp., e.g. P. viticola (grapevine downy mildew) on vines and P. halstedii on sunflowers; Podo-sphaera spp. (powdery mildew) on rosaceous plants, hop, pome and soft fruits (e.g. P. leuco-tricha on apples) and curcurbits (P. xanthii , Polymyxa spp., e.g. on cereals, such as barley and wheat (P. graminis) and sugar beets (P. betae) and thereby transmitted viral diseases; Pseudo-cercosporella herpotrichoides (syn. Oculimacula yallundae, O. acu for mis', eyespot, teleomorph: Tapesia yallundae) on cereals, e.g. wheat or barley; Pseudoperonospora (downy mildew) on various plants, e.g. P. cubensis on cucurbits or P. humili on hop; Pseudopezicula tracheiphila (red fire disease or ,rotbrenner’, anamorph: Phialophora) on vines; Puccinia spp. (rusts) on various plants, e.g. P. triticina (brown or leaf rust), P. striiformis (stripe or yellow rust), P. horde! (dwarf rust), P. graminis (stem or black rust) or P. recondita (brown or leaf rust) on cereals, such as e.g. wheat, barley or rye, P. kuehnii (orange rust) on sugar cane and P. asparagi on asparagus; Pyrenopeziza spp., e.g. P. brassicae on oilseed rape; Pyrenophora (anamorph:Drechslera) tritici-repentis (tan spot) on wheat or P. teres (net blotch) on barley; Pyricularia spp., e.g. P. oryzae (teleomorph: Magnaporthe grisea rice blast) on rice and P. grisea on turf and cereals; Pythium spp. (damping-off) on turf, rice, corn, wheat, cotton, oilseed rape, sunflowers, soybeans, sugar beets, vegetables and various other plants (e.g. P. ultimum or P. aphani-dermatum) and P. oligandrum on mushrooms; Ramularia spp., e.g. R. collo-cygni (Ramularia leaf spots, Physiological leaf spots) on barley, R. areola (teleomorph: Mycosphaerella areola) on cotton and R. beticola on sugar beets; Rhizoctonia spp. on cotton, rice, potatoes, turf, corn, oilseed rape, potatoes, sugar beets, vegetables and various other plants, e.g. R. solan! (root and stem rot) on soybeans, R. solan! (sheath blight) on rice or R. cerealis (Rhizoctonia spring blight) on wheat or barley; Rhizopus stolonifer (black mold, soft rot) on strawberries, carrots, cabbage, vines and tomatoes; Rhynchosporium secalis and R. commune (scald) on barley, rye and triticale; Sarocladium oryzae and S. attenuatum (sheath rot) on rice; Sclerotinia spp. (stem rot or white mold) on vegetables (S. minor and S. sclerotiorum) and field crops, such as oilseed rape, sunflowers (e.g. S. sclerotiorum) and soybeans, S. rolfsii (syn. Athelia rolfsii) on soybeans,25041722peanut, vegetables, corn, cereals and ornamentals; Septoria spp. on various plants, e.g. S. glycines (brown spot) on soybeans, S. tritici (syn. Zymoseptoria tritici, Septoria blotch) on wheat and S. (syn. Stagonospora) nodorum (Stagonospora blotch) on cereals; Uncinula (syn. Ery-siphe) necator (powdery mildew, anamorph: Oidium tuckeri) on vines; Setosphaeria spp. (leaf blight) on corn (e.g. S. turcicum, syn. Helminthosporium turcicum) and turf; Sphacelotheca spp. (smut) on corn, (e.g. S. reiliana, syn. Ustilago reiliana'. head smut), sorghum und sugarcane; Sphaerotheca fuliginea (syn. Podosphaera xanthii: powdery mildew) on cucurbits; Spongospora subterranea (powdery scab) on potatoes and thereby transmitted viral diseases; Stagonospora spp. on cereals, e.g. S. nodorum (Stagonospora blotch, teleomorph: Leptosphaeria [syn. Phae-osphaeria] nodorum, syn. Septoria nodorum) on wheat; Synchytrium endobioticum on potatoes (potato wart disease); Taphrina spp., e.g. T. deformans (leaf curl disease) on peaches and T. pruni (plum pocket) on plums; Thielaviopsis spp. (black root rot) on tobacco, pome fruits, vegetables, soybeans and cotton, e.g. T. basicola (syn. Chalara elegans); Tilletia spp. (common bunt or stinking smut) on cereals, such as e.g. T. tritici (syn. T. caries, wheat bunt) and T. contro-versa (dwarf bunt) on wheat; Trichoderma harzianum on mushrooms’ Typhula incarnata (grey snow mold) on barley or wheat; Urocystis spp., e.g. U. occulta (stem smut) on rye; Uromyces spp. (rust) on vegetables, such as beans (e.g. U. appendiculatus, syn. U. phaseoli), sugar beets (e.g. U. betae or U. beticola) and on pulses (e.g. U. vignae, U. pisi, U. viciae-fabae and U. fa-bae)’ Ustilago spp. (loose smut) on cereals (e.g. U. nuda and U. avaenae), corn (e.g. U. maydis'. corn smut) and sugar cane; Venturia spp. (scab) on apples (e.g. V. inaequalis) and pears; and Verticillium spp. (wilt) on various plants, such as fruits and ornamentals, vines, soft fruits, vegetables and field crops, e.g. V. longisporum on oilseed rape, V. dahliae on strawberries, oilseed rape, potatoes and tomatoes, and V. fungicola on mushrooms; Zymoseptoria tritici on cereals.The a suspension concentrate or suspoemulsion formulations and the spraying suspensions prepared therefrom, respectively, are particularly suitable for controlling the following causal agents of plant diseases: rusts on soybean and cereals (e.g. Phakopsora pachyrhizi and P. mei-bomiae on soy; Puccinia tritici and P. striiformis on wheat); molds on specialty crops, soybean, oil seed rape and sunflowers (e.g. Botrytis cinerea on strawberries and vines, Sclerotinia sclero-tiorum, S. minor and S. rolfsii on oil seed rape, sunflowers and soybean); Fusarium diseases on cereals (e.g. Fusarium culmorum and F. graminearum on wheat); downy mildews on specialty crops (e.g. Plasmopara viticola on vines, Phytophthora infestans on potatoes); powdery mildews on specialty crops and cereals (e.g. Uncinula necator on vines, Erysiphe spp. on various specialty crops, Blumeria graminis on cereals); and leaf spots on cereals, soybean and corn (e.g. Septoria tritici and S. nodorum on cereals, S. glycines on soybean, Cercospora spp. on corn and soybean).It has been observed that populations of phytopathogenic fungi apparently consisting of non-resistant strains can readily develop resistance. The compounds can be applied under such conditions, too, to prevent the formation of resistance and the spread of resistant strains altogether. In this regard it is useful that they have strong activity also against non-resistant phytopathogenic fungi.Fungicide-resistant strains of various phytopathgenic fungi have been reported, with strains resistant to one or more fungicides from various mode of action classes being observed by tar-get-site mutations in the genes of the respective proteins (e.g. Qol (C3, according to FRAC convention, for details www.frac.info), quinone outside stigmatellin binding subsite inhibitors (QoSI;25041723C8), and quinone inside inhibitors (Qil; C4): CytB target protein; sterol demethylaition (DMI, G1): Cyp51 / Erg11; carboxylic acid amides (CAA, H5): CesA3; SDHI (C2): SdhB, SdhC and SdhD; dicarboximides (E3): Os-1 (including Bos1, Daf1 etc.); keto reductase inhibitors (KRI; Class III SBIs; G3): Erg27; and oxysterol binding protein inhibitors (OSBPI; F9): ORP1.Preferably the fungi to be controlled are selected from the genera Puccinia, Erysiphe, Blumeria, Podosphaera, Septoria, Cercospora, Sclerotinia, Pyrenophora, Ramularia, Fusarium, Venturia, and Diplocarpon.The invention furthermore relates to a method for controlling phytopathogenic fungi selected from the genera Puccinia, Erysiphe, Blumeria, Podosphaera, Septoria, Cercospora, Sclerotinia, Pyrenophora, Ramularia, Fusarium, Venturia, and Diplocarpon, comprising contacting the fungi, the plant, or the plant parts to be protected against fungal attack with a fungicidally effective amount of a spraying suspension prepared from one of the suspension concentrates or suspoe-mulsions, described herein.Preferably at least one fungus is selected from the species Puccinia triticina, Erysiphe graminis, Fusarium graminearum, Sclerotinia sclerotiorum, Cercospora beticola, Cercospora sojina, Septoria tritici, Ramularia collo-cygni or Venturia inequalis.Preferably, the spraying suspension is applied when the phytopathogenic fungi is present. Accordingly, the invention comprises a method for controlling phytopathogenic fungi, comprising the steps of a) identifying a plant or a plurality of plants infected or in danger of being infected with at least one fungus selected from the genera Puccinia, Erysiphe, Blumeria, Podosphaera, Septoria, Cercospora, Sclerotinia, Pyrenophora, Ramularia, Fusarium, Venturia, and Diplocarpon andb) comprising contacting the fungi, the plant, or the plant parts infected or in danger of being infected with a fungicidally effective amount of a spraying suspension prepared form a suspension concentrate or suspoemulsion described herein. Preferably the plant is infected or is in danger of being infected by a fungus of the genus Puccinia, Erysiphe, Blumeria, Podosphaera, Septoria, Cercospora, Sclerotinia, Pyrenophora, Ramularia, Fusarium, Venturia, and Diplocarpon. Even more preferred, the plant is infected or is in danger of being infected by a fungus of the species Puccinia triticina, Erysiphe graminis, Fusarium graminearum, Sclerotinia sclerotiorum, Cercospora beticola, Cercospora sojina, Septoria tritici, Ramularia collo-cygni, or Venturia inequalis.The invention comprises a method for controlling phytopathogenic fungi selected from the genera, Erysiphe, Blumeria, Podosphaera, Septoria, Cercospora, Sclerotinia, Pyrenophora, Ramularia, Fusarium, Venturia, and Diplocarpon, comprising contacting the fungi, the plant or the plant parts to be protected against fungal attack with a fungicidally effective amount of a mixture comprising sulfur and at least one terpene, selected from limonene, terpinene, pinene, p-cy-mene, eugenol, geraniol, thymol and carvacrol,! in a weight / weight ratio of sulfur to the combined amounts of limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrols between 25 to 1 and 10 to 1, or between 24 to 1 and 12 to 1, or between 20 to 1 and 10 to 1 , or between 20 to 1 and 12 to 1.The term "fungicidally effective amount" denotes an amount of the spraying solution prepared from the suspension concentrate or suspoemulsion formulation described herein, which is sufficient for controlling harmful fungi and which does not result in a substantial damage to the25041724treated plants, the treated stored products or harvest, or to the treated materials. Such an amount can vary in a broad range and is dependent on various factors, such as the fungal species to be controlled, the treated cultivated plant, stored product, harvest or material and the climatic conditions.Preferably, the method comprises the steps of a) identifying a plant or a plurality of plants infected or in danger of being infected with at least one fungus selected from the genera, Puccinia, Erysiphe, Blumeria, Podosphaera, Septoria, Cercospora, Sclerotinia, Pyrenophora, Ramularia, Fusarium, Venturia, and Diplocarpon and b) comprising contacting the fungi, the plant, or the plant parts to be protected against fungal attack with a fungicidally effective amount of a mixture comprising sulfur and at least one terpene, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, in a weight / weight ratio of sulfur to the combined amount of limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, between 25 to 1 and 10 to 1, or between 24 to 1 and 12 to 1, or between 20 to 1 and 10 to 1 , or between 20 to 1 and 12 to 1.Preferably, the mixture comprises limonene, preferably D-limonene, wherein the weight / weight ratio between sulfur and limonene is between between 25 to 1 and 10 to 1 , or between 24 to 1 and 12 to 1 , or between 20 to 1 and 10 to 1 , or between 20 to 1 and 12 to 1.More preferred at least one fungus is of a genus selected from: Puccinia, Erysiphe, Blumeria, Podosphaera, Septoria, Cercospora, Sclerotinia, Pyrenophora, Ramularia, Fusarium, Venturia, and Diplocarpon.Preferably at least one fungus is from a species selected from: Puccinia triticina, Puccinia strii-formis, Erysiphe graminis, Septoria tritici, Cercospora beticola, Cercospora sojina, Sclerotinia sclerotiorum, Ramularia collo-cygni, Fusarium graminearum, Pyrenophora teres and Venturia inequalis. More preferred at least one fungus is from a species selected from: Puccinia triticina, Puccinia striiformis, Erysiphe graminis, Septoria tritici, Cercospora beticola, Cercospora sojina, Sclerotinia sclerotiorum, Ramularia collo-cygni and Fusarium graminearum.In one embodiment the mixture comprises limonene, preferably D-limonene, wherein the weight / weight ratio between sulfur and limonene is between 25 to 1 and 10 to 1 , or between 24 to 1 and 12 to 1 and at least one fungus is from a genus selected from: Puccinia, Blumeria, Uncinula, Cercospora, Septoria, Ramularia, Venturia, Rhynchosporium and Sphaerotheca.In one embodiment the mixture comprises limonene, preferably D-limonene, wherein the weight / weight ratio between sulfur and limonene is between 25 to 1 and 10 to 1 , or between 24 to 1 and 12 to 1 and at least one fungus is from a species selected from: Puccinia triticina, Puccinia recondita, Blumeria graminis, Uncinula necator, Cercospora beticola, Cercospora sojina, Septoria tritici, Ramularia collo-cygni, Venturia inaequalis, Rhynchosporium secalis and Sphaerotheca fuliginea.In one embodiment the mixture comprises limonene, preferably D-limonene, wherein the weight / weight ratio between sulfur and limonene is between 25 to 1 and 10 to 1 , or between 24 to 1 and 12 to 1 and at least one fungus is from a species selected from: Puccinia triticina, Puccinia recondita, Blumeria graminis, Uncinula necator, Cercospora beticola, Cercospora sojina, Septoria tritici, Ramularia collo-cygni, Venturia inaequalis, Rhynchosporium secalis and Sphaerotheca fuliginea.In one embodiment the mixture comprises limonene, preferably D-limonene, wherein the weight / weight ratio between sulfur and limonene is between 25 to 1 and 10 to 1 , or between 24to 1 and 12 to 1 and at least one fungus is from a species selected from: Puccinia recondita, Cercospora sojina and Sphaerotheca fuliginea.In one embodiment the mixture comprises limonene, preferably D-limonene, wherein the weight / weight ratio between sulfur and limonene is between 25 to 1 and 10 to 1 , or between 24 to 1 and 12 to 1 and at least one fungus is from a species selected from: Cercospora beticola and Venturia inaequalis.In one embodiment the mixture comprises limonene, preferably D-limonene, wherein the weight / weight ratio between sulfur and limonene is between 25 to 1 and 10 to 1 , or between 24 to 1 and 12 to 1 and at least one fungus is from a species selected from: Puccinia triticina, Blu-meria graminis, Uncinula necator, Septoria tritici, Ramularia collo-cygni and Rhynchosporium secalis.Preferably, the mixture is applied when the phytopathogenic fungi is present or infections are likely due to the weather conditions.The invention comprises also a method for controlling or reducing Fusarium head blight (FHB) in wheat, barley, rye or oat, comprising a) identifying a plant or a plurality of plants infected or in danger of being infected by Fusarium head blight and b) contacting the fungi, the plant or the plant parts infected or in danger of being infected by Fusarium head blight with a fungicidally effective amount of a mixture comprising sulfur and at least one terpene, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, wherein the weight / weight ratio of the amount of sulfur to the combined amount of at least one terpene, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, is between 25 to 1 and 10 to 1 , or between 24 to 1 and 12 to 1.In one embodiment at least one of the selected terpenes is limonene, preferably D-limonene, in a weight / weight ratio between sulfur and limonene is between 25 to 1 and 10 to 1 , or between 24 to 1 and 12 to 1.Fusarium head blight is caused by several species of the fungal genus Fusarium. Fusarium gra-minearum is the species that causes the most serious damage to crops. Fungi of the genus Fusarium are known to produce mycotoxins. For example, Fusarium graminearum frequently produces zearalenone and trichothecenes, such as nivalenol, deoxynivalenol (DON) and / or acetylated derivatives of DON such as 3-acetyl-DON and 15-acetyl-DON. Fungi of the genus Cercospora are known to produce mycotoxins called cercosporins.Accordingly, the invention comprises a method to reduce the amount of mycotoxins present in plant material, comprising the steps of a) identifying a plant or a plurality of plants infected or in danger of being infected by mycotoxin producing fungi, preferably the mycotoxin producing fungi belong to the genus Fusarium or Cercospora, and b) contacting the fungi, the plant or the plant parts infected or in danger of being infected by mycotoxin producing fungi with a fungicidally effective amount of a mixture comprising sulfur and at least one terpene, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, wherein the weight / weight ratio of the amount of sulfur to the combined amount of at least one terpene, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, between 25 to 1 and 10 to 1, or between 24 to 1 and 12 to 1 In one embodiment at least one of the selected terpenes is limonene, preferably D-limonene, in a weight / weight ratio between sulfur and limonene is between 100 to 1 and 1 to 2, or between 70 to 1 and 1 to 2, or between 65to 1 and 4 to 1 , or between 63 to 1 and 2 to 1 , or between 30 to 1 and 1 to 1 , or between 25 to 1 and 1 to 1 , or between 24 to 1 and 2 to 1 or between 12 to 1 and 2 to 1 , or between 5 to 1 and 2 to 1.The phytopathogenic fungi of the genus Puccinia are preferably selected from the species Puc-cinia triticina, Puccinia graminis f. sp. avenae, Puccinia graminis f. sp. poae, Puccinia graminis f. sp. secalis, Puccinia graminis f. sp. tritici, Puccinia graminis subsp. graminicola, Puccinia helian-thi, Puccinia hordei, Puccinia sorghi, Puccinia striiformis f. sp. hordei and Puccinia striiformis f. sp. tritici. In one embodiment the phytopathogenic fungi are from the species Puccinia triticina. The phytopathogenic fungi of the genus Podosphaera are preferably selected from the species Podosphaera fuliginea, Podosphaera leucotricha, Podosphaera clandestina, Podosphaera pan-nosa, Podosphaera tridactyla, Podosphaera xanthii, Podosphaera mors-uvae and Podosphaera aphanis or are selected from Podosphaera leucotricha, Podosphaera clandestina, Podosphaera pannosa, Podosphaera tridactyla, Podosphaera xanthii, Podosphaera mors-uvae and Podosphaera aphanis. In one embodiment the phytopathogenic fungi are from the species Podosphaera leucotricha. In another embodiment the phytopathogenic fungi are from the species Podosphaera fuliginea. The phytopathogenic fungi of the genus Erysiphe and Blumeria are preferably selected from the species Blumeria graminis, also known as Erysiphe graminis, Blumeria graminis f. sp. avenae, Blumeria graminis f. sp. hordei, Blumeria graminis f. sp. secalis, Blumeria graminis f. sp. tritici Erysiphe cruciferarum, Erysiphe necator, Erysiphe cichoracearum and Erysiphe betae. In one embodiment the phytopathogenic fungi are from the species Blumeria graminis.The phytopathogenic fungi of the genus Septoria are preferably selected from the species Zy-moseptoria tritici, also known as Septoria tritici, Septoria betae, Septoria glycines, Septoria heli-anthi and Septoria secalis. In one embodiment the phytopathogenic fungi are from the species Zymoseptoria tritici.The phytopathogenic fungi of the genus Cercospora are preferably selected from the species Cercospora beticola, Cercospora brassicicola, Cercospora janseana, Cercospora sojina, Cercospora kikuchii, Cercospora concors, Cercospora solani, Cercospora solani-tuberosi, Cercospora sorghi and Cercospora zeae-maydis. In one embodiment the phytopathogenic fungi are from the species Cercospora beticola. In one embodiment the phytopathogenic fungi are from the species Cercospora sojina.The phytopathogenic fungi of the genus Sclerotinia are preferably selected from the species Sclerotinia sclerotiorum.The phytopathogenic fungi of the genus Ramularia are preferably selected from the species Ramularia collo-cygni and Ramularia beticola. In one embodiment the phytopathogenic fungi are from the species Ramularia collo-cygni.The phytopathogenic fungi of the genus Fusarium are preferably selected from the species Fusarium graminearum, Fusarium culmorum, Fusarium avenaceum, Microdochium nivale, Fusarium verticilloides, Fusarium oxysporum and Fusarium poae.In one embodiment the phytopathogenic fungi is from the species Fusarium graminearum. The phytopathogenic fungi of the genus Pyrenophora are preferably selected from the species Pyrenophora teres, Pyrenophora tritici-repentis, Pyrenophora graminea and Pyrenophora avenae. In one embodiment the phytopathogenic fungi are selected from the species Pyrenophora teres and Pyrenophora tritici-repentis.27The phytopathogenic fungi of the genus Venturia are preferably selected from the species Venturia inaequalis, Venturia carpophila, Venturia cerasi, Venturia nashicola, Venturia pyrina, Venturia oleaginea. In one embodiment the phytopathogenic fungi are selected from the species Venturia inaequalis.The phytopathogenic fungi of the genus Diplocarpon are preferably selected from the species Diplocarpon mall (anamorph Marssonina coronaria), Diplocarpon mespili and Diplocarpon fragariae. In one embodiment the phytopathogenic fungi are selected from the species Diplocarpon mall.In one embodiment the plant or the plant parts to be protected is from the genus Triticum, preferably of the species Triticum aestivum or Triticum durum, more preferred from the species Triticum aestivum, and the phytopathogenic fungi is from a species selected from Puccinia triticina, Puccinia graminis f. sp. tritici, Puccinia striiformis f. sp. tritici, Erysiphe graminis, Blumeria graminis f. sp. tritici, Zymoseptoria tritici and Pyrenophora tritici-repenti. Preferably, the plant or the plant parts are protected from Puccinia triticina and Erysiphe graminis. More preferred, the plant or the plant parts are protected from Puccinia triticina, Erysiphe graminis, and at least one of Zymoseptoria tritici and Pyrenophora tritici-repentis.In one embodiment the plant or the plant parts to be protected is from the species Hordeum vul-gare and the phytopathogenic fungi is from a species selected from Pyrenophora teres, Blumeria graminis f. sp. horde! and Ramularia collo-cygni. Preferably, the plant or the plant parts are protected from at leaf two of Pyrenophora teres, Blumeria graminis f. sp. horde! and Ramularia collo-cygni.In one embodiment the plant or the plant parts to be protected is from the species Secale cere-ale and the phytopathogenic fungi is from a species selected from Puccinia graminis f. sp. secalis, Blumeria graminis f. sp. secalis and Septoria secalis. Preferably, the plant or the plant parts are protected from Puccinia graminis f. sp. secalis and Blumeria graminis f. sp. secalis. In one embodiment the plant or the plant parts to be protected is from the species Avena sativa and the phytopathogenic fungi is from a species selected from Puccinia graminis f. sp. avenae, Blumeria graminis f. sp. avenae, and Pyrenophora avenae. Preferably, the plant or the plant parts are protected from Puccinia graminis f. sp. avenae and Blumeria graminis f. sp. avenae. In one embodiment the plant or the plant parts to be protected is from the species Zea mays and the phytopathogenic fungi is from a species selected from Puccinia sorghi and Cercospora zeae-maydis.In one embodiment the plant or the plant parts to be protected is from the species Beta vulgaris and the phytopathogenic fungi is from a species selected from Cercospora beticola, Septoria betae and Ramularia beticola. Preferably, the plant or the plant parts are protected from Cercospora beticola and at least one of Septoria betae and Ramularia beticola.In one embodiment the plant or the plant parts to be protected is from the species Brassica na-pus and the phytopathogenic fungi is from a species selected from Sclerotinia sclerotiorum and Erysiphe cruciferarum. Preferably, the plant or the plant parts are protected from Sclerotinia sclerotiorum.In one embodiment the plant or the plant parts to be protected is from the species Glycine max and the phytopathogenic fungi is from a species selected from Cercospora kikuchii, Cercospora sojina, Septoria glycines and Sclerotinia sclerotiorum. Preferably, the plant or the plant parts are protected from Sclerotinia sclerotiorum. or Cercospora sojina.25041728In one embodiment the plant or the plant parts to be protected is from the species Solanum tuberosum and the phytopathogenic fungi is from a species selected from Erysiphe cichoracea-rum, Cercospora concors, Cercospora solani, Cercospora solani-tuberosi, and Sclerotinia sclerotiorum. Preferably, the plant or the plant parts are protected from Sclerotinia sclerotiorum. In one embodiment the plant or the plant parts to be protected is from the species Helianthus annuus and the phytopathogenic fungi is from a species selected from Puccinia helianthi, Sep-toria helianthi, and Sclerotinia sclerotiorum. Preferably, the plant or the plant parts are protected from Sclerotinia sclerotiorum.In one embodiment the plant or the plant parts to be protected is from the genus Triticum, Hordeum, Secale or Zea, preferably of the species Triticum aestivum, Triticum durum, Hordeum vulgare, Secale cereale or Zea mays, more preferred from the species Triticum aestivum, and the phytopathogenic fungi is from a species selected from the genus Fusarium, preferably from the species Fusarium graminearum, Fusarium culmorum, Fusarium avenaceum, Fusarium ver-ticilloides, Fusarium oxysporum and Fusarium poae, more preferred from the species Fusarium graminearum.In one embodiment the plant or the plant parts to be protected is from the genus Malus, preferably of the species Malus domestica and the phytopathogenic fungi is from the species Venturia inaequalis, Podosphaera leucotricha.or Diplocarpon mall.In one embodiment the plant or the plant parts to be protected is from the genus Pyrus, preferably of the species Pyrus communis or Pyrus pyrifolia and the phytopathogenic fungi is from the species Venturia pyrina, Venturia nashicola or Diplocarpon mespili.In one embodiment the plant or the plant parts to be protected is from the genus Malus, Prunus, Pyrus or Olea, preferably of the species Malus domestica, Prunus persica, Prunus domestica, Prunus domestica, Prunus armeniaca, Prunus avium, Prunus cerasus, Pyrus pyrifolia, Pyrus communis or Olea europaea, and the phytopathogenic fungi is from a species selected from the genus Venturia, preferably of the species Venturia inaequalis, Venturia carpophila, Venturia cerasi, Venturia nashicola, Venturia pyrina, or Venturia oleaginea.In one embodiment the plant or the plant parts to be protected is from banana or plantain and the phytopathogenic fungi is from a species selected from Mycosphaerella fiijiensis, Myco-sphaerella musicola, Cercospora hayi, Sclerotinia sclerotiorum, or Septoria eumusae.A method for controlling phytopathogenic insects or arachnids or both, comprising contacting the insects or arachnids or both, the plant or the plant parts to be protected against insect or arachnid attack with an effective amount of a spraying solution prepared from the suspension concentrate or suspoemulsion described herein.Accordingly, the invention comprises a method for controlling phytopathogenic insects or arachnids or both, comprising the steps of a) identifying a plant or a plurality of plants infected or in danger of being infected with at least one phytopathogenic insect or arachnid species and b) contacting the phytopathogenic insect or arachnid species, the plant, or the plant parts to be protected against attack by such phytopathogenic insect or arachnid species with an effective amount of a spraying suspension obtained by mixing water and the suspension concentrate or suspoemulsion described herein.The term "effective amount" denotes in this context an amount of the spraying solution prepared from a suspension concentrate or suspoemulsion formulation described herein, which is sufficient for controlling the phytopathogenic insect or arachnid species in question and which does25041729not result in a substantial damage to the treated plants, the treated stored products or harvest, or to the treated materials. Such an amount can vary in a broad range and is dependent on various factors, such as the insect or arachnid species to be controlled, the treated cultivated plant, stored product, harvest or material and the climatic conditions.In one embodiment the insect species is selected from aphids, whiteflies, trips, mealybugs and scale insects, preferably from the genus Acyrthosiphon, Aphis, Rhopalosiphum, Schizaphis and Megoura. Preferably from the species, Acyrthosiphon pisum, Aphis fabae, Myzus persicae, Rhopalosiphum padi, Schizaphis graminum and Megoura viciae.In one embodiment the insect species is selected from whiteflies, preferably from the genus Trialeurodes and Bemisia, preferably from the species Trialeurodes vaporariorum, Bemisia tabacr',In one embodiment the insect species is selected from mealybugs, preferably from the genus Pianococcus or Pseudococcus, preferably from the species Pianococcus citri, Pseudococcus maritimus, Pseudococcus longispinus, and Pseudococcus elisae.In one embodiment the arachnid species is a mite species selected from the genus Penthaleus, Tetranychus, Panonychus, Eutetranychus or Phyllocoptruta, preferably selected from the species Penthaleus major, Tetranychus urticae, Panonychus citri, Panonychus ulmi, Panonychus citri, Eutetranychus orientalis, Eutetranychus banks!, Eutetranychus africanus and Phyllocoptruta oleivora.Another embodiment of the invention is a method for controlling phytopathogenic insects or arachnids or both, comprising contacting the insects and or arachnids or both, the plant or the plant parts to be protected against insect or arachnid attack with an effective amount of a spraying solution comprising a mixture of sulfur and at least one terpene, selected from the group comprising limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, preferably at least one terpene is limonene, more preferred at least one terpene is D-limonene. Even more preferred, the amount of limonene is at least 90% or at least 95%, or at least 98%, or at least 99%, of the total amount of the terpenes present.Preferably the weight / weight ratio ofa) the amount of sulfur to the combined amounts of the terpenes, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, is between 30 to 1 and 10 to 1 , or between 25 to 1 and 10 to 1 , or between 25 to 1 and 12 to 1 , or between 24 to 1 and 8 to 1 , or between 24 to 1 and 10 to 1 , or between 24 to 1 and 12 to 1 , orb) the amount of sulfur to the amount of limonene, preferably D-limonene, is between 30 to 1 and 10 to 1 , or between 25 to 1 and 10 to 1 , or between 25 to 1 and 12 to 1 , or between 24 to 1 and 8 to 1 , or between 24 to 1 and 10 to 1 , or between 24 to 1 and 12 to 1.Typical application rates are between 3500 g to 2000 g of sulfur per hectare (ha) and 600 g to 100 g of the combined amount of terpenes per hectare. Preferably the application rate uses between 600 g to 100 g of limonene, preferably D-limonene, per hectare. Preferred examples for application rates are: 3000 g of sulfur per ha and 500 g of limonene per ha or 3000 g of sulfur per ha and 250 g of limonene per ha or 3000 g of sulfur per ha and 180 g of limonene per ha or 2400 g or sulfur per ha and 200 g of limonene per ha.The mixtures of sulfur and terpenes can be used for controlling phytopathogenic insects or arachnids including:25041730insects from the order of Lepidoptera, e.g. Achroia grisella, Acleris spp. e.g. A. fimbriana, A. gloverana, A. variana; Acrolepiopsis assectella, Acronicta major, Adoxophyes spp. e.g. A. cyr-tosema, A. orana; Aedia leucomelas, Agrotis spp. e.g. A. exclamationis, A. fucosa, A. ipsilon, A. orthogoma, A. segetum, A. subterranea; Alabama argillacea, Aleurodicus dispersus, Alsophila pometaria, Ampelophaga rubiginosa, Amyelois transitella, Anacampsis sarcitella, Anagasta ku-ehniella, Anarsia Hneatella, Anisota sanatoria, Antheraea pernyi, Anticarsia (=Thermesia) spp. e.g. A. gemmatalis; Apamea spp., Aproaerema modicella, Archips spp. e.g. A. argyrospila, A. fuscocupreanus, A. rosana, A. xyloseanus; Argyresthia conjugella, Argyroploce spp., Argyrotae-nia spp. e.g. A. velutinana; Athetis mindara, Austroasca viridigrisea, Autographa gamma, Autog-rapha nigrisigna, Barathra brassicae, Bedellia spp., Bonagota salubricola, Borbo cinnara, Buc-culatrix thurberiella, Bupalus piniarius, Busseola spp., Cacoecia spp. e.g. C. murinana, C. po-dana; Cactoblastis cactorum, Cadra cautella, Calingo braziliensis, Caloptilis theivora, Capua re-ticulana, Carposina spp. e.g. C. niponensis, C. sasakii; Cephus spp., Chaetocnema aridula, Cheimatobia brumata, Chilo spp. e.g. C. Indicus, C. suppressalis, C. partellus; Choreutis pari-ana, Choristoneura spp. e.g. C. conflictana, C. fumiferana, C. longicellana, C. murinana, C. oc-cidentalis, C. rosaceana; Chrysodeixis (=Pseudoplusia) spp., e.g. C. eriosoma, C. includens; Cirphis unipuncta, Clysia ambiguella, Cnaphalocerus spp., Cnaphalocrocis medinalis, Cnepha-sia spp., Cochylis hospes, Coleophora spp., Colias eurytheme, Conopomorpha spp., Conotra-chelus spp., Copitarsia spp., Corcyra cephalonica, Crambus caliginosellus, Crambus teterrellus, Crocidosema (=Epinotia) aporema, Cydalima (=Diaphania) perspectalis, Cydia (=Carpocapsa) spp., e.g. C. pomonella, C. latiferreana; Dalaca noctuides, Datana integerrima, Dasychira pini-cola, Dendrolimus spp., e.g. D. pini, D. spectabilis, D. sibiricus; Desmia funeralis, Diaphania spp., e.g. D. nitidalis, D. hyalinata; Diatraea grandiosella, Diatraea saccharalis, Diphthera fes-tiva, Earias spp. e.g. E. insulana, E. vittella; Ecdytolopha aurantianu, Egira (=Xylomyges) curi-alis, Elasmopalpus lignosellus, Eldana saccharina, Endopiza viteana, Ennomos subsignaria, Eoreuma loftini, Ephestia spp., e.g. E. cautella, E. elutella, E. kuehniella; Epinotia aporema, Epiphyas postvittana, Erannis tiliaria, Erionota thrax, Etiella spp., Eulia spp., Eupoecilia ambiguella, Euproctis chrysorrhoea, Euxoa spp., Evetria bouliana, Faronta albilinea, Feltia spp. e.g. F. subterranean; Galleria mellonella, Gracillaria spp., Grapholita spp. e.g. G. funebrana, G. molesta, G. inopinata; Halysidota spp., Harrisina americana, Hedylepta spp., Helicoverpa spp. e.g. H. armigera (=Heliothis armigera), H. zea (=Heliothis zea); Heliothis spp. e.g. H. assulta, H. subflexa, H. virescens; Hellula spp. e.g. H. undalis, H. rogatalis; Helocoverpa gelotopoeon, Hemileuca oliviae, Herpetogramma licarsisalis, Hibernia defoliaria, Hofmannophila pseu-dospretella, Homoeosoma electellum, Homona magnanima, Hypena scabra, Hyphantria cunea, Hyponomeuta padella, Hyponomeuta malinellus, Kakivoria flavofasciata, Keiferia lycopersicella, Lambdina fiscellaria fiscellaria, Lambdina fiscellaria lugubrosa, Lamprosema indicata, Laspeyre-sia molesta, Leguminivora glycinivorella, Lerodea eufala, Leucinodes orbonalis, Leucoma sali-cis, Leucoptera spp. e.g. L. coffeella, L. scitella; Leuminivora lycinivorella, Lithocolletis blancar-della, Lithophane antennata, Llattia octo (=Amyna axis), Lobesia botrana, Lophocampa spp., Loxagrotis albicosta, Loxostege spp. e.g. L. sticticalis, L. cereralis; Lymantria spp., e.g. L. dispar, L. monacha; Lyonetia clerkella, Lyonetia prunifoliella, Malacosoma spp., e.g. M. ameri-canum, M. californicum, M. constrictum, M. neu-stria; Mamestra spp., e.g. M. brassicae, M. con-figurata; Mamstra brassicae, Manduca spp. e.g. M. quinquemaculata, M. sexta; Marasmia spp, Marmara spp., Maruca testulalis, Megalopyge lanata, Melanchra picta, Melanitis leda, Mods spp., e.g. M. lapites, M. repanda; Mods latipes, Monochroa fragariae, Mythimna separata,25041731Nemapogon cloacella, Neoleucinodes elegantalis, Nepytia spp., Nymph ula spp., Oiketicus spp., Omiodes indicata, Omphisa anastomosalis, Operophtera brumata, Orgyia pseudotsugata, Oria spp., Orthaga thyrisalis, Ostrinia spp. e.g. O. nubilalis; Oulema oryzae, Paleacrita vernata, Panolis flammea, Parnara spp., Papaipema nebris, Papilio cresphontes, Paramyelois transitella, Paranthrene regalis, Paysandisia archon, Pectinophora spp. e.g. P. gossypiella; Peridroma sau-cia, Perileucoptera spp., e.g. P. coffeella; Phalera bucephala, Phryganidia californica, Phthori-maea spp. e.g. P. operculella; Phyllocnistis citrella, Phyllonorycter spp. e.g. P. blancardella, P. crataegella, P. issikii, P. ringoniella; Pieris spp. e.g. P. brassicae, P. rapae, P. napi; Pilocrocis tripunctata, Plathypena scabra, Platynota spp. e.g. P. flavedana, P. idaeusalis, P. stultana; Platyptilia carduidactyla, Plebejus argus, Plo-dia interpunctella, Plusia spp, Plutella maculi-pennis, Plutella xylostella, Pontia protodica, Prays spp., Prodenia spp., Proxenus lepigone, Pseudaletia spp. e.g. P. sequax, P. unipuncta; Pyrausta nubilalis, Rachiplusia nu, Richia al-bicosta, Rhizobius ventralis, Rhyacionia frustrana, Sabulodes aegrotata, Schizura concinna, Schoenobius spp., Schreckensteinia festaliella, Scirpophaga spp. e.g. S. incertulas, S. innotata; Scotia segetum, Sesamia spp. e.g. S. inferens, Seudyra sub f lava, Sitotroga cerealella, Sparganothis pilleriana, Spilonota lechriaspis, S. ocelli-na, Spodoptera (=Lamphygma) spp. e.g. S. cosmoides, S. eridania, S. exigua, S. frugiperda, S. latisfascia, S. littoralis, S. litura, S. omithogalli; Stigmella spp., Stomopteryx subsecivella, Strymon bazochii, Sylepta derogata, Synanthedon spp. e.g. S. exitiosa, Tecia solanivora, Telehin Ileus, Thaumatopoea pityocampa, Thaumatotibia (=Cryptophlebia) leucotreta, Thaumetopoea pityocampa, Thecla spp., Theresi-mima ampelophaga, Thyrinteina spp, Tildenia inconspicuella, Tinea spp. e.g. T. cloacella, T. pellionella; Tineola bisselliella, Tortrix spp. e.g. T. viridana; Trichophaga tapetzella, Trichoplusia spp. e.g. T. ni; Tuta (=Scrobipalpula) absoluta, Udea spp. e.g. U. rubigalis, U. rubigalis; Vira-chola spp., Yponomeuta padella, and Zeiraphera canadensis’insects from the order of Coleoptera, e.g. Acalymma vittatum, Acanthoscehdes obtectus, Adore-tus spp., Agelastica alni, Agrilus spp. e.g. A. anxius, A. planipennis, A. sinuatus; Agriotes spp. e.g. A. fuscicollis, A. lineatus, A. obscurus; Alphitobius diaperinus, Amphimallus solstitialis, Ani-sandrus dispar, Anisoplia austriaca, Anobium punctatum, Anomala corpulenta, Anomala rufocu-prea, Anoplophora spp. e.g. A. glabripennis; Anthonomus spp. e.g. A. eugenii, A. grandis, A. pomorum; Anthrenus spp., Aphthona euphoridae, Apion spp., Apogonia spp., Athous haemor-rhoidalis, Atomaria spp. e.g. A. linearis; Attagenus spp., Aulacophora femoralis, Blastophagus piniperda, Blitophaga undata, Bruchidius obtectus, Bruchus spp. e.g. B. lentis, B. pisorum, B. rufimanus; Byctiscus betulae, Callidiellum rufipenne, Callopistria floridensis, Callosobruchus chinensis, Cameraria ohridella, Cassida nebulosa, Cerotoma trifurcata, Cetonia aurata, Ceutho-rhynchus spp. e.g. C. assimilis, C. napi; Chaetocnema tibialis, Cleonus mendicus, Conoderus spp. e.g. C. vespertinus; Conotrachelus nenuphar, Cosmopolites spp., Costelytra zealandica, Crioceris asparagi, Cryptolestes ferruginous, Cryptorhynchus lapathi, Ctenicera spp. e.g. C. destructor; Curculio spp., Cylindrocopturus spp., Cyclocephala spp., Dac-tylispa balyi, Dectes texanus, Dermestes spp., Diabrotica spp. e.g. D. undecim punctata, D. speciosa, D. longicornis, D. semipunctata, D. virgifera; Diaprepes abbreviates, Dichocrocis spp., Dicladispa armigera, Dilo-boderus abderus, Diocalandra frumenti (Diocalandra stigmaticollis), Enaphalodes rufulus, Epi-lachna spp. e.g. E. varivestis, E. vigintioctomaculata; Epitrix spp. e.g. E. hirtipennis, E. similaris; Eutheola humilis, Eutinobothrus brasiliensis, Faustinus cubae, Gibbium psylloides, Gnathocerus cornutus, Hellula undalis, Heteronychus arator, Hylamorpha elegans, Hylobius abietis, Hy-lotrupes bajulus, Hypera spp., e.g. H. brunneipennis, H. postica; Hypomeces squamosus,25041732Hypothenemus spp., Ips typographus, Lachnosterna consanguinea, Lasioderma serricorne, La-theticus oryzae, Lathridius spp., Lema spp. e.g. L. bilineata, L. melanopus; Leptinotarsa spp. e.g. L. decemlineata; Leptispa pygmaea, Limonius californi-cus, Lissorhoptrus oryzophilus, Lixus spp., Luperodes spp., Lyctus spp. e.g. L. bruneus; Liogenys fuscus, Macrodactylus spp. e.g. M. subspinosus; Maladera matrida, Megaplatypus mutates, Megascelis spp., Melanotus communis, Meligethes spp. e.g. M. aeneus; Melolontha spp. e.g. M. hippocastani, M. melolon-tha; Metamasius hemipterus, Microtheca spp., Migdolus spp. e.g. M. fryanus, Monochamus spp. e.g. M. alternatus; Naupactus xanthographus, Niptus hololeucus, Oberia brevis, Oemona hirta, Oryctes rhinoceros, Oryzaephilus surinamensis, Oryzaphagus oryzae, Otiorrhynchus sul-catus, Otiorrhynchus ovatus, Otiorrhynchus sulcatus, Oulema melanopus, Oulema oryzae, Ox-ycetonia jucunda, Phaedon spp. e.g. P. brassicae, P. cochleariae; Phoracantha recurva, Phyl-lobius pyri, Phyllopertha horticola, Phyllophaga spp. e.g. P. helleri; Phyllotreta spp. e.g. P. chrysocephala, P. nemorum, P. striolata, P. vittula; Phyllopertha horticola, Popillia japonica, Premnotrypes spp., Psacothea hilaris, Psylliodes chrysocephala, Prostephanus truncates, Psyl-liodes spp., Ptinus spp., Pulga saltona, Rhizopertha dominica, Rhynchophorus spp. e.g. R. billineatus, R. ferruginous, R. palmarum, R. phoenicis, R. vulneratus; Saperda Candida, Scoly-tus schevyrewi, Scyphophorus acupunctatus, Sitona lineatus, Sitophilus spp. e.g. S. granaria, S. oryzae, S. zeamais; Sphenophorus spp. e.g. S. levis; Stegobium paniceum, Sternechus spp. e.g. S. subsignatus; Strophomorphus ctenotus, Symphyletes spp., Tanymecus spp., Tenebrio molitor, Tenebrioides mauretanicus, Tribolium spp. e.g. T. castaneum; Trogoderma spp., Ty-chius spp., Xylotrechus spp. e.g. X. pyrrhoderus; and, Zabrus spp. e.g. Z. tenebrioides insects from the order of Diptera e.g. Aedes spp. e.g. A. aegypti, A. albopictus, A. vexans; Anastrepha ludens, Anopheles spp. e.g. A. albimanus, A. crucians, A. freeborni, A. gambiae, A. leucosphyrus, A. maculipennis, A. minimus, A. quadrimaculatus, A. sinensis; Bactrocera in-vadens, Bibio hortulanus, Calliphora erythrocephala, Calliphora vicina, Ceratitis capitata, Chrysomyia spp. e.g. C. bezziana, C. hominivorax, C. macellaria; Chrysops atlanticus, Chrys-ops discalis, Chrysops silacea, Cochliomyia spp. e.g. C. hominivorax; Contarinia spp. e.g. C. sorghicola; Cordylobia anthropophaga, Culex spp. e.g. C. nigripalpus, C. pipiens, C. quinque-fasciatus, C. tarsalis, C. tritaeniorhynchus; Culicoides furens, Culiseta inornata, Culiseta melanura, Cuterebra spp., Dacus cucurbitae, Dacus oleae, Dasineura brassicae, Dasineura ox-ycoccana, Delia spp. e.g. D. antique, D. coarctata, D. platura, D. radicum; Dermatobia hominis, Drosophila spp. e.g. D. suzukii, Fannia spp. e.g. F. canicularis; Gastraphilus spp. e.g. G. intesti-nalis; Geomyza tipunctata, Glossina spp. e.g. G. fuscipes, G. morsitans, G. palpalis, G. tachi-noides; Haematobia irritans, Haplodiplosis equestris, Hippelates spp., Hylemyia spp. e.g. H. platura; Hypoderma spp. e.g. H. lineata; Hyppobosca spp., Hydrellia philippina, Leptoconops tor-rens, Liriomyza spp. e.g. L. sativae, L. trifolii; Lucilia spp. e.g. L. caprina, L. cuprina, L. sericata; Lycoria pectoralis, Mansonia titillanus, Mayetiola spp. e.g. M. destructor; Musca spp. e.g. M. au-tumnalis, M. domestica; Muscina stabulans, Oestrus spp. e.g. O. ovis; Opomyza florum, Osci-nella spp. e.g. O. frit; Orseolia oryzae, Pegomya hysocyami, Phlebotomus argentipes, Phorbia spp. e.g. P. antiqua, P. brassicae, P. coarctata; Phytomyza gymnostoma, Prosimulium mixtum, Psila rosae, Psorophora columbiae, Psorophora discolor, Rhagoletis spp. e.g. R. cerasi, R. cingulate, R. indifferens, R. mendax, R. pomonella; Rivellia quadrifasciata, Sarcophaga spp. e.g. S. haemorrhoidalis; Simulium vittatum, Sitodiplosis mosellana, Stomoxys spp. e.g. S. calcitrans; Tabanus spp. e.g. T. atratus, T. bovinus, T. lineola, T. similis; Tannia spp., Thecodiplo-sis ja-ponensis, Tipula oleracea, Tipula paludosa, Wohlfahrtia spp, and Zaprionus indianus:25041733insects from the order of Thysanoptera e.g., Baliothrips biformis, Dichromothrips corbetti, Di-chromothrips ssp., Echinothrips americanus, Enneothrips flavens, Frankliniella spp. e.g. F. fusca, F. occidentalis, F. tritici; Heliothrips spp., Hercinothrips femoralis, Kakothrips spp., Micro-cephalothrips abdominalis, Neohydatothrips samayunkur, Pezothrips kellyanus, Rhipiphoro-thrips cruentatus, Scirtothrips spp. e.g. S. citri, S. dorsalis, S. perseae; Stenchaetothrips spp, Taeniothrips cardamon!, Taeniothrips inconsequens, Thrips spp. e.g. T. imagines, T. ha- waiiensis, T. oryzae, T. palmi, T. parvispinus, T. tabacr',insects from the order of Hemiptera e.g., Acizzia jamatonica, Acrosternum spp., e.g. A. hilare; Acyrthosipon spp., e.g. A. onobrychis, A. pisum; Adelges laricis, Adelges tsugae, Adelphocoris spp., e.g. A. rapidus, A. superbus; Aeneolamia spp., Agonoscena spp., Aulacorthum solani, Al-eurocanthus woglumi, Aleurodes spp., Aleurodicus disperses, Aleurolobus barodensis, Aleuro-thrixus spp., Amrasca spp., Anasa tristis, Antestiopsis spp., Anuraphis cardui, Aonidiella spp., Aphanostigma piri, Aphidula nasturtii, Aphis spp. e.g. A. craccivora, A. fabae, A. forbesi, A. gossypii, A. grossulariae, A. maidiradicis, A. pomi, A. sambuci, A. schneideri, A. spiraecola; Ar-boridia apicalis, Arilus critatus, Aspidiella spp., Aspidiotus spp., Atanus spp., Aulacaspis ya-sumatsui, Aulacorthum solani, Bactericera cockerelli (Paratrioza cockerelli), Bemisia spp. e.g. B. argentifolii, B. tabaci (Aleurodes tabaci); Blissus spp. e.g. B. leucopterus; Brachycaudus spp. e.g. B. cardui, B. helichrysi, B. persicae, B. prunicola; Brachycolus spp., Brachycorynella as-paragi, Brevicoryne brassicae, Cacopsylla spp. e.g. C. fulguralis, C. pyricola (Psylla piri); Cal-ligypona marginata, Calocoris spp., Campylomma livida, Capitophorus horni, Carneocephala fulgida, Cavelerius spp., Ceraplastes spp., Ceratovacuna lanigera, Ceroplastes ceriferus, Ce-rosipha gossypii, Chaetosiphon fragaefolii, Chionaspis tegalensis, Chlorita onukii, Chromaphis juglandicola, Chrysomphalus ficus, Cicadulina mbila, Cimex spp. e.g. C. hemipterus, C. lectular-ius; Circulifer tenellus, Coccomytilus halli, Coccus spp. e.g. C. hesperidum, C. pseudomagnoliarum; Corythucha arcuata, Creontiades dilutus, Cryptomyzus ribis, Chrysomphalus aonidum, Cryptomyzus ribis, Ctenarytaina spatulata, Cyrtopeltis notatus, Dalbulus spp., Dasynus piperis, Dialeurodes spp. e.g. D. citrifolii; Dalbulus maidis, Diaphorina spp. e.g. D. citri; Diaspis spp. e.g. D. bromeliae; Dichelops furcatus, Diconocoris heweti, Doralis spp., Dreyfusia nordmannianae, Dreyfusia piceae, Drosicha spp., Dysaphis spp. e.g. D. plantaginea, D. pyri, D. radicola; Dysaulacorthum pseudosolani, Dysdercus spp. e.g. D. cingulatus, D. intermedius; Dysmicoccus spp., Edessa spp., Geocoris spp., Empoasca spp. e.g. E. fabae, E. solana; Epidi-aspis leperii, Eriosoma spp. e.g. E. lanigerum, E. pyricola; Erythroneura spp., Eurygaster spp. e.g. E. integriceps; Euscelis bilobatus, Euschistus spp. e.g. E. heros, E. impictiventris, E. ser-vus; Fiorinia theae, Geococcus coffeae, Glycaspis brimblecombei, Halyomorpha spp. e.g. H. halys; Heliopeltis spp., Homalodisca vitripennis (=H. coagulata), Horcias nobilellus, Hyalopterus pruni, Hyperomyzus lactucae, Icerya spp. e.g. I. purchase; Idiocerus spp., Idioscopus spp., La-odelphax striatellus, Lecanium spp., Lecanoideus floccissimus, Lepidosaphes spp. e.g. L. ulmi; Leptocorisa spp., Leptoglossus phyllopus, Lipaphis erysimi, Lygus spp. e.g. L. hesperus, L. line-olaris, L. praten-sis; Maconellicoccus hirsutus, Marchalina hellenica, Macropes excavatus, Macrosiphum spp. e.g. M. rosae, M. avenae, M. euphorbiae; Macrosteles quadrilineatus, Ma-hanarva fimbriolata, Megacopta cribraria, Megoura viciae, Melanaphis pyrarius, Melanaphis sacchari, Melanocallis (=Tinocallis) caryaefoliae, Metcafiella spp., Metopolophium dirhodum, Monellia costalis, Mo-nelliopsis pecanis, Myzocallis coryli, Murgantia spp., Myzus spp. e.g. M. ascalonicus, M. cerasi, M. nicotianae, M. persicae, M. varians; Nasonovia ribisnigri, Neotox-optera formosana, Neomegalotomus spp, Nephotetix spp. e.g. N. malayanus, N. nigropictus, N.25041734parvus, N. vires-cens; Nezara spp. e.g. N. viridula; Nilaparvata lugens, Nysius huttoni, Oebalus spp. e.g. O. pugnax; Oncometopia spp., Orthezia praelonga, Oxycaraenus hyalinipennis, Para-bemisia myricae, Parlatoria spp., Parthenolecanium spp. e.g. P. corn!, P. persicae; Pemphigus spp. e.g. P. bursarius, P. populivenae; Peregrinus maidis, Perkinsiella saccharicida, Phena-coccus spp. e.g. P. aceris, P. gossypii; Phloeomyzus passerinii, Phorodon humuli, Phylloxera spp. e.g. P. devastatrix, Piesma quadrata, Piezodorus spp. e.g. P. guildinii; Pinnaspis aspidis-trae, Pianococcus spp. e.g. P. citri, P. ficus; Prosapia bicincta, Protopulvinaria pyriformis, Psal-lus seriatus, Pseudacysta persea, Pseudaulacaspis pentagona, Pseudococcus spp. e.g. P. comstocki; Psylla spp. e.g. P. mall; Pteromalus spp., Pulvinaria amygdali, Pyrilla spp., Quad-raspidiotus spp., e.g. Q. perniciosus; Quesada gigas, Rastrococcus spp., Reduvius senilis, Rhi-zoecus americanus, Rhodnius spp., Rhopalomyzus ascalonicus, Rhopalosiphum spp. e.g. R. pseudobrassicas, R. insertum, R. maidis, R. padi; Sagatodes spp., Sahlbergella singularis, Saissetia spp., Sappaphis mala, Sappaphis mall, Scaptocoris spp., Scaphoideus titanus, Schi-zaphis graminum, Schizoneura lanuginosa, Scotinophora spp., Selenaspidus articulatus, Sito-bion avenae, Sogata spp., Sogatella furcifera, Solubea insularis, Spissistilus festinus (=Sticto-cephala festina), Stephanitis nashi, Stephanitis pyrioides, Stephanitis takeyai, Tenalaphara malayensis, Tetraleurodes perseae, Therioaphis maculate, Thyanta spp. e.g. T. accerra, T. per-ditor; Tibraca spp., Tomaspis spp., Toxoptera spp. e.g. T. aurantii; Trialeurodes spp. e.g. T. abutilonea, T. ricini, T. vaporariorum; Triatoma spp., Trioza spp., Typhlocyba spp., Unaspis spp. e.g. U. citri, U. yanonensis; and Viteus vitifolii,Insects from the order Hymenoptera e.g. Acanthomyops interjectus, Athalia rosae, Atta spp. e.g. A. capiguara, A. cephalotes, A. cephalotes, A. laevigata, A. robusta, A. sexdens, A. texana, Bombus spp., Brachymyrmex spp., Camponotus spp. e.g. C. floridanus, C. pennsylvanicus, C. modoc; Cardiocondyla nuda, Chalibion sp, Crematogaster spp., Dasymutilla occidentalis, Diprion spp., Dolichovespula maculata, Dorymyrmex spp., Dryocosmus kuriphilus, Formica spp., Hoplocampa spp. e.g. H. minuta, H. testudinea; Iridomyrmex humilis, Lasius spp. e.g. L. niger, Linepithema humile, Liometopum spp., Leptocybe invasa, Monomorium spp. e.g. M. pharaonis, Monomorium, Nylandria fulva, Pachycondyla chinensis, Paratrechina longicornis, Paravespula spp., e.g. P. germanica, P. pennsylvanica, P. vulgaris; Pheidole spp. e.g. P. megacephala; Pogonomyrmex spp. e.g. P. barbatus, P. californicus, Polistes rubiginosa, Prenolepis impairs, Pseudomyrmex gracilis, Schelipron spp., Sirex cyaneus, Solenopsis spp. e.g. S. geminata, S. Invicta, S. molesta, S. richteri, S. xyloni, Sphecius speciosus, Sphex spp., Tapi noma spp. e.g. T. melanocephalum, T. sessile; Tetramorium spp., e.g. T. caespitum, T. bicarinatum, Vespa spp., e.g. V. crabro; Vespula spp., e.g. V. squamosal; Wasmannia auropunctata, Xylocopa sp; Insects from the order Orthoptera e.g. Acheta domesticus, Calliptamus italicus, Chortoicetes ter-minifera, Ceuthophilus spp., Diastrammena asynamora, Dociostaurus maroccanus, Gryllotalpa spp. e.g. G. africana, G. gryllotalpa; Gryllus spp., Hieroglyphus daganensis, Kraussaria angulif-era, Locusta spp. e.g. L. migratoria, L. pardalina; Melanoplus spp. e.g. M. bivittatus, M. femurrubrum, M. mexicanus, M. sanguinipes, M. spretus; Nomadacris septemfasciata, Oedaleus senegalensis, Scapteriscus spp., Schistocerca spp. e.g. S. americana, S. gregaria, Stemopel-matus spp., Tachycines asynamorus, and Zonozerus variegatus;Pests from the Class Arachnida e.g. Acari.e.g. of the families Argasidae, Ixodidae and Sarcopti-dae, e.g. Amblyomma spp. (e.g. A. americanum, A. variegatum, A. maculatum), Argas spp. e.g. A. persicu), Boophilus spp. e.g. B. annulatus, B. decoloratus, B. microplus, Dermacentor spp. e.g. D.silvarum, D. andersoni, D. variabilis, Hyalomma spp. e.g. H. truncatum, Ixodes spp. e.g. I.25041735ricinus, I. rubicundus, I. scapularis, I. holocyclus, I. pacificus, Rhipicephalus sanguineus, Orni-thodorus spp. e.g. O. moubata, O. hermsi, O. turicata, Ornithonyssus bacoti, Otobius megnini, Dermanyssus gallinae, Psoroptes spp. e.g. P. ovis, Rhipicephalus spp. e.g. R. sanguineus, R. appendiculatus, Rhipicephalus everts!, Rhizoglyphus spp., Sarcoptes spp. e.g. S. Scabiei; and Family Eriophyidae including Aceria spp. e.g. A. sheldoni, A. anthocoptes, Acallitus spp., Acu-lops spp. e.g. A. lycopersici, A. pelekassi; Aculus spp. e.g. A. schlechtendali; Colomerus vitis, Epitrimerus pyri, Phyllocoptruta oleivora; Eriophytes ribis and Eriophyes spp. e.g. Eriophyes sheldoni; Family Tarsonemidae including Hemitarsonemus spp., Phytonemus pallidus and Po-lyphagotarsonemus latus, Stenotarsonemus spp. Steneotarsonemus spinki; Family Tenuipalpi-dae including Brevipalpus spp. e.g. B. phoenicis; Family Tetranychidae including Eotetranychus spp., Eutetranychus spp., Oligonychus spp., Petrobia latens, Tetranychus spp. e.g. T. cinnabari-nus, T. evansi, T. kanzawai, T, pacificus, T. phaseulus, T. telarius and T. urticae; Bryobia praeti-osa; Panonychus spp. e.g. P. ulmi, P. citri; Metatetranychus spp. and Oligonychus spp. e.g. O. pratensis, O. perseae, Vasates lycopersici; Raoiella indica, Family Carpoglyphidae including Carpoglyphus spp.; Penthaleidae spp. e.g. Halotydeus destructor; Family Demodicidae with species e.g. Demodex spp.; Family Trombicidea including Trombicula spp.; Family Macronyssi-dae including Ornothonyssus spp.; Family Pyemotidae including Pyemotes tritici; Tyrophagus putrescentiae; Family Acaridae includ-ing Acarus siro; Family Araneida including Latrodectus mactans, Eratigena agrestis, Cheiracanthium sp, Lycosa sp Achaearanea tepidariorum and Loxosceles reclusaPests from the Phylum Nematoda, e.g. plant parasitic nematodes e.g. root-knot nematodes, Meloidogyne spp. e.g. M. hapla, M. incognita, M. javanica; cyst-forming nematodes, Globodera spp. e.g. G. rostochiensis; Heterodera spp. e.g. H. avenae, H. glycines, H. schachtii, H. trifolii; Seed gall nematodes, Anguina spp.; Stem and foliar nematodes, Aphelenchoides spp. e.g. A. besseyi; Sting nematodes, Belonolaimus spp. e.g. B. longicaudatus; Pine nematodes, Bur-saphelenchus spp. e.g. B. lignicolus, B. xylophilus; Ring nematodes, Criconema spp., Criconemella spp. e.g. C. xenoplax and C. ornata; and, Criconemoides spp. e.g. Criconemoides informis; Mesocriconema spp.; Stem and bulb nematodes, Ditylenchus spp. e.g. D. destructor, D. dipsaci; Awl nematodes, Dolichodorus spp.; Spiral nematodes, Heliocotylenchus multicinc-tus; Sheath and sheathoid nematodes, Hemicycliophora spp. and Hemicriconemoides spp.; Hirshmanniella spp.; Lance nematodes, Hoploaimus spp.; False rootknot nematodes, Nacobbus spp.; Needle nematodes, Longidorus spp. e.g. L. elongatus; Lesion nematodes, Pratylenchus spp. e.g. P. brachyurus, P. neglectus, P. penetrans, P. curvitatus, P. goodeyi; Burrowing nematodes, Radopholus spp. e.g. R. similis; Rhadopholus spp.; Rhodopholus spp.; Reniform nematodes, Rotylenchus spp. e.g. R. robustus, R. reniformis; Scutellonema spp.; Stubby-root nematode, Trichodorus spp. e.g. T. obtusus, T. primitivus; Paratrichodorus spp. e.g. P. minor; Stunt nematodes, Tylenchorhynchus spp. e.g. T. claytoni, T. dubius; Citrus nematodes, Tylenchulus spp. e.g. T. semipenetrans; Dagger nematodes, Xiphinema spp.’ and other plant parasitic nematode species;Insects from the order Blattodea e.g. Macrotermes spp. e.g. M. natalensis; Cornitermes cu-mu-lans, Procornitermes spp., Globitermes sulfureus, Neocapritermes spp. e.g. N. opacus, N. parvus; Odontotermes spp., Nasutitermes spp. e.g. N. corniger; Coptotermes spp. e.g. C. fior-mo-sanus, C. gestroi, C. acinaciformis; Reticulitermes spp. e.g. R. hesperus, R. tibialis, R. speratus, R. flavipes, R. grassei, R. lucifugus, R. virginicus; Heterotermes spp. e.g. H. aureus, H. longi-ceps, H. tenuis; Cryptotermes spp. e.g. C. brevis, C. cavifrons; Incisitermes spp. e.g. I. minor, I.25041736snyderi; Marginitermes hubbardi, Kalotermes flavicollis, Neotermes spp. e.g. N. cas-taneus, Zootermopsis spp. e.g. Z. angusticollis, Z. nevadensis, Mastotermes spp. e.g. M. dar-winiensis; Blatta spp. e.g. B. orientalis, B. lateralis; Blattella spp. e.g. B. asahinae, B. germanica; Rhyparo-bia maderae, Panchlora nivea, Periplaneta spp. e.g. P. americana, P. australasiae, P. brunnea, P. fuliginosa, P. japonica; Supella longipalpa, Parcoblatta pennsylvanica, Eurycotis floridana, Pycnoscelus surinamensis,Insects from the order Siphonoptera e.g. Cediopsylla simples, Ceratophyllus spp., Ctenoce-phalides spp. e.g. C. fells, C. cam's, Xenopsylla cheopis, Pulex irritans, Trichodectes canis, Tunga penetrans, and Nosopsyllus fasciatus,Insects from the order Thysanura e.g. Lepisma saccharina, Ctenolepisma urbana, and Thermo-bia domestica,Pests from the class Chilopoda e.g. Geophilus spp., Scutigera spp. e.g. Scutigera coleoptrata-Pests from the class Diplopoda e.g. Blaniulus guttulatus, Julus spp., Narceus spp.,Pests from the class Symphyla e.g. Scutigerella immaculata,Insects from the order Dermaptera, e.g. Forficula auricularia,Insects from the order Collembola, e.g. Onychiurus spp., e.g. Onychiurus armatus,Pests from the order Isopoda, e.g. Armadillidium vulgare, Oniscus asellus, Porcellio scaber, Insects from the order Phthiraptera, e.g. Damalinia spp., Pediculus spp. e.g. Pediculus hu-ma-nus capitis, Pediculus humanus corporis, Pediculus humanus humanus; Pthirus pubis, Haematopinus spp. e.g. Haematopinus eurysternus, Haematopinus suis; Linognathus spp. e.g.Linognathus vituli; Bovicola bovis, Menopon gallinae, Menacanthus stramineus and Soleno-potes capillatus, Trichodectes spp. ,Further pest species which may be controlled by compounds I include: from the Phylum Mol-lusca, class Bivalvia, e.g., Dreissena spp.; class Gastropoda, e.g., Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Pomacea canaliclata, Succinea spp.’ from the class of the helminths, e.g., Ancylostoma duodenale, Ancy-lostoma ceylanicum, Acylostoma braziliensis, Ancylostoma spp., Ascaris lubricoides, Ascaris spp., Brugia malayi, Brugia timori, Bunostomum spp., Chabertia spp., Clonorchis spp., Cooperia spp., Dicrocoelium spp., Dictyocaulus filaria, Diphyllobothrium latum, Dracunculus medinensis, Echinococcus granulosus, Echinococcus multilocularis, Enterobius vermicularis, Faciola spp., Haemonchus spp. e.g. Haemonchus contortus; Heterakis spp., Hymenolepis nana, Hyostrongu-lus spp., Loa Loa, Nematodirus spp., Oesophagostomum spp., Opisthorchis spp., Onchocerca volvulus, Ostertagia spp., Paragonimus spp., Schistosomen spp., Strongyloides fuel-leborni, Strongyloides stercora Ils, Stronyloides spp., Taenia saginata, Taenia solium, Trichinella spiralis, Trichinella nativa, Trichinella britovi, Trichinella nelson!, Trichinella pseudopsiralis, Tricho-strongulus spp., Trichuris trichuria, Wuchereria bancrofti.The compounds of the invention are particularly suitable for efficiently combatinginsects from the sub-order of Auchenorrhyncha, e.g. Amrasca biguttula, Empoasca spp., Ne-photetix virescens, Sogatella furcifera, Mahanarva spp., Laodelphax striatellus, Nilapar-vata lugens, Diaphorina citri, Lycorma delicatula, Pentastiridus leporinus- Lepidoptera, e.g. Helicoverpa spp., Heliothis virescens, Lobesia botrana, Ostrinia nubilalis, Plu-tella xylostella, Pseudoplusia includens, Scirpophaga incertulas, Spodoptera spp., Trichoplusia ni, Tuta absoluta, Cnaphalocrocis medians, Cydia pomonella, Chilo suppressalis, Anticarsia gemmatalis, Agrotis ipsilon, Chrysodeixis includens-25041737True bugs, e.g. Lygus spp., Stink bugs such as Euschistus spp., Halyomorpha halys, Nezara viridula, Piezodorus guildinii, Dichelops furcatus:Thrips, e.g. Frankliniella spp., Thrips spp., Dichromothrips corbettii;Aphids, e.g. Acyrthosiphon pisum, Aphis spp., Myzus persicae, Rhopalosiphum spp., Schizaphis graminum, Megoura viciae;Whiteflies, e.g. Trialeurodes vaporariorum, Bemisia spp.;Coleoptera, e.g. Phyllotreta spp., Melanotus spp., Meligethes aeneus, Leptinotarsa decimline-ata, Ceutorhynchus spp., Diabrotica spp., Anthonomus grandis, Atomaria linearia, Agriotes spp., Epilachna spp.’Flies, e.g. Delia spp., Ceratitis capitate, Bactrocera spp., Liriomyza spp.’Coccoidea, e.g. Aonidiella aurantia, Ferrisia virgate:Anthropods of class Arachnida (Mites), e.g. Penthaleus major, Tetranychus spp. ’In some embodiments the mixture of sulfur and at least one terpene, selected from the group comprising limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, preferably at least one terpene is limonene, more preferred at least one terpene is D-limonene has a synergistic effect for controlling the phytopathogenic insect or arachnid of interest.Preferably the weight / weight ratio ofa) the amount of sulfur to the combined amounts of the terpenes, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, is between 30 to 1 and 10 to 1 , or between 25 to 1 and 10 to 1 , or between 25 to 1 and 12 to 1 , or between 24 to 1 and 8 to 1 , or between 24 to 1 and 10 to 1 , or between 24 to 1 and 12 to 1 , orb) the amount of sulfur to the amount of limonene, preferably D-limonene, is between 30 to 1 and 10 to 1 , or between 25 to 1 and 10 to 1 , or between 25 to 1 and 12 to 1 , or between 24 to 1 and 8 to 1 , or between 24 to 1 and 10 to 1 , or between 24 to 1 and 12 to 1.Preferably the insect species is selected from aphids, whiteflies, trips, mealybugs and scale insects, preferably from the genus Acyrthosiphon, Aphis, Rhopalosiphum, Schizaphis and Megoura. Preferably from the species, Acyrthosiphon pisum, Aphis fabae, Myzus persicae, Rhopalosiphum padi, Schizaphis graminum and Megoura viciae.In one embodiment the insect species is selected from whiteflies, preferably from the genus Trialeurodes and Bemisia, preferably from the species Trialeurodes vaporariorum, Bemisia tabacr',In one embodiment the insect species is selected from mealybugs, preferably from the genus Pianococcus or Pseudococcus, preferably from the species Pianococcus citri, Pseudococcus maritimus, Pseudococcus longispinus, and Pseudococcus elisae.Preferably the arachnid species is a mite species selected from the genus Penthaleus, Tetranychus, Panonychus, Eutetranychus or Phyllocoptruta, preferably selected from the species Penthaleus major, Tetranychus urticae, Panonychus citri, Panonychus ulmi, Panonychus citri, Eutetranychus orientalis, Eutetranychus banksi, Eutetranychus africanus and Phyllocoptruta oleivora.In one embodiment the mixtures are used to control at least one of the species, selected from Oscinella frit, Delia coarctata, Haplodiplosis marginata, Chlorops pumilionis, Hydrellia griseola, Oulema lichenis, Oulemamelanopus, Cnephasia pumicana, Cnephasia longana, Sitobion avenae, Metopolophium dirhodum, Rhopalosiphum padi, Rhopalosiphum maidis, Contarinia tritici and Sitodiplosis mosellana,25041738In one embodiment the mixtures are used to control at least one of the species, selected from Limothrips, Haplothrips, and Stenothrips.Another embodiment of the invention is the use of an effective amount of a spraying solution comprising a mixture of sulfur and at least one terpene, selected from the group comprising limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, for controlling phy-topathogenic insects or arachnids or both.Preferably at least one terpene is limonene, more preferred at least one terpene is D-limonene, even more preferred, the amount of limonene is at least 90% or at least 95%, or at least 98%, or at least 99%, of the total amount of the terpenes present.Preferably the weight / weight ratio ofa) the amount of sulfur to the combined amounts of the terpenes, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, is between 30 to 1 and 10 to 1 , or between 25 to 1 and 10 to 1 , or between 25 to 1 and 12 to 1 , or between 24 to 1 and 8 to 1 , or between 24 to 1 and 10 to 1 , or between 24 to 1 and 12 to 1 , orb) the amount of sulfur to the amount of limonene, preferably D-limonene, is between 30 to 1 and 10 to 1 , or between 25 to 1 and 10 to 1 , or between 25 to 1 and 12 to 1 , or between 24 to 1 and 8 to 1 , or between 24 to 1 and 10 to 1 , or between 24 to 1 and 12 to 1.Preferably the insect species to be controlled is selected from aphids, whiteflies, trips, mealybugs and scale insects, preferably from the genus Acyrthosiphon, Aphis, Rhopalosiphum, Schi-zaphis and Megoura. Preferably from the species, Acyrthosiphon pisum, Aphis fabae, Myzus persicae, Rhopalosiphum padi, Schizaphis graminum and Megoura viciae.In one embodiment the insect species to be controlled is selected from whiteflies, preferably from the genus Trialeurodes and Bemisia, preferably from the species Trialeurodes vaporario-rum, Bemisia tabaci;In one embodiment the insect species to be controlled is selected from mealybugs, preferably from the genus Pianococcus or Pseudococcus, preferably from the species Pianococcus citri, Pseudococcus maritimus, Pseudococcus longispinus, and Pseudococcus elisae.Preferably the arachnid species to be controlled is a mite species selected from the genus Pen-thaleus, Tetranychus, Panonychus, Eutetranychus or Phyllocoptruta, preferably selected from the species Penthaleus major, Tetranychus urticae, Panonychus citri, Panonychus ulmi, Panonychus citri, Eutetranychus orientalis, Eutetranychus banks!, Eutetranychus africanus and Phyllocoptruta oleivora.In one embodiment the mixtures are used to control at least one of the species, selected from Oscinella frit, Delia coarctata, Haplodiplosis marginata, Chlorops pumilionis, Hydrellia griseola, Oulema lichenis, Oulemamelanopus, Cnephasia pumicana, Cnephasia longana, Sitobion avenae, Metopolophium dirhodum, Rhopalosiphum padi, Rhopalosiphum maidis, Contarinia tritici and Sitodiplosis mosellana,In one embodiment the mixtures are used to control at least one of the species, selected from Limothrips, Haplothrips, and Stenothrips.The mixtures may be combined with biopesticides. The biopesticides may be added to the mixtures as a tank mix to prepare the spraying suspensions or may be directly added as integral part of the agrochemical formulation comprising the mixtures. Alternatively, the biopesticides can be applied to the fungi, the plant or the plant parts to be protected against fungal attack shortly before or after the spraying suspension comprising the mixtures is applied.25041739The following list of biopesticides can be used in combination with the mixtures described herein. The list is intended to illustrate the possible combinations but does not limit them:BiopesticidesL1) Microbial pesticides with fungicidal, bactericidal, viricidal and / or plant defense activator activity: Ampelomyces quisqualis, Aspergillus flavus, Aureobasidium pullulans, Bacillus altitudinis, B. amyloliquefaciens, B. amyloliquefaciens ssp. plantarum (also referred to as B. velezensis), B. megaterium, B. mojavensis, B. mycoides, B. pumilus, B. simplex, B. solisalsi, B. subtilis, B. subtilis var. amyloliquefaciens, B. velezensis, Candida ole- ophila, C. saitoana, Clavibacter michiganensis (bacteriophages), Coniothyrium minitans, Cryphonectria parasitica, Cryptococcus albidus, Dilophosphora alopecuri, Fusarium oxysporum, Clonostachys rosea f. catenulate (also named Gliocladium ca- tenulatum), Gliocladium roseum, Lysobacter antibioticus, L. enzymogenes, Metschni- kowia fructicola, Microdochium dimerum, Microsphaeropsis ochracea, Muscodor albus, Paenibacillus alvei, Paenibacillus epiphyticus, P. polymyxa, Pantoea vagans, Penicil- lium bilaiae, Phlebiopsis gigantea, Pseudomonas sp., Pseudomonas chloraphis, Pseudozyma flocculosa, Pichia anomala, Pythium oligandrum, Sphaerodes mycopara- sitica, Streptomyces griseoviridis, S. lydicus, S. violaceusniger, Talaromyces flavus, Trichoderma asperelloides, T. asperellum, T. atroviride, T. fertile, T. gamsii, T. harma- tum, T. harzianum, T. polysporum, T. stromaticum, T. virens, T. viride, Typhula phacor- rhiza, Ulocladium oudemansii, Verticillium dahlia, zucchini yellow mosaic virus (aviru- lent strain);L2) Biochemical pesticides with fungicidal, bactericidal, viricidal and / or plant defense activator activity: harpin protein, Reynoutria sachalinensis extract;The methods for controlling phytopathogenic fungi described herein do not include the prophylactic or therapeutic treatment of the animal or human body.Typically, the mixtures are diluted with water to obtain spraying suspensions, which are then applied in the methods for controlling phytopathogenic fungi.Preferably the mixtures are comprised in agrochemical formulations, which are then diluted with water to prepare the spraying suspensions.Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs.ExamplesThe present invention will be described in greater detail by means of the following examples. The following examples are for illustrative purposes and are not intended to limit the scope of the invention.Example 1 :Preparation of Sulfur + Orange oil suspoemulsions:To a stirred solution of dispersing and wetting agents in water, crystalline sulfur in powder form was added slowly. After complete wetting of the sulfur, the mixture was further stirred until a homogenous, coarse suspension was obtained. Then, this was passed over a bead mill in25041740circulation mode until the desired particle size distribution was obtained. To this suspension, the water soluble adjuvants were added under stirring. After all had been added, stirring was continued for 5 minutes, then antifreeze and the thickener were added and stirring was continued for another 2 hours until the thickener got activated. This suspension premix was set aside until the organic oil phase comprising the orange oil was prepared.In a separate beaker, the necessary amount of orange oil was weighed in, followed by emulsifiers and if required additionally vegetable oil. Everything was stirred until a homogenous solution, the orange oil phase, was obtained.In the next step, the previously prepared orange oil phase was poured slowly into the stirred suspension premix from above. After the addition was completed, stirring was continued for 10 minutes, then the complete coarse suspoemulsion was passed as a single pass over a colloid mill (rotor-startor mill). The obtained fine suspoemulsion was checked for particle size distribution and continued to stir while adding the residual amount of antifreeze and the biocides. Active ingredient assay was checked and corrected if necessary to achieve the final suspoemulsion. The such obtained samples were submitted to accelerated storage protocols and then measured again for particle size distribution using a static light scattering device.Table 1 (not performing formulations)Formulation 1 2 3 4 5 6 8 9 13 Sulfur 600 600 600 600 600 600 600 600 600 Limonene 50 30 50 50 50 50 50 50 50 Soprophor BSU 75 75 25 16 16 24 Lutensit A-BO 21 21 21 37 37 71 21 37 33 Morwet D-425 21 21 21 21 21 21 50 77,5 45 Lutensol XP 80 75 75 25 42 Lutensol ON 60 50 50 Carrier oilAnti freeze 35 35 35 35 35 35 35 35 35 Thickener 1,4 1,4 2 Biocides 3 3 3 3 3 3 3 3 3 Antifoam 5 5 5 5 5 5 5 5 5 EmulsifiersWetting agent 16water ad 1 ad 1 ad 1 L ad 1 ad 1 L ad 1 ad 1 ad 1 ad 1 L L L L L L LAppearance after solid solid solid solid solid solid solid solid solidpreparation“solid” means that formulation becomes highly viscous during or directly after preparation and cannot be further analysed.Table 2 (performing formulations)Formula7 10 11 12 14 15 16 17 18 19 tionSulfur 600 600 600 600 600 600 600 600 600 600Limonene 50 50 50 50 50 50 50 50 50 25 Sopro- 16 16 25 25 24 16 8 24 25 23 phor BSULutensit 37 37 31 31 33 29 25 33 21 32 A-BOMorwet 55 55 55 55 55 55 55 55 21 45 D-425Lutensol 25 40 42 28 14 50 40 41 XP 80LutensolON 60carrier oil 50 25 Antifreeze 35 35 35 35 35 35 35 35 35 35 Thickener 0,7 0,7 0,7 2 2,5 3 2 1 1,5 Biocides 3 3 3 3 3 3 3 3 3 3 Antifoam 5 5 5 5 5 5 5 5 5 5 Emulsifi11 11 ersWettingagentwater ad 1 ad 1 ad 1 ad 1 ad 1 ad 1 ad 1 ad 1 ad 1 ad 1L L L L L L L L L LAppearan ok ok ok ok ok ok ok ok ok ok ce afterpreparationviscosity 145 179 191 221 158 [100 s-1]mPasAppearan ok ok ok ce afterstorage% Vol < 6,71 6,76 0,991 pm,initial% Vol > 0,34 0,36 9,86 pm,initialD90 [pm], 2,65 2,69 initial% Vol < 3,46 6,22 0,991 pm,% Vol > 0 0 9,86 pm,1W40CD90 [pm], 4,34 2,61W40C1 W40C means 1 week of storage at 40°C.

Claims

43Claims:

1. A suspension concentrate or suspoemulsion formulation comprising:a) 400 to 800 grams / liter of sulfurb) 10 to 70 grams / liter of one or more terpenes, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol,c) 5 to 30 grams / liter of one or more polyalkoxylated arylalkylphenolsd) 20 to 40 grams / liter of one or more sulphosuccinatese) 10 to 60 grams / liter of one or more alkyl naphthalene sulfonatesf) optionally 10 to 60 grams / liter of one or more propoxylated and / or ethoxylated Guerbet alcohol alkoxylatesg) optionally 10 to 100 grams / liter of one or more carrier oils andg) optionally further components,with the proviso, that if the suspension concentrate or suspoemulsion formulation comprises less than 50 grams / liter of one or more alkyl naphthalene sulfonates the suspension concentrate or suspoemulsion formulation comprises 10 to 100 grams / liter of one or more carrier oils.

2. A suspension concentrate or suspoemulsion formulation as claimed in claim 1 , comprising:a) 500 to 700 grams / liter of sulfurb) 20 to 70 grams / liter of one or more terpenes, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol,c) 5 to 25 grams / liter of one or more polyalkoxylated arylalkylphenols,d) 20 to 40 grams / liter of one or more sulphosuccinates,e) 20 to 60 grams / liter of one or more alkyl naphthalene sulfonates,f) optionally 10 to 60 grams / liter of one or more propoxylated and / or ethoxylated Guerbet alcohol alkoxylatesg) optionally 20 to 80 grams / liter of one or more carrier oils andg) optionally further components,with the proviso, that if the suspension concentrate or suspoemulsion formulation comprises less than 50 grams / liter of one or more alkyl naphthalene sulfonates the suspension concentrate or suspoemulsion formulation comprises 20 to 80 grams / liter of one or more carrier oils.

3. A suspension concentrate or suspoemulsion formulation as claimed in claim 1 or 2, wherein the weight / weight ratio of sulfur to the combined amount of all terpenes, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, is between 24 to 1 and 12 to 1.

4. A suspension concentrate or suspoemulsion formulation as claimed in any one of claims 1 to 3, comprising one or more carrier oils, wherein the weight / weight ratio of the combined amount of all carrier oils to the combined amount of all terpenes, selected from limonene, terpinene, pinene, p-cymene, eugenol, geraniol, thymol and carvacrol, is between 2:1 to 1 to 2.250417445. A suspension concentrate or suspoemulsion formulation as claimed in any one of claims 1 to 4, wherein at least one selected terpene is limonene.

6. A suspension concentrate or suspoemulsion formulation as claimed in any one of claims 1 to 5, wherein the weight / weight ratio of limonene to the combined amount other terpenes is 90 to 1 or higher.

7. A method for controlling phytopathogenic fungi comprising contacting the fungi, the plant or the plant parts to be protected against fungal attack with a fungicidally effective amount of a spraying solution prepared from the suspension concentrate or suspoemulsion as claimed in any one of claims 1 to 6.

8. A method for controlling phytopathogenic fungi as claimed in claim 7, wherein the fungi to be controlled are selected from the genera Puccinia, Erysiphe, Blumeria, Podosphaera, Septoria, Cercospora, Sclerotinia, Pyrenophora, Ramularia, Fusarium, Venturia, and Dip- locarpon.

9. A method for controlling phytopathogenic insects or arachnids or both, comprising contacting the insects and or arachnids or both, the plant or the plant parts to be protected against insect or arachnid attack with an effective amount of a spraying solution prepared from the suspension concentrate or suspoemulsion as claimed in any one of claims 1 to 6.

10. A method as claimed in claim 9, wherein the insects or arachnids are selected from aphids, whiteflies, trips, mealybugs, scale insects and mites.

11. A method as claimed in claim 9 or 10, wherein at least one arachnid species selected from the genus Penthaleus, Tetranychus, Panonychus, Eutetranychus or Phyllocoptruta is controlled.

12. The use of a suspension concentrate or suspoemulsion formulation as claimed in any one of claims 1 to 6 to control phytopathogenic fungi.

13. The use of a suspension concentrate or suspoemulsion formulation as claimed in any one of claims 1 to 6 to control at least one phytopathogenic insect or arachnid species.

14. The use as claimed in claim 12 or 13, wherein the mixture, suspension concentrate or suspoemulsion formulation comprises limonene in a weight / weight ratio of sulfur to limonene between 24 to 1 and 12 to 1.

15. The use as claimed in claim 12, wherein at least one fungus species to be controlled is selected from Puccinia triticina, Puccinia striiformis, Erysiphe graminis, Septoria tritici, Cercospora beticola, Cercospora sojina, Sclerotinia sclerotiorum, Ramularia collo-cygni, Fusarium graminearum, Pyrenophora teres and Venturia inequalis.

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