Composition, surface treatment agent, article, and method for producing article

Abstract

Provided are: a composition capable of forming a surface layer having excellent water sliding properties and abrasion resistance; a surface treatment agent; an article having a surface layer formed from the composition; and a method for producing the article. A composition according to the present invention comprises: a first compound selected from compounds represented by Aa1-La1-Qa1-(Ta1)ma1 and (Ta1)ma1-Qa1-La2-Qa1-(Ta1)ma1; and a second compound selected from compounds represented by (Rf1)nb1-Qb1-(Tb1)mb1 and (Tb1)mb1-Qb2-Rf2-Qb2-(Tb1)mb1. Aa1 represents an alkyl group or the like, La1 represents a chain group, La2 represents a chain group not including a fluorine atom, Qa1 represents a single bond or the like, Ta1 represents a group including a reactive silyl group, Rf1 represents a group including a fluoropolyether chain, Rf2 represents a fluoropolyether chain, Qb1 represents a linking group, Qb2 represents a linking group, Tb1 represents a group including a reactive silyl group, and ma1, nb1, and mb1 are each at least 1.

Description

Composition, surface treatment agent, article, and method for manufacturing article

[0001] This disclosure relates to compositions, surface treatment agents, articles, and methods for manufacturing articles.

[0002] In recent years, technologies that make optical articles less prone to fingerprints and easier to clean have become widespread in eyeglass lenses, wearable devices, touch panel displays, and other devices to improve their appearance and visibility. One specific method for applying these technologies to improve the appearance, visibility, and other performance aspects of these devices is to form a surface layer on the surface of the article using a surface treatment agent. The use of materials with such surface layers is expected to contribute to achieving Goal 12 of the United Nations' Sustainable Development Goals (SDGs), "Responsible Consumption and Production," as it leads to a longer product lifecycle and, consequently, a reduction in waste.

[0003] For example, Patent Document 1 describes a method for forming a surface layer on the surface of a substrate using a surface treatment agent containing a perfluoropolyether compound represented by the following formula.

[0004]

[0005] International Publication No. 2018 / 056413

[0006] In recent years, the performance requirements for surface layers have increased, and depending on the application, surface layers with excellent water-repellent and abrasion-resistant properties are required. Here, water-repellent properties refer to the property of water adhering to the surface layer to easily fall off. When the present inventors evaluated a surface layer formed using the above compound described in Patent Document 1, they found that the water-repellent properties of the surface layer were insufficient and that there was room for improvement.

[0007] This disclosure has been made in view of these circumstances and aims to provide a composition capable of forming a surface layer with excellent water-repellent and abrasion-resistant properties, a surface treatment agent, an article having a surface layer formed from the composition, and a method for manufacturing the article.

[0008] As a result of intensive studies on the above problem, the present inventors have found that the above problem can be solved by the following constitution. [1] A composition comprising: a first compound selected from the group consisting of a compound represented by formula (1-1) and a compound represented by formula (1-2); and a second compound selected from the group consisting of a compound represented by formula (2-1) and a compound represented by formula (2-2). A ａ１ -L ａ１ -Q ａ１ -(T ａ１ ) ｍａ１ (1-1) (T ａ１ ) ｍａ１ -Q ａ１ -L ａ２ -Q ａ１ -(T ａ１ ) ｍａ１ (1-2) Provided that: A ａ１ is an alkyl group, or a group containing at least one selected from Si, Ge and Sn and having no reactive silyl group, L ａ１ is a chain group, and L ａ２ is a chain group containing no fluorine atom, Q ａ１ is a single bond or a (ma1+1)-valent group, T ａ１ is a group containing a reactive silyl group, and ma1 is an integer of 1 or more. (R ｆ１ ) ｎｂ１ -Q ｂ１ -(T ｂ１ ) ｍｂ１ (2-1) (T ｂ１ ) ｍｂ１ -Q ｂ２ -R ｆ２ -Q ｂ２ -(T ｂ１ ) ｍｂ１ (2-2) Provided that: R ｆ１ is a group containing a fluoropolyether chain and having no reactive silyl group, R ｆ２ is a divalent fluoropolyether chain, Q ｂ１ is a (nb1+mb1)-valent linking group, Q ｂ２ is a (mb1+1)-valent linking group, T ｂ１is a group containing a reactive silyl group, nb1 is an integer of 1 or more, and mb1 is an integer of 1 or more. [2] In the above formulas (2-1) and (2-2), T ｂ１ However, the composition described in [1] is a group represented by the following formula (TB). ｂ１ -[Si(R ｂ１ ) ２ - Q ｂ３ ] ｒｂ１ -Si(R ｂ１ ) ３ (TB) However, R ｂ１ Each of these is independently a hydrolyzable group, a group having a hydrolyzable group, a hydroxyl group, or a hydrocarbon group, R ｂ１ At least one of them is a hydrolyzable group, a group having a hydrolyzable group, or a hydroxyl group, Q ｂ３ is an oxygen atom, or -CR ｂ２ ２ - and R ｂ２ is a hydrogen atom or hydrocarbon group, rb1 is an integer from 0 to 3, * ｂ１ Q ｂ１ Or Q ｂ２ It is the bonding position with. [3] The composition according to [1] or [2], wherein mb1 in formula (2-1) and formula (2-2) is 1. [4] The first compound comprises the compound represented by formula (1-1), wherein A in formula (1-1) ａ１ The composition according to any one of [1] to [3], wherein the group is represented by formula (A1), formula (A2), or formula (A3). ａ２１ ３ M-(Q) ａ１１ ) ｚａ１ - (R ａＳｉ ) ｚａ２ - (A1) However, R ａ２１ Each of these independently comprises a hydrocarbon group, or R ｂ２１ ３ M-R ｂ２２ - and R ｂ２１ Each of these independently comprises a hydrocarbon group, or R ｃ２１ ３ M-R ｃ２２ - and R ｃ２１each independently represents a hydrocarbon group, or R ｄ２１ ３ M-R ｄ２２ -, and R ｄ２１ each independently represents a hydrocarbon group, or R ｅ２１ ３ M-R ｅ２２ -, and R ｅ２１ each independently represents a hydrocarbon group, and R ｂ２２ , R ｃ２２ , R ｄ２２ , R ｅ２２ each independently represents an oxygen atom or an alkylene group having 1 to 6 carbon atoms, and R ａ２４ each independently represents a hydrocarbon group, or R ｂ２１ ３ M-R ｂ２２ -, and ta11 is an integer of 1 to 5, and R ａ２５ each independently represents a hydrocarbon group, or R ｂ２１ ３ M-R ｂ２２ -, and each M is independently Si, and Q ａ１１ is -O-, -C(=O)-, or an alkylene group having 1 to 6 carbon atoms, za1 is 0 or 1, za2 is 0 or 1, and R ａＳｉ is a group represented by the following formula (RSi). -(SiR ａ４１ ２ O) ｓａ４１ -SiR ａ４１ ２ - (RSi) with the proviso that R ａ４１ each independently represents a hydrocarbon group, and sa41 is a number of 0 or more. [5] The composition according to any one of [1] to [4], wherein the first compound comprises a compound represented by the formula (1-1), and L in the formula (1-1) ａ１ comprises a group represented by formula (LD), -(CR ａ１３ ２ ) ｓａ４ - (LD) with the proviso that R ａ１３Each of these is independently a hydrogen atom or a hydrocarbon group which may have an ether bond between carbon atoms, and sa4 is an integer from 1 to 200. [6] In the above formulas (1-1) and (1-2), T ａ１ However, the composition is one of the following [1] to [5], wherein the group is represented by the following formula (TA). ａ１ -[Si(R ａ１ ) ２ -Q ａ１３ ] ｒａ１ -Si(R ａ１ ) ３ (TA) However, R ａ１ Each of these is independently a hydrolyzable group, a group having a hydrolyzable group, a hydroxyl group, or a hydrocarbon group, R ａ１ At least one of them is a hydrolyzable group, a group having a hydrolyzable group, or a hydroxyl group, Q ａ１３ is an oxygen atom, or -CR ａ２ ２ - and R ａ２ is a hydrogen atom or hydrocarbon group, ra1 is an integer from 0 to 3, * ａ１ Q ａ１ [7] The bonding position with [1] to [6]. [8] A surface treatment agent comprising the composition according to any one of [1] to [7]. [9] The surface treatment agent according to [8] further comprising a liquid medium.

[10] The surface treatment agent according to [8] or [9], which is an antifouling coating agent or a waterproof coating agent.

[11] An article having a surface layer formed using the surface treatment agent according to any one of [8] to

[10] on the surface of a substrate.

[12] The article according to

[11] , which is an optical member.

[13] The article according to

[11] or

[12] , which has the above surface layer on the surface of a member constituting the surface touched by a finger on a touch panel.

[14] A method for manufacturing an article, comprising forming a surface layer by a dry coating method using the surface treatment agent according to any one of [8] to

[10] .

[15] A method for manufacturing an article, comprising forming a surface layer by a wet coating method using the surface treatment agent according to [8] to

[10] .

[0009] This disclosure provides a composition capable of forming a surface layer with excellent water-repellent and abrasion-resistant properties, a surface treatment agent, an article having a surface layer formed from the composition, and a method for manufacturing the article.

[0010] This is a schematic cross-sectional view showing an example of an article in this disclosure.

[0011] The embodiments for carrying out the embodiments of this disclosure will be described in detail below. However, the embodiments of this disclosure are not limited to the embodiments described below. In the embodiments described below, the components (including elemental steps, etc.) are not essential unless otherwise specified. The same applies to numerical values ​​and their ranges, and do not limit the embodiments of this disclosure.

[0012] In this disclosure, numerical ranges indicated using "~" include the numbers before and after "~" as the minimum and maximum values, respectively. In numerical ranges described in stages in this disclosure, the upper or lower limit of one numerical range may be replaced with the upper or lower limit of another numerical range described in stages. Also, in numerical ranges described in this disclosure, the upper or lower limit of that numerical range may be replaced with the values ​​shown in the examples. In this disclosure, each component may contain multiple types of the corresponding substance. If multiple types of the substance corresponding to each component are present in the composition, the content or amount of each component means the total content or amount of the multiple types of substances present in the composition, unless otherwise specified. In this disclosure, "surface layer" means a layer formed on the surface of a substrate using a surface treatment agent. In this disclosure, when a compound or group is represented by a specific formula (X), the compound or group represented by formula (X) may be written as compound (X) or compound X, and group (X) or group X, respectively. In this disclosure, "Me" may mean a methyl group, and "Et" may mean an ethyl group. In this disclosure, if there are multiple identical symbols in a single chemical formula, those identical symbols may represent the same structure, or they may represent different structures within a defined range.

[0013] In this disclosure, "fluoroalkyl group" is a general term encompassing both perfluoroalkyl groups and partial fluoroalkyl groups. "Perfluoroalkyl group" refers to a group in which all hydrogen atoms of the alkyl group are replaced with fluorine atoms. "Partial fluoroalkyl group" refers to an alkyl group in which one or more hydrogen atoms are replaced with fluorine atoms and which has one or more hydrogen atoms. In other words, a fluoroalkyl group is an alkyl group having one or more fluorine atoms. Fluoroalkylene groups are also similar. In this disclosure, "organic group" refers to a hydrocarbon group that may have substituents and may have heteroatoms or other bonds in its carbon chain. "Hydrogen group" refers to an aliphatic hydrocarbon group (linear alkylene group, branched alkylene group, cycloalkylene group, etc.), an aromatic hydrocarbon group (phenylene group, etc.), or a group consisting of a combination thereof. In this disclosure, "number-average molecular weight" (Mn) is a value measured by size exclusion chromatography (gel permeation chromatography) using polystyrene as a standard substance.

[0014] [Composition] The composition of the present disclosure (hereinafter also referred to as "the composition") comprises a first compound selected from the group consisting of a compound represented by formula (1-1) and a compound represented by formula (1-2) described later, and a second compound selected from the group consisting of a compound represented by formula (2-1) and a compound represented by formula (2-2) described later.

[0015] When this composition is used as a surface treatment agent, a surface layer with excellent water-repellent properties and abrasion resistance can be formed. This is because, by using a composition containing both a first compound that can impart excellent water-repellent properties to the surface layer and a second compound that can impart excellent abrasion resistance to the surface layer, the performance of both compounds is balanced, resulting in a surface layer with excellent water-repellent and abrasion-resistant properties.

[0016] <First Compound> The first compound is selected from the group consisting of compounds represented by the following formula (1-1) and compounds represented by the following formula (1-2).

[0017] A ａ１ -Lａ１ -Q ａ１ - (T ａ１ ) ｍａ１ (1-1) (T ａ１ ) ｍａ１ -Q ａ１ -L ａ２ -Q ａ１ - (T ａ１ ) ｍａ１ (1-2)

[0018] However, A ａ１ L is a group that comprises an alkyl group or one or more selected from Si, Ge, and Sn, and does not have a reactive silyl group. ａ１ L is a chain-like group. ａ２ Q is a chain group that does not contain fluorine atoms. ａ１ is a single bond or a (ma1+1) valence group, T ａ１ is a group containing a reactive silyl group, and ma1 is an integer greater than or equal to 1.

[0019] A ａ１ The alkyl group may be a linear alkyl group, a branched alkyl group, or a cyclic alkyl group. From the viewpoint of improving liquid repellency, a linear alkyl group or a branched alkyl group is preferred. The number of carbon atoms in the alkyl group is preferably 1 to 10, more preferably 1 to 6, and even more preferably 1 to 4. Specific examples of alkyl groups include a methyl group, an ethyl group, an n-propyl group, an n-butyl group, and a tert-butyl group. From the viewpoint of further improving liquid repellency, a methyl group, an ethyl group, or a tert-butyl group is preferred, and a methyl group is more preferred.

[0020] A ａ１ Examples of groups that include one or more selected from Si, Ge, and Sn and do not have a reactive silyl group include the groups represented by the following formulas (A1) to (A3). ａ２１ ３ M-(Q) ａ１１ ) ｚａ１ - (R ａＳｉ ) ｚａ２ - (A1)

[0021]

[0022] However, R ａ２１ Each of these independently comprises a hydrocarbon group, or R ｂ２１ ３ M-R ｂ２２ - and R ｂ２１ Each of these independently comprises a hydrocarbon group, or R ｃ２１ ３ M-R ｃ２２ - and R ｃ２１ Each of these independently comprises a hydrocarbon group, or R ｄ２１ ３ M-R ｄ２２ - and R ｄ２１ Each of these independently comprises a hydrocarbon group, or R ｅ２１ ３ M-R ｅ２２ - and R ｅ２１ Each of these is independently a hydrocarbon group, and R ｂ２２ , R ｃ２２ , R ｄ２２ , R ｅ２２ Each is independently an oxygen atom or an alkylene group having 1 to 6 carbon atoms, R ａ２４ Each of these independently comprises a hydrocarbon group or R ｂ２１ ３ M-R ｂ２２ - and ta11 is an integer from 1 to 5, R ａ２５ Each of these independently comprises a hydrocarbon group or R ｂ２１ ３ M-R ｂ２２ - and M is independently Si, Ge, or Sn, Q ａ１１ is -O-, -C(=O)-, or an alkylene group having 1 to 6 carbon atoms, za1 is 0 or 1, za2 is 0 or 1, R ａＳｉ This is a group represented by the following formula (RSi): -(SiR ａ４１ ２ O) ｓａ４１ -SiR ａ４１ ２ - (RSi) R ａ４１ Each of these is independently a hydrocarbon group, and sa41 is a number greater than or equal to 0.

[0023] R ａ２１ , R ｂ２１ , R ｃ２１ , Rｄ２１ , R ｅ２１ , R ａ２４ , R ａ２５ and R ａ４１ The hydrocarbon group in this material can be an aliphatic hydrocarbon group or an aromatic hydrocarbon group, with an aliphatic hydrocarbon group being preferred and an alkyl group being more preferred. The alkyl group may be a linear alkyl group, a branched alkyl group, or a cyclic alkyl group. From the viewpoint of improving liquid repellency, a linear alkyl group or a branched alkyl group is preferred. The number of carbon atoms in the hydrocarbon group is preferably 1 to 10, more preferably 1 to 6, and even more preferably 1 to 4. Specific examples of hydrocarbon groups include a methyl group, an ethyl group, an n-propyl group, an n-butyl group, and a tert-butyl group, with a methyl group or an ethyl group being preferred, and a methyl group being more preferred, from the viewpoint of further improving liquid repellency.

[0024] R ｂ２２ , R ｃ２２ , R ｄ２２ , R ｅ２２ and Q ａ１１ In this formula, linear alkylene groups with 1 to 6 carbon atoms are preferred. Specific examples of alkylene groups with 1 to 6 carbon atoms include methylene, ethylene, propylene, butylene, pentylene, and hexylene groups.

[0025] ta11 is MR ａ２４ ２ The number of repetitions of O is an integer from 1 to 5, preferably an integer from 1 to 3. M is Si, Ge, or Sn, preferably Si. sa41 is SiR ａ４１ ２ The number of repetitions of O is zero or greater, preferably 1 or greater, more preferably 1 to 600, even more preferably 2 to 500, and particularly preferably 8 to 50.

[0026] From equation (A1), (Q ａ１１ ) ｚａ１ - (R ａＳｉ ) ｚａ２ The following are specific examples of substructures excluding Q. However, * indicates Q ａ１１ , R ａＳｉ or L ａ１ This is the connection point.

[0027]

[0028] From equation (A2), (Q ａ１１ ) ｚａ１ - (R ａＳｉ ) ｚａ２ Specific examples of substructures excluding the following are listed below. However, * represents Q. ａ１１ , R ａＳｉ or L ａ１ This is the connection point.

[0029]

[0030] From equation (A3), (Q ａ１１ ) ｚａ１ - (R ａＳｉ ) ｚａ２ Specific examples of substructures excluding the following are listed below. However, * represents Q. ａ１１ , R ａＳｉ or L ａ１ This is the connection point.

[0031]

[0032] A ａ１ Preferably, the group is represented by formula (A1), the group is represented by formula (A2), or the group is represented by formula (A3), where M is independently Si, and more preferably, the group represented by each formula is in the above preferred form.

[0033] L ａ１ The chain group in, and L ａ２ Examples of fluorine-free chain groups in this context include one or more combinations selected from the groups represented by the following formulas (LA) to (LD): -(SiR ａ１１ ２ O) ｓａ１ -SiR ａ１１ ２ - (LA) - (SiR ａ１１ ２ -R ａ１２ ) ｓａ２ -SiR ａ１１ ２ - (LB) -(SiR ａ１１ ２ -R ａ１２ O)ｓａ３ -SiR ａ１１ ２ - (LC) - (CR ａ１３ ２ ) ｓａ４ - (LD) However, R ａ１１ Each of these is independently a monovalent hydrocarbon group or organopolysiloxane residue which may have an ether bond between carbon atoms, and R ａ１２ Each of these is independently a divalent hydrocarbon group which may have an ether bond between carbon atoms, and R ａ１３ Each of these is independently a hydrogen atom or a monovalent hydrocarbon group which may have an ether bond between carbon atoms, and each of sa1, sa2, and sa3 is independently a number from 1 to 200. Sa4 is an integer from 1 to 200.

[0034] R ａ１１ Among these, hydrocarbon groups are preferred, and alkyl groups are more preferred. The alkyl group may be a linear alkyl group, a branched alkyl group, or a cyclic alkyl group. From the viewpoint of improving liquid repellency, linear alkyl groups or branched alkyl groups are preferred. The number of carbon atoms in the hydrocarbon group is preferably 1 to 10, more preferably 1 to 6, and even more preferably 1 to 4. Specific examples of hydrocarbon groups include methyl groups, ethyl groups, n-propyl groups, n-butyl groups, and tert-butyl groups. From the viewpoint of further improving liquid repellency, methyl groups or ethyl groups are preferred, and methyl groups are more preferred. ａ１２ Among these, divalent hydrocarbon groups are preferred, and alkylene groups are more preferred. The alkylene group may be a linear alkylene group, a branched alkylene group, or a cyclic alkylene group. From the viewpoint of improving liquid repellency, linear alkylene groups or branched alkylene groups are preferred. The number of carbon atoms in the hydrocarbon group is preferably 1 to 10, more preferably 1 to 6, and even more preferably 1 to 4. ａ１３ R is preferably a hydrogen atom or a monovalent hydrocarbon group, and as a monovalent hydrocarbon group, ａ１１ The structure mentioned above is preferred. ａ１３Hydrogen atoms are more preferred. Sa1, Sa2, and Sa3 are each independently preferably 1 to 150, more preferably 1 to 100, and even more preferably 1 to 20. Sa4 is preferably 11 to 150, more preferably 21 to 100, and even more preferably 29 to 36, from the viewpoint of superior wear resistance.

[0035] L ａ１ The group is preferably represented by the following formulas (L1a) to (L1b): -Ak １ - (L1a) -Ak １ -R Ｓｉ -Ak １ - (L1b) However, Ak １ R is a group represented by the above formula (LD), Ｓｉ is a group represented by the above formula (LA) or a group represented by the above formula (LB). Among them, L ａ１ As such, the group represented by the above formula (LD) is more preferred because of its superior wear resistance, and R in formula (LD) ａ１３ Furthermore, if sa4 is the above-described preferred embodiment, it is even more preferable.

[0036] L ａ２ The group is preferably represented by the following formulas (L2a) to (L2c). -R Ｓｉ - (L2a) -Ak １ -R Ｓｉ -Ak １ - (L2b) -R Ｓｉ -Ak １ -R Ｓｉ - (L2c) However, Ak １ R is a group represented by the above formula (LD), Ｓｉ This is a group represented by the above formula (LA) or a group represented by the above formula (LB).

[0037] Q ａ１ In this, the (ma1+1) valence base is preferably the base represented by the following formula (QA). * ａ２ -Q ａ４ -R ａ３ -Q ａ５ (-R ａ４ - * ａ３ ) ｍａ１(QA) However, Q ａ４ R is a single bond or a divalent group. ａ３ Q is a hydrocarbon group which may have a single bond or an ether bond between carbon atoms. ａ５ R is a single bond or a (ma1+1) valence group. ａ４ is a hydrocarbon group which may have a single bond or an ether bond between carbon atoms, ma1 is an integer of 1 or more, * ａ２ is, L ａ１ or L ａ２ This is the bonding position with, * ａ３ is, T ａ１ This is the connection point.

[0038] Q ａ４ These are single bonds, -O-, -S-, -C(=O)NR ａ５ -, -NR ａ５ C(=O)-, -C(=O)-, -C(=O)O-, -OC(=O)-, -NR ａ５ C(=O)NR ａ５ -, -C(=O)S-, -SC(=O)-, -S(=O) ２ NR ａ５ -, -NR ａ５ S (=O) ２ -, -S (=O) ２ O-, -OS (=O) ２ - or a phenylene group is preferred. However, R ａ５ is a hydrogen atom or a hydrocarbon group.

[0039] Q ａ５ is a single bond, CR ａ６ ｍａ２ , NR ａ７ ｍａ３ , SiR ａ８ ｍａ４ A (ma1+1) valent ring structure, a (ma1+1) valent organopolysiloxane residue, or a (ma1+1) valent hydrocarbon residue is preferred. However, R ａ６ R is a hydrogen atom, a hydroxyl group, or a hydrocarbon group which may have an ether bond between carbon atoms. ａ７ and R ａ８m is a hydrogen atom, or a hydrocarbon group which may have an ether bond between carbon atoms, ma2 is an integer from 0 to 2 and the sum of ma1 and ma2 is 3, ma3 is 0 or 1 and the sum of ma1 and ma3 is 2, and ma4 is an integer from 0 to 2 and the sum of ma1 and ma4 is 3.

[0040] T ａ１ Examples of groups containing a reactive silyl group represented by the following formula (TA) include the group represented by the following formula. * ａ１ -[Si(R ａ１ ) ２ -Q ａ１３ ] ｒａ１ -Si(R ａ１ ) ３ (TA) However, R ａ１ Each of these is independently a hydrolyzable group, a group having a hydrolyzable group, a hydroxyl group, or a hydrocarbon group, R ａ１ At least one of them is a hydrolyzable group, a group having a hydrolyzable group, or a hydroxyl group, Q ａ１３ is an oxygen atom, or -CR ａ２ ２ - and R ａ２ is a hydrogen atom or hydrocarbon group, ra1 is an integer from 0 to 3, * ａ１ Q ａ１ This is the connection point.

[0041] A hydrolyzable group is a group that becomes a hydroxyl group through hydrolysis. Si-R ａ１ If the group represented is a silyl group having a hydrolyzable group, it undergoes a hydrolysis reaction to become a silanol group represented as Si-OH. The silanol groups further react with each other to form Si-O-Si bonds. In addition, silanol groups can undergo a dehydration condensation reaction with silanol groups derived from oxides present on the surface of the substrate to form Si-O-Si bonds.

[0042] R ａ１ Examples of hydrolyzable groups in this context include alkoxy groups, aryloxy groups, halogen atoms, acyl groups, acyloxy groups, amino groups, and -O-N=CR groups. ｒ ２and isocyanate groups (-NCO) are examples. The alkoxy group is preferably an alkoxy group having 1 to 4 carbon atoms. The aryloxy group is preferably an aryloxy group having 3 to 10 carbon atoms. However, the aryl group of the aryloxy group includes heteroaryl groups. The halogen atom is preferably a chlorine atom. The acyl group is preferably an acyl group having 1 to 6 carbon atoms. The acyloxy group is preferably an acyloxy group having 1 to 6 carbon atoms. R ｒ Each of these is independently an alkyl group having 1 to 10 carbon atoms.

[0043] R ａ１ Groups having hydrolyzable groups include groups in which the hydrolyzable group is bonded to a linking group. Examples of linking groups include alkylene groups, -O- groups, and combinations thereof. Examples of groups having hydrolyzable groups include alkoxyalkyleneoxy groups. Preferably, an alkoxyalkyleneoxy group is a group in which an alkoxy group having 1 to 4 carbon atoms is bonded to a carbon atom of an alkyleneoxy group having 1 to 10 carbon atoms. Specific examples of alkoxyalkyleneoxy groups include 2-methoxyethoxy groups. Among these, R ａ１ From the viewpoint of ease of compound production, an alkoxy group or halogen atom having 1 to 4 carbon atoms is preferred. ａ１ Because it exhibits less outgassing during application and superior storage stability of the compound, an alkoxy group having 1 to 4 carbon atoms is preferred, and an ethoxy group or a methoxy group is more preferred. Specific examples of hydrolyzable groups include -O-Si(OCH) ３ ) ３ ien-CH ２ -Si(OCH) ３ ) ３ , -C(CH ３ ) ２ -Si(OCH) ３ ) ３ , -O-Si(OCH ２ CH ３ ) ３ ien-CH ２ -Si(OCH) ２ CH ３ ) ３ , -C(CH ３ ) ２ -Si(OCH) ２ CH３ ) ３ These are some examples.

[0044] R ａ１ Examples of hydrocarbon groups in this compound include alkyl groups, cycloalkyl groups, alkenyl groups, and allyl groups. From the viewpoint of ease of synthesis, saturated hydrocarbon groups are preferred, and alkyl groups are more preferred. ａ１ The number of carbon atoms in the hydrocarbon group is preferably 1 to 6, more preferably 1 to 3, and even more preferably 1 to 2.

[0045] Specific examples of groups (TA) when ra1 is 1 or greater include -Si(OCH) ３ ) ２ -O-Si(OCH) ３ ) ３ , -Si(OCH ３ ) ２ -CH ２ -Si(OCH) ３ ) ３ , -Si(OCH ３ ) ２ -C(CH ３ ) ２ -Si(OCH) ３ ) ３ , -Si(OCH ２ CH ３ ) ２ -O-Si(OCH) ３ ) ３ , -Si(OCH ３ ) ２ -O-Si(OCH) ２ CH ３ ) ３ , -Si(OCH ２ CH ３ ) ２ -O-Si(OCH) ２ CH ３ ) ３ , -Si(OCH ２ CH ３ ) ２ -CH ２ -Si(OCH) ３ ) ３ , -Si(OCH ３ ) ２ -CH ２ -Si(OCH) ２ CH ３ ) ３,-Si(OCH ２ HH ３ ) ２ -CH ２ -Si (O) ２ HH ３ ) ３ ,-Si(OCH ２ HH ３ ) ２ -C(CH ３ ) ２ -Si (O) ３ ) ３ ,-Si(OCH ３ ) ２ -C(CH ３ ) ２ -Si (O) ２ HH ３ ) ３ ,-Si(OCH ２ HH ３ ) ２ -C(CH ３ ) ２ -Si (O) ２ HH ３ ) ３ ,-Si(OH) ２ -O-Si (O) ３ ,-Si(OH) ２ -O-Si (OCH) ３ ) ３ ,-Si(OCH ３ ) ２ -O-Si (O) ３ ,-Si(OH) ２ -CH ２ -Si (O) ３ ,-Si(OH) ２ -CH ２ -Si (O) ３ ) ３ ,-Si(OCH ３ ) ２ -CH ２ -Si (O) ３ ,-Si(OH) ２ -C(CH ３ ) ２ -Si (O) ３ ,-Si(OH) ２ -C(CH ３ ) ２ -Si (O) ３ ) ３, -Si(OCH ３ ) ２ -C(CH ３ ) ２ -Si(OH) ３ These are some examples.

[0046] When ra1 is 0, the above group (TA) is the group represented by the following formula (T1). * ａ１ -Si(R ａ１ ) ３ (T1) However, R ａ１ Each of these is independently a hydrolyzable group, a group having a hydrolyzable group, or a hydroxyl group, * ａ１ Q ａ１ This is the connection point.

[0047] ma1 is an integer greater than or equal to 1, preferably between 1 and 10, more preferably between 1 and 3, and even more preferably 1, as it provides superior wear resistance to the surface layer.

[0048] Q ａ１ - (T ａ１ ) ｍａ１ Specific examples include the following. However, α is an integer from 1 to 100, and * is L ａ１ or L ａ２ This is the connection point.

[0049]

[0050]

[0051] Specific examples of the first compound include the following compounds, where n1 is the average of 3, 4, 5, 6, 7, 8, 9, 10, 13, or 15.5.

[0052]

[0053]

[0054]

[0055]

[0056] The composition preferably contains a compound represented by formula (1-1) as the first compound, and more preferably contains a compound represented by formula (1-1) in which each group in formula (1-1) is in the preferred form described above.

[0057] The content of the first compound is preferably 0.1 to 99.9% by mass, more preferably 1 to 99% by mass, and even more preferably 10 to 90% by mass, based on the total amount of the composition. If the content of the first compound is above the lower limit, the water-slip and oil-slip properties of the surface layer are better. If the content of the first compound is below the upper limit, the abrasion resistance of the surface layer is better. Here, oil-slip properties refer to the property that oil adhering to the surface layer is easily removed. The water-slip properties are as described above.

[0058] <Second Compound> The second compound is selected from the group consisting of the compound represented by formula (2-1) and the compound represented by formula (2-2).

[0059] (R ｆ１ ) ｎｂ１ -Q ｂ１ - (T ｂ１ ) ｍｂ１ (2-1) (T ｂ１ ) ｍｂ１ -Q ｂ２ -R ｆ２ -Q ｂ２ - (T ｂ１ ) ｍｂ１ (2-2)

[0060] However, R ｆ１ R is a group that contains a fluoropolyether chain and does not have a reactive silyl group. ｆ２ Q is a divalent fluoropolyether chain. ｂ１ is a (nb1 + mb1) valence linking group, Q ｂ２ is a (mb1+1) valence linking group, and T ｂ１ nb1 is a group containing a reactive silyl group, nb1 is an integer greater than or equal to 1, and mb1 is an integer greater than or equal to 1.

[0061] T ｂ１ Examples of groups containing a reactive silyl group represented by the following formula (TB) include the group represented by the following formula. *ｂ１ -[Si(R ｂ１ ) ２ -Q ｂ３ ] ｒｂ１ -Si(R ｂ１ ) ３ (TB) However, R ｂ１ Each of these is independently a hydrolyzable group, a group having a hydrolyzable group, a hydroxyl group, or a hydrocarbon group, R ｂ１ At least one of them is a hydrolyzable group, a group having a hydrolyzable group, or a hydroxyl group, Q ｂ３ is an oxygen atom, or -CR ｂ２ ２ - and R ｂ２ is a hydrogen atom or hydrocarbon group, rb1 is an integer from 0 to 3, * ｂ１ Q ｂ１ Or Q ｂ２ This is the connection point.

[0062] R ｂ１ The definitions of each group and preferred embodiments in the above formula (TA) are as follows: ａ１ The definitions and preferred embodiments of each group are the same as those described above. Specific examples and preferred embodiments of the group represented by formula (TB) are the same as those described above for the group represented by formula (TA). Among these, rb1 is preferably 1 to 3 because it provides superior wear resistance to the surface layer.

[0063] mb1 is an integer greater than or equal to 1, preferably 1 to 10, more preferably 1 to 3, and even more preferably 1, as it provides superior water-repellent and oil-repellent properties to the surface layer.

[0064] R is a fluoropolyether chain (a monovalent fluoropolyether chain). ｆ１ , and R, which is a divalent fluoropolyether chain. ｆ２ R is a group having two or more oxyfluoroalkylene units. ｆ１ and R ｆ２ It may have a hydrogen atom, but Q ｂ１ Or Q ｂ２ The carbon atoms at the end of the molecule shall have a fluorine atom.

[0065] The molecular weight per fluoropolyether chain is preferably 2,000 to 20,000, more preferably 2,500 to 15,000, and even more preferably 3,000 to 10,000, from the viewpoint of superior wear resistance of the surface layer.

[0066] R ｆ１ The following structure (A1) is preferred.

[0067] R ｆ１１ - ( OR ｆ１２ ) ｍ１ - (A1)

[0068] However, R ｆ１１ R is a fluoroalkyl group having 1 to 20 carbon atoms. ｆ１１ If there are multiple R ｆ１１ They may be the same or different from each other, R ｆ１２ R is a fluoroalkylene group having 1 to 6 carbon atoms. ｆ１２ If there are multiple R ｆ１２ The two integers may be the same or different from each other, and m1 is an integer of 2 or more. m1 is preferably an integer between 2 and 500, more preferably an integer between 10 and 200, and even more preferably between 10 and 100.

[0069] R ｆ２ The following structure (A2) is preferred.

[0070] -R ｆ２１ - ( OR ｆ２２ ) ｍ２ - (A2)

[0071] However, R ｆ２１ R is a fluoroalkylene group having 1 to 6 carbon atoms. ｆ２２ R is a fluoroalkylene group having 1 to 6 carbon atoms. ｆ２２ If there are multiple R ｆ２２ The two integers may be the same or different from each other, and m2 is an integer greater than or equal to 2. m2 is preferably an integer between 2 and 500, more preferably between 10 and 200, and even more preferably between 10 and 100.

[0072] (OR ｆ１２ ) and (OR ｆ２２) preferably has the following structure (f2).

[0073] - [(OG ｆ１ ) ｍ１１ (OG ｆ２ ) ｍ１２ (OG ｆ３ ) ｍ１３ (OG ｆ４ ) ｍ１４ (OG ｆ５ ) ｍ１５ (OG ｆ６ ) ｍ１６ ] - (f2)

[0074] However, G ｆ１ This is a fluoroalkylene group having 1 carbon atom, G ｆ２ This is a fluoroalkylene group with 2 carbon atoms, G ｆ３ This is a fluoroalkylene group with 3 carbon atoms, G ｆ４ This is a fluoroalkylene group with 4 carbon atoms, G ｆ５ This is a fluoroalkylene group with 5 carbon atoms, G ｆ６ m11 is a fluoroalkylene group having 6 carbon atoms, and m11, m12, m13, m14, m15, and m16 each independently represent an integer of 0 or 1 or more, and m11 + m12 + m13 + m14 + m15 + m16 is preferably an integer between 2 and 200. Note that in structure (f2) (OG ｆ１ ) ~ (OG ｆ６ The order of joining the elements is arbitrary. m11 to m16 of structure (f2) are respectively (OG ｆ１ ) ~ (OG ｆ６ This represents the number of (OG) and not their arrangement. For example, (OG ｆ５ ) ｍ１５ (OG ｆ５ This indicates that the number of ) is m15, (OG ｆ５ ) ｍ１５ This does not represent the block arrangement structure. Similarly, (OG ｆ１ ) ~ (OG ｆ６ The order in which the units are listed does not represent the bonding order of each unit. Furthermore, the fluoroalkylene group having 3 to 6 carbon atoms may be a linear fluoroalkylene group, or a branched or cyclic fluoroalkylene group.

[0075] G ｆ１ A specific example is -CF ２ - and -CHF- are mentioned. G ｆ２ A specific example is -CF ２ CF ２ -, -CHFCF ２ -, -CHFCHF-, -CH ２ CF ２ -ien-CH ２ CHF- is one example. ｆ３ A specific example is -CF ２ CF ２ CF ２ -, -CF ２ CHFCF ２ -, -CF ２ CH ２ CF ２ -, -CHFCF ２ CF ２ -, -CHFCHFCF ２ -, -CHFCHFCHF-, -CHFCH ２ CF ２ -ien-CH ２ CF ２ CF ２ -ien-CH ２ CHFCF ２ -ien-CH ２ CH ２ CF ２ -ien-CH ２ CF ２ CHF-Ya-CH ２ CHFCHF-, -CH ２ CH ２ CHF-, -CF (CF ３ ) - CF ２ -, -CF(CHF ２ ) - CF ２ -, -CF(CH ２ F) - CF ２ -, -CF(CH ３ ) - CF ２ -, -CF (CF ３ ) -CHF-, -CF(CHF ２ ) -CHF-, -CF(CH ２ F) -CHF-, -CF(CH ３ ) -CHF-, -CF(CF ３ ) - CH ２-, -CF(CHF ２ )-CH ２ -, -CF(CH ２ F)-CH ２ -, -CF(CH ３ )-CH ２ -, -CH(CF ３ )-CF ２ -, -CH(CHF ２ )-CF ２ -, -CH(CH ２ F)-CF ２ -, -CH(CH ３ )-CF ２ -, -CH(CF ３ )-CHF-, -CH(CHF ２ )-CHF-, -CH(CH ２ F)-CHF-, -CH(CH ３ )-CHF-, -CH(CF ３ )-CH ２ -, -CH(CHF ２ )-CH ２ -, -CH(CH ２ F)-CH ２ -. Specific examples of G ｆ４ include, -CF ２ CF ２ CF ２ CF ２ -, -CHFCF ２ CF ２ CF ２ -, -CH ２ CF ２ CF ２ CF ２ -, -CF ２ CHFCF ２ CF ２ -, -CHFCHFCF ２ CF ２ -, -CH ２ CHFCF ２ CF ２ -, -CF ２ CH ２ CF ２ CF ２ -, -CHFCH ２ CF ２ CF ２ -, -CH ２ CH ２ CF ２CF3 ２ -, -CHFCF2 ２ CHFCF3 ２ -, -CH2 ２ CF2CF3 ２ CHFCF2CF3 ２ -, -CF2 ２ CHFCHFCF2CF3 ２ -, -CHFCHFCHFCF2CF3 ２ -, -CH2 ２ CHFCHFCF2CF3 ２ -, -CF2 ２ CH2 ２ CHFCF2CF3 ２ -, -CHFCH2 ２ CH2CF2CF3 ２ -, -CH2 ２ CH2 ２ CHFCF2CF3 ２ -, -CF2 ２ CH2 ２ CH2 ２ CF2CF3 ２ -, -CHFCH2 ２ CH2 ２ CF2CF3 ２ -, -CH2 ２ CH2 ２ CH2 ２ CF2CF3 ２ -, -CHFCH2 ２ CH2 ２ CHF-, -CH2 ２ CH2 ２ CH2 ２ CHF-, -cycloC ４ F9 ６ -. Specific examples of G ｆ５ include -CF2 ２ CF2 ２ CF2 ２ CF2 ２ CF3 ２ -, -CHFCF2 ２ CF2 ２ CF2 ２ CF3 ２ -, -CH2 ２ CHFCF2 ２ CF2 ２ CF3 ２ -, -CF2 ２ CHFCF2 ２ CF2 ２ CF3 ２ -, -CHFCHFCF2 ２ CF3 ２CF ２ -, -CF ２ CH ２ CF ２ CF ２ CF ２ -, -CHFCH ２ CF ２ CF ２ CF ２ -, -CH ２ CH ２ CF ２ CF ２ CF ２ -, -CF ２ CF ２ CHFCF ２ CF ２ -, -CHFCF ２ CHFCF ２ CF ２ -, -CH ２ CF ２ CHFCF ２ CF ２ -, -CH ２ CF ２ CF ２ CF ２ CH ２ -, -cycloC ５ F ８ -. As a specific example of G ｆ６ , -CF ２ CF ２ CF ２ CF ２ CF ２ CF ２ -, -CF ２ CF ２ CHFCHFCF ２ CF ２ -, -CHFCF ２ CF ２ CF ２ CF ２ CF ２ -, -CHFCHFCHFCHFCHFCHF-, -CHFCF ２ CF ２ CF ２ CF ２ CH ２ -, -CH ２ CF ２ CF ２ CF ２ CF ２ CH２ -, -cycloC ６ F １０ - is one example. Here, -cycloC ４ F ６ The dash (-) indicates a perfluorocyclobutanediyl group, and specific examples include the perfluorocyclobutane-1,2-diyl group and the perfluorocyclobutane-1,3-diyl group. ５ F ８ The dash (-) indicates a perfluorocyclopentanediyl group, a specific example of which is the perfluorocyclopentane-1,3-diyl group. ６ F １０ The dash (-) indicates a perfluorocyclohexanediyl group, and a specific example of this is the perfluorocyclohexane-1,4-diyl group.

[0076] - ( OR ｆ１２ ) ｍ１ - and - (OR ｆ２２ ) ｍ２ - From the viewpoint of superior wear resistance of the surface layer, it is preferable to have one of the structures represented by the following structures (f3) to (f5), and from the viewpoint of superior alkali resistance, it is more preferable to have the structure represented by structure (f3), (OCF ２ ) ｍ１１ (OCF ２ CF ２ ) ｍ１２ A structure represented by (OCF) is even more preferable. ２ ) ｍ１１ (OCF ２ CF ２ ) ｍ１２ In this case, m12 / m11 is preferably 0.1 to 10, more preferably 0.2 to 5.0, even more preferably 0.2 to 2.0, particularly preferably 0.2 to 1.5, and most preferably 0.2 to 0.85, from the viewpoint of superior abrasion resistance and fingerprint removal properties of the surface layer.

[0077] - (OG ｆ１ ) ｍ１１ (OG) ｆ２ ) ｍ１２ - (f3) -(OG ｆ２ ) ｍ１２ (OG)ｆ４ ) ｍ１４ - (f4) -(OG ｆ３ ) ｍ１３ - (f5)

[0078] However, the symbols for structures (f3) to (f5) are the same as those for structure (f2) above.

[0079] In structures (f3) and (f4), (OG ｆ１ ) and (OG ｆ２ ), (OG ｆ２ ) and (OG ｆ４ The order in which the terms are joined is arbitrary. For example, in formula (G2), (OG ｆ１ ) and (OG ｆ２ ) may be arranged alternately, (OG ｆ１ ) and (OG ｆ２ ) may be placed in each block, or they may be random. The same applies to structure (f5). In structure (f3), m11 is preferably 1 to 30, and more preferably 1 to 20. Also, m12 is preferably 1 to 30, and more preferably 1 to 20. In structure (f4), m12 is preferably 1 to 30, and more preferably 1 to 20. Also, m14 is preferably 1 to 30, and more preferably 1 to 20. In structure (f5), m13 is preferably 1 to 30, and more preferably 1 to 20.

[0080] - ( OR ｆ１２ ) ｍ１ - and - (OR ｆ２２ ) ｍ２ - The proportion of fluorine atoms in the mixture [{number of fluorine atoms / (number of fluorine atoms + number of hydrogen atoms)} × 100 (%)] is preferably 60% or more, more preferably 70% or more, and even more preferably 80% or more, from the viewpoint of superior wear resistance of the surface layer. Also, - (OR ｆ１２ ) ｍ１ - and - (OR ｆ２２ ) ｍ２ The molecular weight of the - portion is preferably 2,000 to 20,000, more preferably 2,500 to 15,000, and even more preferably 3,000 to 10,000, from the viewpoint of superior wear resistance of the surface layer.

[0081] Q ｂ１is a (nb1 + mb1) valence linking group, Q ｂ２ is a (mb1+1) valence linking group. Hereafter, Q will be used as a representative example. ｂ１ I will explain the following. Q ｂ２ The answer is Q below. ｂ１ In the explanation, nb1 is understood to be limited to 1.

[0082] Q ｂ１ T can be any group that does not impair the effects of the present disclosure, for example, an alkylene group which may have an etheric oxygen atom or a divalent organopolysiloxane group, a carbon atom, a nitrogen atom, a silicon atom, a divalent to octavalent organopolysiloxane group, and from the groups (3-1A), (3-1B), (3-1A-1) to (3-1A-7) described later, ｂ１ The groups excluding the one mentioned above are listed.

[0083] Also, Q ｂ１ These may be groups (g2-1) to (g2-14) described later.

[0084] mb1 is an integer greater than or equal to 1. From the viewpoint of superior wear resistance of the surface layer, mb1 is preferably 1 to 15, more preferably 1 to 6, even more preferably 2 to 4, and particularly preferably 2 or 3.

[0085] nb1 is an integer greater than or equal to 1. From the viewpoint of superior wear resistance of the surface layer, nb1 is preferably 1 to 3, and more preferably 1.

[0086] -Q in equation (2-1) ｂ１ - (T ｂ１ ) ｍｂ１ The group represented is preferably (3-1A) or (3-1B), with group (3-1A) being more preferred.

[0087] - Q ａ -X ３１ (-Q ｂ -T ｂ１ ) ｈ (-R ３１ ) ｉ (3-1A) -Q ｃ - [CH ２ C(R ３２ ) (-Q ｄ -T ｂ１)] ｙ -R ３３ (3-1B) Q ａ These are single or divalent linking groups. Examples of divalent linking groups include divalent hydrocarbon groups, divalent heterocyclic groups, -O-, -S-, and -SO ２ -, -N(R ｄ )-, -C(=O)-, -C(=S)-, -Si(R ａ ) ２ - and groups formed by combining two or more of these. The above-mentioned divalent hydrocarbon group may be a divalent saturated hydrocarbon group, a divalent aromatic hydrocarbon group which may have substituents, an alkenylene group, or an alkylylene group. The divalent saturated hydrocarbon group may be linear, branched, or cyclic, and an example is an alkylene group. The number of carbon atoms in the alkylene group is preferably 1 to 30, more preferably 1 to 20, even more preferably 4 to 20, and particularly preferably 5 to 15. In addition, the divalent aromatic hydrocarbon group is preferably one which has 5 to 20 carbon atoms, and an example is a phenylene group. Other examples include alkenylene groups with 2 to 20 carbon atoms and alkylylene groups with 2 to 20 carbon atoms. The above-mentioned R ａ R is an alkyl group (preferably having 1 to 10 carbon atoms) or a phenyl group. ｄ This is a hydrogen atom or an alkyl group (preferably having 1 to 10 carbon atoms). Examples of groups formed by combining two or more of these include -OC(=O)-, -C(=O)O-, -C(=O)S-, and -C(=O)N(R). ｄ )-,-N(R ｄ )C(=O)-,-N(R ｄ )C(=O)N(R ｄ )-,-N(R ｄ )C(=O)O-, -OC(=O)N(R ｄ ) -, -SO ２ N(R) ｄ )-,-N(R ｄ ) SO ２ -, -C(=O)N(R ｄ )- an alkylene group having -N(R ｄ ) an alkylene group having C(=O)-, -OC(=O)N(R ｄ)-, an alkylene group having -S-, an alkylene group having -OC(=O)-, an alkylene group having -C(=O)O-, an alkylene group having -C(=O)S-, -N(R ｄ )-, an alkylene group having -N(R ｄ )C(=O)N(R ｄ )-, an alkylene group having -SO ２ N(R ｄ )-, an alkylene group having an alkylene group -Si(R ａ ) ２ -phenylene group -Si(R ａ ) ２ include the above. Among them, Q ａ is a divalent hydrocarbon group other than an alkylene group, a divalent heterocyclic group, -O-, -S-, -SO ２ -, -N(R ｄ )-, -C(=O)-, -Si(R ａ ) ２ -, -OC(=O)-, -C(=O)O-, -C(=O)S-, -C(=O)N(R ｄ )-, -N(R ｄ )C(=O)-, -N(R ｄ )C(=O)N(R ｄ )-, -N(R ｄ )C(=O)O-, -OC(=O)N(R ｄ )-, -SO ２ N(R ｄ )-, -N(R ｄ )SO ２ -, an alkylene group having -C(=O)N(R ｄ )-, an alkylene group having -N(R ｄ )C(=O)-, an alkylene group having -OC(=O)N(R ｄ )-, an alkylene group having an etheric oxygen atom, an alkylene group having -S-, an alkylene group having -OC(=O)-, an alkylene group having -C(=O)O-, an alkylene group having -C(=O)S-, -N(R ｄ )-, an alkylene group having -N(R ｄ )C(=O)N(R ｄ )-, an alkylene group having, or -SO ２ N(Rｄ an alkylene group having )- is preferred, and an alkylene group having -OC(=O)- or -C(=O)N(R ｄ )-, an alkylene group having -OC(=O)N(R ｄ )-, an alkylene group having an etheric oxygen atom, an alkylene group having -S-, an alkylene group having -C(=O)O-, an alkylene group having -C(=O)S-, an alkylene group having -N(R ｄ )- or an alkylene group having -N(R ｄ )C(=O)N(R ｄ )- is more preferred, and an alkylene group having -C(=O)O- or an alkylene group having -C(=O)N(R ｄ )- is even more preferred.

[0088] In formula (3-1A), X ３１ is a single bond, an alkylene group, a carbon atom, a nitrogen atom, a silicon atom, a di- to octavalent organopolysiloxane group, or a group having a (h+i+1)-valent ring. The alkylene group may have -O-, a silphenylene skeleton group, a divalent organopolysiloxane group or a dialkylsilylene group between carbon atoms. The alkylene group may have a plurality of groups selected from the group consisting of -O-, a silphenylene skeleton group, a divalent organopolysiloxane group and a dialkylsilylene group. X ３１ The number of carbon atoms in the alkylene group represented by is preferably 1 to 20, more preferably 1 to 10. Examples of the di- to octavalent organopolysiloxane group include a divalent organopolysiloxane group and a (w2+1)-valent organopolysiloxane group described later.

[0089] In formula (3-1A), when X ３１ is a group having a (h+i+1)-valent ring, Q ａ , (-Q ｂ -T ｂ１ ) and R ３１ are directly bonded to atoms constituting the ring, provided that the ring is other than an organopolysiloxane ring. X ３１The ring in the expression may be a monoring, a fused polyring, a bridging ring, a spiroring, or an aggregated polyring. The atoms constituting the ring may be a carbon ring consisting only of carbon atoms, or a heteroring consisting of a heteroatom with a valence of 2 or more and a carbon atom. The bonds between the atoms constituting the ring may be single bonds or multiple bonds. Furthermore, the ring may be aromatic or a non-aromatic ring. As a monoring, a 4-membered to 8-membered ring is preferred, and a 5-membered or 6-membered ring is more preferred. As a fused polyring, a fused polyring formed by the fusion of two or more 4-membered to 8-membered rings is preferred, and a fused polyring formed by the bonding of two or three rings selected from 5-membered and 6-membered rings, or a fused polyring formed by the bonding of one or two rings selected from 5-membered and 6-membered rings and one 4-membered ring is more preferred. As the bridging ring, a bridging ring with a 5-membered or 6-membered ring as the largest ring is preferred, and as the spiro ring, a spiro ring consisting of two 4-membered to 6-membered rings is preferred. As the aggregated polyring, an aggregated polyring in which two or three rings selected from the 5-membered and 6-membered rings are bonded via single bonds, one to three carbon atoms, or one heteroatom with a valency of 2 or 3 is preferred. In the aggregated polyring, each ring has Q ａ , (-Q ｂ -T ｂ１ ) and R ３１ It is preferable that one of the following (when i = 1 or greater) is bonded. The heteroatoms constituting the ring are preferably nitrogen atoms, oxygen atoms, or sulfur atoms, and more preferably nitrogen atoms or oxygen atoms. It is preferable that the number of heteroatoms constituting the ring is three or less. Furthermore, if the number of heteroatoms constituting the ring is two or more, those heteroatoms may be different.

[0090] X ３１The preferred rings in the compound are those selected from the group consisting of a 3- to 8-membered aliphatic ring, a benzene ring, a 3- to 8-membered heteroring, a fused ring formed by the fusion of two or three of these rings, a bridging ring with a 5- or 6-membered ring as the largest ring, and a polycyclic aggregate having two or more of these rings, where the linking group is a single bond, an alkylene group with 3 or fewer carbon atoms, an oxygen atom, or a sulfur atom. Preferred rings are a benzene ring, a 5- or 6-membered aliphatic ring, a 5- or 6-membered heteroring having a nitrogen atom or an oxygen atom, and a fused ring of a 5- or 6-membered carbon ring and a 4- to 6-membered heteroring. Specific examples of rings include the following, as well as 1,3-cyclohexadiene rings, 1,4-cyclohexadiene rings, anthracene rings, cyclopropane rings, decahydronaphthalene rings, norbornene rings, norbornadiene rings, furan rings, pyrrole rings, thiophene rings, pyrazine rings, morpholine rings, aziridine rings, isoquinoline rings, oxazole rings, isoxazole rings, thiazole rings, imidazole rings, pyrazole rings, pyran rings, pyridazine rings, pyrimidine rings, and indene rings. Rings containing an oxo group (=O) are also shown below.

[0091]

[0092] X ３１ In this case, the bonds between atoms that constitute a ring and that do not constitute a ring are Q ａ , (-Q ｂ -T ｂ１ ) or R ３１ This is a bond that connects to Q. If there are any remaining bonds, these bonds are attached to a hydrogen atom or a substituent. Examples of such substituents include halogen atoms, alkyl groups (which may contain an etheric oxygen atom between carbon atoms), cycloalkyl groups, alkenyl groups, allyl groups, alkoxy groups, and oxo groups (=O). In addition, one of the carbon atoms constituting the ring may be Q. ａ , (-Q ｂ -T ｂ１ ) or R ３１ If it has two bonding bonds, one of the carbon atoms is Q ａ and (-Q ｂ -T ｂ１) and may be joined together, and two (-Q ｂ -T ｂ１ ) may be joined together. Q ａ And, (-Q ｂ -T ｂ１ ) or R ３１ It is preferable that it is bonded to a different ring-constituting atom. h (-Q ｂ -T ｂ１ Each of these may be bonded to a separate ring-forming atom, two of which may be bonded to one ring-forming carbon atom, and two of these may be bonded to two (-Q ｂ -T ｂ１ There may be two or more ring-forming carbon atoms to which ) are bonded. i R ３１ Each of these may be bonded to a separate ring-forming atom, two of which may be bonded to one ring-forming carbon atom, and two R ３１ There may be two or more ring-forming carbon atoms to which the compound is bonded.

[0093] Among them, X ３１ From the standpoint of superior wear resistance of the surface layer, carbon atoms, nitrogen atoms, silicon atoms, 4-8 valent organopolysiloxane groups, or groups having a (h+i+1) valent ring are preferred, with carbon atoms being more preferred.

[0094] In equation (3-1A), Q ｂ It is a single bond or a divalent linking group. The definition of a divalent linking group is given in Q above. ａ This is synonymous with the definition explained earlier.

[0095] Among them, Q ｂ The alkylene group is preferably an alkylene group which may have an etheric oxygen atom. The number of carbon atoms in the alkylene group is preferably 1 to 30, more preferably 1 to 20, even more preferably 2 to 20, and may be 2 to 10, 2 to 6, or 2 to 5. Examples include 2, 3, 8, 9, and 11. The number of carbon atoms may also be 1 to 10.

[0096] In formula (3-1A), R ３１ This is a hydrogen atom, a hydroxyl group, or an alkyl group. The number of carbon atoms in the alkyl group is preferably 1 to 5, more preferably 1 to 3, and even more preferably 1.

[0097] X３１ When X is a single bond or an alkylene group, h is 1 and i is 0, and ３１ When X is a nitrogen atom, h is an integer of 1 to 2, i is an integer of 0 to 1, which satisfies h + i = 2, and ３１ When X is a carbon atom or a silicon atom, h is an integer of 1 to 3, i is an integer of 0 to 2, which satisfies h + i = 3, and ３１ When X is an organopolysiloxane group having a valence of 2 to 8, h is an integer of 1 to 7, i is an integer of 0 to 6, which satisfies h + i = 1 to 7. When ３１ X is a group having a (h + i + 1)-valent ring, h is an integer of 1 to 7, i is an integer of 0 to 6, which satisfies h + i = 1 to 7. If there are two or more (-Q ｂ -T ｂ１ ) groups, the two or more (-Q ｂ -T ｂ１ ) groups may be the same or different. If there are two or more R ３１ groups, the two or more (-R ３１ ) groups may be the same or different.

[0098] Among these, i is preferably 0 from the viewpoint of further improving the abrasion resistance of the surface layer.

[0099] In formula (3-1A), when Q ａ , X ３１ , and Q ｂ are each a single bond, T ｂ１ is directly bonded to R ｆ１ .

[0100] In formula (3-1B), Q ｃ is a single bond or a divalent linking group. The definition of the divalent linking group in Q ｃ is the same as the definition described for Q ａ above.

[0101] In formula (3-1B), R ３２ is a hydrogen atom or an alkyl group having 1 to 10 carbon atoms, and is preferably a hydrogen atom from the viewpoint of facilitating production of the compound. A methyl group is preferred as the alkyl group.

[0102] In formula (3-1B), Q ｄQ is a single bond or an alkylene group. The number of carbon atoms in the alkylene group is preferably 1 to 10, and more preferably 1 to 6. From the viewpoint of ease of compound production, ｄ This is a single bond or -CH ２ - is preferable.

[0103] In formula (3-1B), R ３３ This atom is either a hydrogen atom or a halogen atom, and is preferably a hydrogen atom because it facilitates the production of compounds.

[0104] y is an integer between 1 and 10, preferably between 1 and 6. Two or more [CH ２ C(R ３２ ) (-Q ｄ -T ｂ１ ) ] may be the same or different.

[0105] The following groups (3-1A-1) to (3-1A-7) are preferred as the group (3-1A). -Z １ - (X ３２ ) ｓ１ - Q ｂ１ -T ｂ１ (3-1A-1) -Z １ - (X ３３ ) ｓ２ - Q ａ２ -N[-Q ｂ２ -T ｂ１ ] ２ (3-1A-2) -Q ａ３ -Si(R ｇ ) [-Q ｂ３ -T ｂ１ ] ２ (3-1A-3) -Z １ - [Q] ｅ ] ｓ４ - Q ａ４ - (O) ｔ４ -C[-(O) ｕ４ - Q ｂ４ -T ｂ１ ] ３－ｗ１ (-R ３１ ) ｗ１ (3-1A-4) -Q ａ５ -Si[-Q] ｂ５ -T ｂ１ ] ３ (3-1A-5) -Z１ - [Q] ｅ ] ｖ - Q ａ６ -Z ａ [-Q] ｂ６ -T ｂ１ ] ｗ２ (3-1A-6) -Z １ - [Q] ｅ ] ｓ４ - Q ａ４ - (O) ｔ４ -Z ｃ [-(O-Q) ｂ４ ) ｕ４ -T ｂ１ ] ｗ３ (-OH) ｗ４ (3-1A-7)

[0106] Among these, base (3-1A-1) is preferred because it exhibits superior water-repellent and oil-repellent properties in the surface layer.

[0107] In equations (3-1A-1), (3-1A-2), (3-1A-4), (3-1A-6), and (3-1A-7), Z １ This is an alkylene group which may have a single bond or an oxygen atom between carbon atoms. The alkylene group is Q. ａ An example of a divalent linking group represented by is an alkylene group, and the preferred embodiment is the same.

[0108] In the base (3-1A-1), X ３２ is -O-, -S-, -N(R ｄ )-, -C(=O)-, -C(=O)O-, -C(=O)S-, -SO ２ N(R) ｄ )-,-N(R ｄ ) SO ２ -, -N(R ｄ )C(=O)-,-N(R ｄ )C(=O)N(R ｄ )-, -OC(=O)N(R ｄ )-, or-C(=O)N(R ｄ ) - (where N in the formula is Q) ｂ１ (to be joined). R ｄ The definition is as described above. s1 is either 0 or 1.

[0109] Among them, X ３２ is -O-, -S-, -N(R ｄ )-, -C(=O)-, -C(=O)O-, -C(=O)S-, -SO ２ N(R) ｄ )-,-N(R ｄ ) SO ２ -, -N(R ｄ )C(=O)-,-N(R ｄ )C(=O)N(R ｄ )-, -OC(=O)N(R ｄ )-, or -C(=O)N(R ｄ )- is preferred, -O-, -S-, -N(R ｄ )-, -C(=O)O-, -C(=O)S-, -N(R ｄ )C(=O)N(R ｄ )-, -OC(=O)N(R ｄ )-, or-C(=O)N(R ｄ )- is more preferable, -C(=O)O- or -C(=O)N(R ｄ ) - is even more preferable.

[0110] Q ｂ１ This is a single bond or an alkylene group. The alkylene group may have -O-, a sylphenylene skeleton group, or a dialkylsilylene group. The alkylene group may have multiple groups selected from the group consisting of -O-, a sylphenylene skeleton group, a divalent organopolysiloxane group, and a dialkylsilylene group. When the alkylene group has -O-, a sylphenylene skeleton group, a divalent organopolysiloxane group, or a dialkylsilylene group, it is preferable that these groups are located between carbon atoms. Q ｂ１ The number of carbon atoms in the alkylene group represented by is preferably 1 to 30, more preferably 1 to 20, even more preferably 2 to 20, and particularly preferably 2 to 6. The number of carbon atoms may also be 1 to 10.

[0111] Among them, Q ｂ１ The alkylene group having 2 to 6 carbon atoms is preferred.

[0112] -(X) in base (3-1A-1) ３２ ) ｓ１ - Q ｂ１ -T ｂ１Specific examples include the following base. In the following formula, * represents Z １ This indicates the connection point with [the other element].

[0113]

[0114] In the base (3-1A-2), X ３３ is -O-, -S-, -N(R ｄ )-, -C(=O)-, -C(=O)O-, -C(=O)S-, -SO ２ N(R) ｄ )-,-N(R ｄ ) SO ２ -, -N(R ｄ )C(=O)-,-N(R ｄ )C(=O)N(R ｄ )-, -OC(=O)N(R ｄ )-, or-C(=O)N(R ｄ ) - is R ｄ The definition is as described above. s2 is either 0 or 1. s2 is preferably 0 because it facilitates the production of the compound.

[0115] Among them, X ３３ is -O-, -S-, -N(R ｄ )-, -C(=O)-, -C(=O)O-, -C(=O)S-, -SO ２ N(R) ｄ )-,-N(R ｄ ) SO ２ -, -N(R ｄ )C(=O)-,-N(R ｄ )C(=O)N(R ｄ )-, -OC(=O)N(R ｄ )-, or -C(=O)N(R ｄ )- is preferred, -C(=O)O-, -C(=O)S-, -SO ２ N(R) ｄ )-, or-C(=O)N(R ｄ ) - is preferable.

[0116] Q ａ２ This includes single bonds, alkylene groups, -C(=O)-, or etheric oxygen atoms between carbon atoms of alkylene groups with 2 or more carbon atoms, -C(=O)-, -C(=O)O-, -OC(=O)-, and -C(=O)N(R). ｄ)-,-N(R ｄ )C(=O)-,-N(R ｄ )C(=O)N(R ｄ )-,-N(R ｄ )C(=O)O-, -OC(=O)N(R ｄ ) -, -SO ２ N(R) ｄ )-,-N(R ｄ ) SO ２ -, -C(=O)N(R ｄ ) - or -NH- is a group having . Q ａ２ The number of carbon atoms in the alkylene group represented by is preferably 1 to 20, more preferably 1 to 10, even more preferably 1 to 6, and particularly preferably 1 to 3. Q ａ２ An alkylene group with 2 or more carbon atoms represented by an etheric oxygen atom between carbon atoms, -C(=O)-, -C(=O)O-, -OC(=O)-, -C(=O)N(R) ｄ )-,-N(R ｄ )C(=O)-,-N(R ｄ )C(=O)N(R ｄ )-,-N(R ｄ )C(=O)O-, -OC(=O)N(R ｄ ) -, -SO ２ N(R) ｄ )-,-N(R ｄ ) SO ２ -, -C(=O)N(R ｄ The number of carbon atoms in the group having - or -NH- is preferably 2 to 10, and more preferably 2 to 6.

[0117] Q ａ２ From the standpoint of facilitating the production of compounds, a single bond or -C(=O)- is preferred.

[0118] Q ｂ２ This refers to an alkylene group, or a group having a divalent organopolysiloxane group, an etheric oxygen atom, or -NH- between carbon atoms of an alkylene group having two or more carbon atoms. Q ｂ２The number of carbon atoms in the alkylene group represented by is preferably 1 to 30, more preferably 1 to 20, even more preferably 2 to 20, and may also be 2 to 10 or 2 to 6. For example, 2, 3, 8, 9, and 11 are given. Also, the above number of carbon atoms may be 1 to 10. Q ｂ２ The number of carbon atoms in the group having a divalent organopolysiloxane group, an etheric oxygen atom, or -NH- between carbon atoms of the alkylene group with 2 or more carbon atoms represented by is preferably 2 to 10, and more preferably 2 to 6.

[0119] Q ｂ２ As for the ease of producing the compound, -CH ２ CH ２ CH ２ -ien-CH ２ CH ２ OCH ２ CH ２ CH ２ - is preferable (however, the right side is bonded to Si).

[0120] Two [-Q ｂ２ -T ｂ１ These may be the same or different.

[0121] Base (3-1A-2) - (X ３３ ) ｓ２ - Q ａ２ -N[-Q ｂ２ -T ｂ１ ] ２ Specific examples include the following base. In the following formula, * represents Z １ This indicates the bonding position with. Also, in the formula, T ｂ１ (CH ２ ) α In this formula, α is an integer representing the number of methylene groups, preferably 1 to 30, more preferably 1 to 20, even more preferably 2 to 20, and may also be 2 to 10 or 2 to 6. Examples include 2, 3, 8, 9, and 11. The number of carbon atoms may also be 1 to 10. Multiple α atoms in the same compound may be the same or different, but it is preferable that they be the same. For example, multiple α atoms in the same compound are all 2, 3, 8, 9, and 11. The same applies hereafter.

[0122]

[0123] In the base (3-1A-3), Q ａ３ This is an alkylene group which may have a single bond or an etheric oxygen atom. From the standpoint of ease of compound production, Q ａ３ A single bond is preferred. The number of carbon atoms in the alkylene group, which may have an etheric oxygen atom, is preferably 1 to 10, and particularly preferably 2 to 6.

[0124] R ｇ R is a hydrogen atom, a hydroxyl group, or an alkyl group. ｇ From the standpoint of ease of compound production, hydrogen atoms or alkyl groups are preferred. The alkyl group preferably has 1 to 10 carbon atoms, more preferably 1 to 4 carbon atoms, and even more preferably a methyl group.

[0125] Q ｂ３ This refers to an alkylene group, or a group having an etheric oxygen atom or a divalent organopolysiloxane group between carbon atoms of an alkylene group having two or more carbon atoms. Q ｂ３ The number of carbon atoms in the alkylene group represented by is preferably 1 to 30, more preferably 1 to 20, even more preferably 2 to 20, and may also be 2 to 10 or 2 to 6. For example, 2, 3, 8, 9, and 11 are given. Also, the above number of carbon atoms may be 1 to 10. Q ｂ３ The number of carbon atoms in the alkylene group having two or more carbon atoms, represented by the formula, is preferably 2 to 20, more preferably 2 to 10, and even more preferably 2 to 6. ｂ３ Because it is easy to manufacture the compound, -CH ２ CH ２ -ien-CH ２ CH ２ CH ２ -, or -CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ - is preferable.

[0126] Two [-Qｂ３ -T ｂ１ These may be the same or different.

[0127] -Si(R) of the (3-1A-3) group ｇ ) [-Q ｂ３ -T ｂ１ ] ２ Specific examples include the following base. In the following formula, * represents Q ａ３ This indicates the connection point with [the other element].

[0128]

[0129] In the base (3-1A-4), Q ｅ is -C(=O)O-, -SO ２ N(R) ｄ )-,-N(R ｄ ) SO ２ -, -N(R ｄ )C(=O)-, -OC(=O)-, or -C(=O)N(R ｄ ) - is R ｄ The definition is as stated above. R ３１ The definition is as described above. If w1 is 1 or 2, R ３１ It is preferably a hydrogen atom. s4 is 0 or 1. Q ａ４ This is an alkylene group which may have a single bond or an etheric oxygen atom. The number of carbon atoms in the alkylene group which may have an etheric oxygen atom is preferably 1 to 20, more preferably 1 to 10, even more preferably 1 to 6, and particularly preferably 1 to 3. t4 is 0 or 1 (however, Q ａ４ It is 0 if it is a single bond. ) -Q ａ４ - (O) ｔ４ - As for the ease of compound production, if s4 is 0, it is a single bond, -CH ２ O-, -CH ２ OCH ２ -ien-CH ２ OCH ２ CH ２ O-, -CH ２ OCH ２ CH ２ OCH ２ -ien-CH ２ OCH２ CH ２ CH ２ CH ２ OCH ２ - is preferred, and if s4 is 1, a single bond, -CH ２ -ien-CH ２ CH ２ - is preferable.

[0130] Q ｂ４ This is an alkylene group, and the above alkylene group is -O-, -C(=O)N(R ｄ ) - (R ｄ The definition is as described above. It may have a silphenylene skeleton group, a divalent organopolysiloxane group, or a dialkylsilylene group. When the alkylene group has an -O- or silphenylene skeleton group, it is preferable that the -O- or silphenylene skeleton group is between carbon atoms. Also, the alkylene group may have -C(=O)N(R ｄ )-, if it has a dialkylsilylene group or a divalent organopolysiloxane group, carbon-carbon or (O) ｕ４ It is preferable to have these groups at the terminal end that bonds with the other. ｂ４ The number of carbon atoms in the alkylene group represented by is preferably 1 to 30, more preferably 1 to 20, even more preferably 2 to 20, and may also be 2 to 10 or 2 to 6. For example, 2, 3, 8, 9, and 11 are given. The above number of carbon atoms may also be 1 to 10.

[0131] u4 is either 0 or 1. - (O) ｕ４ - Q ｂ４ -As for the ease of manufacturing the compound, -CH ２ CH ２ -ien-CH ２ CH ２ CH ２ -ien-CH ２ OCH ２ CH ２ CH ２ -ien-CH ２ OCH ２ CH ２ CH ２ CH ２ CH ２ -, -OCH ２ CH２ CH ２ -, -OSi(CH ３ ) ２ CH ２ CH ２ CH ２ -, -OSi(CH ３ ) ２ OSi(CH ３ ) ２ CH ２ CH ２ CH ２ -ien-CH ２ CH ２ CH ２ Si(CH) ３ ) ２ PhSi(CH ３ ) ２ CH ２ CH ２ - is preferable (however, the right side is T) ｂ１ (Combine.)

[0132] w1 is an integer between 0 and 2, preferably 0 or 1, and particularly preferably 0. [-(O) ｕ４ - Q ｂ４ -T ｂ１ If there are two or more [-(O)] ｕ４ - Q ｂ４ -T ｂ１ ] may be the same or different. ３１ If there are two or more (-R ３１ These may be the same or different.

[0133] Base (3-1A-4) [Q ｅ ] ｓ４ - Q ａ４ - (O) ｔ４ -C[-(O) ｕ４ - Q ｂ４ -T ｂ１ ] ３－ｗ１ (-R ３１ ) ｗ１ Specific examples include the following base. In the following formula, * represents Z １ This indicates the connection point with [the other element].

[0134]

[0135] In the base (3-1A-5), Qａ５ This is an alkylene group which may have an etheric oxygen atom. The number of carbon atoms in the alkylene group which may have an etheric oxygen atom is preferably 1 to 10, and particularly preferably 2 to 6. Q ａ５ As for the ease of producing the compound, -OCH ２ CH ２ CH ２ -, -OCH ２ CH ２ OCH ２ CH ２ CH ２ -ien-CH ２ CH ２ -ien-CH ２ CH ２ CH ２ - is preferable (however, the right side is T) ｂ１ (Combine.)

[0136] Q ｂ５ This refers to an alkylene group, or a group having an etheric oxygen atom or a divalent organopolysiloxane group between carbon atoms of an alkylene group having two or more carbon atoms. Q ｂ５ The number of carbon atoms in the alkylene group represented by is preferably 1 to 30, more preferably 1 to 20, even more preferably 2 to 20, and may also be 2 to 10 or 2 to 6. For example, 2, 3, 8, 9, and 11 are given. Also, the above number of carbon atoms may be 1 to 10. Q ｂ５ The number of carbon atoms in the alkylene group having two or more carbon atoms, represented by the formula, is preferably 2 to 20, more preferably 2 to 10, and even more preferably 2 to 6. ｂ５ As for the ease of producing the compound, -CH ２ CH ２ CH ２ -ien-CH ２ CH ２ OCH ２ CH ２ CH ２ - is preferable (however, the right side is T) ｂ１ (Combine.)

[0137] 3 [-Q ｂ５ -T ｂ１These may be the same or different.

[0138] Specific examples of the group (3-1A-5) include the following group. In the following formula, * represents R ｆ１ This indicates the connection point with [the other element].

[0139]

[0140] Q in the base (3-1A-6) ｅ The definition of is as defined in the above-mentioned base (3-1A-4). v is either 0 or 1.

[0141] Q ａ６ This is an alkylene group which may have an etheric oxygen atom. The number of carbon atoms in the alkylene group which may have an etheric oxygen atom is preferably 1 to 10, and particularly preferably 2 to 6. Q ａ６ As for the ease of producing the compound, -CH ２ OCH ２ CH ２ CH ２ -ien-CH ２ OCH ２ CH ２ OCH ２ CH ２ CH ２ -ien-CH ２ CH ２ -ien-CH ２ CH ２ CH ２ - is preferable (however, the right side is Z) ａ (Combine.)

[0142] Z ａ is a (w²+1) valent organopolysiloxane group, or a (w²+1) valent group having an alkylene group between organopolysiloxane groups. w² is an integer from 2 to 7. Examples of (w²+1) valent organopolysiloxane groups and (w²+1) valent groups having an alkylene group between organopolysiloxane groups are listed below. However, R in the following formula ａ This is as described above. * indicates the binding site.

[0143]

[0144] Q ｂ６ This refers to an alkylene group, or a group having an etheric oxygen atom or a divalent organopolysiloxane group between carbon atoms of an alkylene group having two or more carbon atoms. Q ｂ６ The number of carbon atoms in the alkylene group represented by is preferably 1 to 30, more preferably 1 to 20, even more preferably 2 to 20, and may also be 2 to 10 or 2 to 6. For example, 2, 3, 8, 9, and 11 are given. Also, the above number of carbon atoms may be 1 to 10. Q ｂ６ The number of carbon atoms in the alkylene group having two or more carbon atoms, represented by the formula, is preferably 2 to 20, more preferably 2 to 10, and even more preferably 2 to 6. ｂ６ As for the ease of producing the compound, -CH ２ CH ２ -ien-CH ２ CH ２ CH ２ - is preferable. Two [-Q] ｂ６ -T ｂ１ These may be the same or different.

[0145] Base (3-1A-6) - [Q ｅ ] ｖ - Q ａ６ -Z ａ [-Q] ｂ６ -T ｂ１ ] ｗ２ Specific examples include the following base. In the following formula, * represents Z １ This indicates the connection point with [the other element].

[0146]

[0147] In base (3-1A-7), Z ｃ w3 is a (w3 + w4 + 1) valent hydrocarbon group. w3 is an integer greater than or equal to 4. w4 is an integer greater than or equal to 0. Q ｅ s4, Q ａ４ t4, Q ｂ４ The definitions and preferred ranges of u4 and u4 are the same as the definitions of each symbol in base (3-1A-4).

[0148] Z ｃ It may consist of a hydrocarbon chain, and may have etheric oxygen atoms between carbon atoms in the hydrocarbon chain; it is preferable that it consists of a hydrocarbon chain. ｃ The valency is preferably 5 to 20, more preferably 5 to 10, even more preferably 5 to 8, and particularly preferably 5 to 6. ｃ The number of carbon atoms in w3 is preferably 3 to 50, more preferably 4 to 40, and even more preferably 5 to 30. The number of carbon atoms in w3 is preferably 4 to 20, more preferably 4 to 16, even more preferably 4 to 8, and particularly preferably 4 to 5. The number of carbon atoms in w4 is preferably 0 to 10, more preferably 0 to 8, even more preferably 0 to 6, particularly preferably 0 to 3, and most preferably 0 to 1. [-(O-Q ｂ４ ) ｕ４ -T ｂ１ If there are two or more [-(O-Q], then two or more [-(O-Q) ｂ４ ) ｕ４ -T ｂ１ These may be the same or different.

[0149] Base (3-1A-7) - [Q ｅ ] ｓ４ - Q ａ４ - (O) ｔ４ -Z ｃ [-(O-Q) ｂ４ ) ｕ４ -T ｂ１ ] ｗ３ Specific examples include the following base. In the following formula, * represents Z １ This indicates the connection point with [the other element].

[0150]

[0151] Q ｂ１ The base may be (g2-1) (where nb1 = d1 + d3 and mb1 = d2 + d4), base (g2-2) (where nb1 = e1 and mb1 = e2), base (g2-3) (where nb1 = 1 and mb1 = 2), base (g2-4) (where nb1 = h1 and mb1 = h2), base (g2-5) (where nb1 = i1 and mb1 = i2), base (g2-6) (where nb1 = 1 and mb1 = 1), or base (g2-7) (where nb1 = 1 and mb1 = i3).

[0152]

[0153] (-A １ - Q １２ -) ｅ１ C(R ｅ２ ) ４－ｅ１－ｅ２ (-Q ２２ -) ｅ２ (g2-2) -A １ - Q １３ -N(-Q) ２３ -) ２ (g2-3) (-A １ - Q １４ -) ｈ１ Z(-Q) ２４ -) ｈ２ (g2-4) (-A １ - Q １５ -) ｉ１ Si(R ｅ３ ) ４－ｉ１－ｉ２ (-Q ２５ -) ｉ２ (g2-5) -A １ - Q ２６ - (g2-6) -A １ - Q １２ -CH(-Q) ２２ -)-Si(R ｅ３ ) ３－ｉ３ (-Q ２５ -) ｉ３ (g2-7)

[0154] However, in equations (g2-1) to (g2-7), A １ The side is R ｆ１ Combined with Q ２２ Q ２３ Q ２４ Q ２５ Or Q ２６ The side is T ｂ１ It combines with A. １ This is a single bond, -C(=O)NR ｅ６ -, -C(=O)-, -OC(=O)O-, -NHC(=O)O-, -NHC(=O)NR ｅ６ -, -O-, or SO ２ NR ｅ６ - is the case. Q １２This refers to a single bond, an alkylene group, or an alkylene group having two or more carbon atoms with -C(=O)NR between carbon atoms. ６ -, -C(=O)-, -NR ６ A group having - or O-, Q １２ If there are two or more Q １２ They may be the same or different. Q １３ This refers to single bonds, alkylene groups, and alkylene groups with two or more carbon atoms, where -C(=O)NR is the carbon-carbon bond between the carbon atoms. ６ -, -C(=O)-, -NR ６ It is a group having - or -O-, or a group having -C(=O)- at the N-side terminal of an alkylene group. Q １４ Q １４ If the atom at Z to which it is bonded is a carbon atom, then Q １２ Q １４ If the atom at Z to which the bond is formed is a nitrogen atom, then Q １３ Q １４ If there are two or more Q １４ They may be the same or different. Q １５ This refers to an alkylene group, or an alkylene group having 2 or more carbon atoms with -C(=O)NR between carbon atoms. ６ -, -C(=O)-, -NR ６ A group having - or O-, Q １５ If there are two or more Q １５ They may be the same or different. Q ２２ This refers to an alkylene group, an alkylene group with 2 or more carbon atoms, with -C(=O)NR between carbon atoms. ６ -, -C(=O)-, -NR ６ A group having - or O-, an alkylene group T ｂ１ -C(=O)NR on the end that is not connected ６ -, -C(=O)-, -NR ６ A group having - or O-, or an alkylene group having 2 or more carbon atoms with -C(=O)NR between carbon atoms. ６ -, -C(=O)-, -NR ６ - or O- and T ｂ１ -C(=O)NR on the end that is not connected ６-, -C(=O)-, -NR ６ A group having - or -O-, Q ２２ If there are two or more Q ２２ They may be the same or different. Q ２３ This refers to an alkylene group, or an alkylene group having 2 or more carbon atoms with -C(=O)NR between carbon atoms. ６ -, -C(=O)-, -NR ６ A group having - or -O-, and two Q ２３ They may be the same or different. Q ２４ Q ２４ If the atom at Z to which it is bonded is a carbon atom, then Q ２２ Q ２４ If the atom at Z to which the bond is formed is a nitrogen atom, then Q ２３ Q ２４ If there are two or more Q ２４ They may be the same or different. Q ２５ This refers to an alkylene group, or an alkylene group having 2 or more carbon atoms with -C(=O)NR between carbon atoms. ６ -, -C(=O)-, -NR ６ A group having - or O-, Q ２５ If there are two or more Q ２５ They may be the same or different. Q ２６ This refers to an alkylene group, or an alkylene group having 2 or more carbon atoms with -C(=O)NR between carbon atoms. ６ -, -C(=O)-, -NR ６ It is a group having - or -O-. Q ２２ Q ２３ Q ２４ Q ２５ Q ２６ If it is an alkylene group, the number of carbon atoms is preferably 1 to 20, more preferably 1 to 10, and even more preferably 1 to 6. Z is Q １４ It has a carbon or nitrogen atom that is directly bonded to it, and Q ２４ R is a group having a (h1 + h2) valence ring structure with a carbon or nitrogen atom directly bonded to it. ｅ１ is a hydrogen atom or an alkyl group, R ｅ１If there are two or more, then there are two or more R ｅ１ They may be the same or different. ｅ２ R is a hydrogen atom, a hydroxyl group, an alkyl group, or an acyloxy group. ｅ３ R is an alkyl group. ６ These are a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or a phenyl group.

[0155] d1 is an integer between 0 and 3, preferably 1 or 2. d2 is an integer between 0 and 3, preferably 1 or 2. d1 + d2 is an integer between 1 and 3. d3 is an integer between 0 and 3, preferably 0 or 1. d4 is an integer between 0 and 3, preferably 2 or 3. d3 + d4 is an integer between 1 and 3. d1 + d3 is an integer between 1 and 5, preferably 1 or 2. d2 + d4 is an integer between 1 and 5, preferably 2 or 3. e1 + e2 is 3 or 4. e1 is an integer between 1 and 3, preferably 1 or 2. e2 is an integer between 1 and 3, preferably 2 or 3. h1 is an integer of 1 or more, preferably 1 or 2. h2 is an integer of 1 or more, preferably 2 or 3. i1 + i2 is 3 or 4. i1 is an integer between 1 and 3, preferably 1 or 2. i2 is an integer between 1 and 3, preferably 2 or 3. i3 is 2 or 3.

[0156] Q １２ Q １３ Q １４ Q １５ Q ２２ Q ２３ Q ２４ Q ２５ and Q ２６The number of carbon atoms in the alkylene group is preferably 1 to 30, more preferably 1 to 20, even more preferably 2 to 20, and may also be 2 to 10 or 2 to 6, from the standpoint of ease of compound production and superior wear resistance of the surface layer. Examples include 2, 3, 8, 9, and 11. Furthermore, the above number of carbon atoms may also be 1 to 10, 1 to 6, or 1 to 4. However, the lower limit of the number of carbon atoms in the alkylene group when there is a specific bond between carbon atoms is 2.

[0157] The ring structure in Z is the ring structure described above, and the preferred form is also the same. Note that the ring structure in Z is Q １４ Ya Q ２４ Because they bond directly, for example, an alkylene group is linked to the ring structure, and Q is attached to that alkylene group. １４ Ya Q ２４ They will not be connected.

[0158] R ｅ１ , R ｅ２ or R ｅ３ The number of carbon atoms in the alkyl group is preferably 1 to 6, more preferably 1 to 3, and particularly preferably 1 to 2, from the standpoint of facilitating compound production. ｅ２ The number of carbon atoms in the alkyl group portion of the acyloxy group is preferably 1 to 6, more preferably 1 to 3, and particularly preferably 1 to 2, from the standpoint of ease of compound production. For h1, it is preferably 1 to 6, more preferably 1 to 4, even more preferably 1 or 2, and particularly preferably 1, from the standpoint of ease of compound production and superior abrasion resistance of the surface layer. For h2, it is preferably 2 to 6, more preferably 2 to 4, and particularly preferably 2 or 3, from the standpoint of ease of compound production and superior abrasion resistance of the surface layer.

[0159] Q １Other forms include base (g2-8) (where nb1 = d1 + d3, mb1 = d2 × k3 + d4 × k3), base (g2-9) (where nb1 = e1, mb1 = e2 × k3), base (g2-10) (where nb1 = 1, mb1 = 2 × k3), base (g2-11) (where nb1 = h1, mb1 = h2 × k3), base (g2-12) (where nb1 = i1, mb1 = i2 × k3), base (g2-13) (where nb1 = 1, mb1 = k3), or base (g2-14) (where nb1 = 1, mb1 = i3 × k3).

[0160]

[0161] (-A １ - Q １２ -) ｅ１ C(R ｅ２ ) ４－ｅ１－ｅ２ (-Q ２２ -G １ ) ｅ２ (g2-9) -A １ - Q １３ -N(-Q) ２３ -G １ ) ２ (g2-10) (-A １ - Q １４ -) ｈ１ Z(-Q) ２４ -G １ ) ｈ２ (g2-11) (-A １ - Q １５ -) ｉ１ Si(R ｅ３ ) ４－ｉ１－ｉ２ (-Q ２５ -G １ ) ｉ２ (g2-12) -A １ - Q ２６ -G １ (g2-13) -A １ - Q １２ -CH(-Q) ２２ -G １ )-Si(R ｅ３ ) ３－ｉ３ (-Q ２５ -G １ ) ｉ３(g2-14)

[0162] However, in equations (g2-8) to (g2-14), A １ The side is R ｆ１ Combined with G １ The side is T ｂ１ It combines with it.

[0163] G １ The following group (g3) is Q ｂ１ two or more G １ They may be the same or different. G １ The signs other than are the same as the signs in equations (g2-1) to (g2-7). -Si(R ８ ) ３－ｋ３ (-Q ３ -) ｋ３ (g3) However, in the base (g3), the Si side is Q ２２ Q ２３ Q ２４ Q ２５ and Q ２６ Connect to Q ３ The side is T ｂ１ Connect to R. ８ It is an alkyl group. Q ３ This refers to an alkylene group, an alkylene group with 2 or more carbon atoms, with -C(=O)NR between carbon atoms. ６ -, -C(=O)-, -NR ６ - or a group having -O-, or (OSi(R ９ ) ２ ) ｐ -O- and Q is 2 or greater. ３ They may be the same or different. k3 is 2 or 3. R ６ R is a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or a phenyl group. ９ is an alkyl group, a phenyl group, or an alkoxy group, and has two R ９ They may be the same or different. p is an integer from 0 to 5, and if p is 2 or greater, then 2 or greater (OSi(R ９ ) ２ ) may be the same or different.

[0164] Q ３The number of carbon atoms in the alkylene group is preferably 1 to 30, more preferably 1 to 20, even more preferably 2 to 20, and may also be 2 to 10 or 2 to 6, from the standpoint of ease of compound production and superior wear resistance of the surface layer. Examples include 2, 3, 8, 9, and 11. Furthermore, the above number of carbon atoms may be 1 to 10, 1 to 6, or 1 to 4. However, the lower limit of the number of carbon atoms in the alkylene group when there is a specific bond between carbon atoms is 2. ８ The number of carbon atoms in the alkyl group is preferably 1 to 6, more preferably 1 to 3, and even more preferably 1 to 2, from the standpoint of facilitating compound production. ９ The number of carbon atoms in the alkyl group is preferably 1 to 6, more preferably 1 to 3, and even more preferably 1 to 2, from the standpoint of facilitating compound production. ９ The number of carbon atoms in the alkoxy group is preferably 1 to 6, more preferably 1 to 3, and particularly preferably 1 to 2, from the viewpoint of excellent storage stability of the compound. p is preferably 0 or 1.

[0165] As a second compound, for example, the compound shown below is preferred because it is easy to manufacture industrially, easy to handle, and exhibits even better effects than those of the present disclosure. R in the compound shown below ｔ (R) in equation (2-1) ｆ１ It is similar to ) and the preferred form is also similar.

[0166] Q in equation (2-1) ｂ１ Examples of compounds in which the group (g2-1) is shown below include the following compounds.

[0167]

[0168] Q in equation (2-1) ｂ１ Examples of compounds in which the group (g2-2) is shown below. In the formula below, Ak means an alkyl group (for example, an alkyl group having 1 to 15 carbon atoms).

[0169]

[0170]

[0171] Q in equation (2-1)ｂ１ Examples of compounds in which the group (g2-3) is shown below include the following compounds.

[0172]

[0173] Q in equation (2-1) ｂ１ Examples of compounds in which the group (g2-4) is shown below include the following compounds.

[0174]

[0175] Q in equation (2-1) ｂ１ Examples of compounds in which the group (g2-5) is shown below include the following compounds.

[0176]

[0177] Q in equation (2-1) ｂ１ Examples of compounds in which the group (g2-6) is shown below include the following compounds.

[0178]

[0179] Q in equation (2-1) ｂ１ Examples of compounds in which the group (g2-7) is shown below include the following compounds.

[0180]

[0181] Q in equation (2-1) ｂ１ Examples of compounds in which the group (g2-8) is shown below include the following compounds.

[0182]

[0183] Q in equation (2-1) ｂ１ Examples of compounds in which the group (g2-9) is shown below include the following compounds.

[0184]

[0185] Q in equation (2-1) ｂ１ Examples of compounds in which the group (g2-10) is shown below include the following compounds.

[0186]

[0187] Q in equation (2-1) ｂ１ Examples of compounds in which the group (g2-11) is shown below include the following compounds.

[0188]

[0189] Q in equation (2-1) ｂ１ Examples of compounds in which the group (g2-12) is shown below include the following compounds.

[0190]

[0191] Q in equation (2-1) ｂ１ Examples of compounds in which the group (g2-13) is shown below include the following compounds.

[0192]

[0193] Q in equation (2-1) ｂ１ Examples of compounds in which the group (g2-14) is shown below include the following compounds.

[0194]

[0195] Specific examples of the second compound include, but are not limited to, the following compounds. In the formula, n is an integer of 1 or more, preferably an integer between 1 and 250, more preferably an integer between 5 and 250, and even more preferably an integer between 5 and 50. It may also be an integer between 1 and 50, or an integer between 5 and 30. For example, 10, 14, 15, 20, 23, and 25 are given. The same applies to the following. In the formula, x5 is an integer between 0 and 30.

[0196]

[0197]

[0198] Rf １１１ The above Rf １Similar examples can be given. Among them, the base represented by the following formula is preferred. In the formula, x11, x21, x31, and x41 are each independent integers of 1 or more, preferably integers from 1 to 250, more preferably integers from 5 to 250, and even more preferably integers from 5 to 50. They may also be integers from 1 to 50, or integers from 5 to 30. For example, 10, 14, 15, 20, 23, and 25 can be given. * indicates the bonding position.

[0199]

[0200]

[0201]

[0202]

[0203]

[0204]

[0205]

[0206] The composition preferably includes, as a second compound, the compound represented by formula (2-1) in terms of superior effects of the present disclosure.

[0207] The content of the second compound is preferably 0.1 to 99.9% by mass, more preferably 1 to 99% by mass, and even more preferably 10 to 50% by mass, based on the total amount of the composition. If the content of the second compound is above the lower limit, the abrasion resistance of the surface layer is better. If the content of the first compound is below the upper limit, the water-repellent and oil-repellent properties of the surface layer are better.

[0208] In this composition, the mass ratio of the content of the first compound to the content of the second compound (content of the first compound / content of the second compound) is preferably 0.1 / 99.9 to 99.9 / 0.1, more preferably 1 / 99 to 99 / 1, even more preferably 10 / 90 to 90 / 10, and particularly preferably 50 / 50 to 90 / 10. If the above mass ratio is above the lower limit, the water-repellent and oil-repellent properties of the surface layer are better. If the above mass ratio is below the upper limit, the abrasion resistance of the surface layer is better. Other preferred ranges include the mass ratio of the content of the first compound to the content of the second compound (content of the first compound / content of the second compound) in this composition, which is preferably 70.000 / 30.000 to 99.999 / 0.001, more preferably 80.000 / 20.000 to 99.997 / 0.003, and even more preferably 90.000 / 10.000 to 99.995 / 0.005. If the above mass ratio is above the lower limit, the water-repellent and oil-repellent properties of the surface layer are better. If the above mass ratio is below the upper limit, the abrasion resistance of the surface layer is better.

[0209] <Liquid Medium> This composition may further contain a liquid medium. When this composition contains a liquid medium, it may be a solution or a dispersion. This composition containing a liquid medium is useful for coating applications and can be used as a coating liquid.

[0210] As the liquid medium, an organic solvent is preferred. The organic solvent may be a fluorine-containing organic solvent, a non-fluorine-containing organic solvent, or a mixture of both. Specific examples of fluorine-containing organic solvents include fluorinated alkanes, fluorinated aromatic compounds, fluoroalkyl ethers, fluorinated alkylamines, fluoroalcohols, and hydrofluoroolefins (HFOs). As fluorinated alkanes, compounds having 4 to 8 carbon atoms are preferred. Specific examples of commercially available products include C ６ F １３ H (AGC Corporation, Asahi Clean® AC-2000), C ６ F １３ C ２ H ５ (Manufactured by AGC Corporation, Asahi Clean® AC-6000), C ２ F５ CHFCHFCF ３ (Chemours Bartrell® XF) is one example. Specific examples of fluorinated aromatic compounds include hexafluorobenzene, trifluoromethylbenzene, perfluorotoluene, and bis(trifluoromethyl)benzene. As for fluoroalkyl ethers, compounds with 4 to 12 carbon atoms are preferred. A specific example of a commercially available product is CF ３ CH ２ OCF ２ CF ２ H (manufactured by AGC Corporation, Asahi Clean® AE-3000), C ４ F ９ OCH ３ (Manufactured by 3M, Novec® 7100), C ４ F ９ OC ２ H ５ (Manufactured by 3M, Novec® 7200), C ２ F ５ CF(OCH) ３ ) C ３ F ７ (Novec® 7300, manufactured by 3M) is one example. Specific examples of fluorinated alkylamines include perfluorotripropylamine and perfluorotributylamine. Specific examples of fluoroalcohols include 2,2,3,3-tetrafluoropropanol, 2,2,2-trifluoroethanol, and hexafluoroisopropanol. Specific examples of HFOs include 1-chloro-2,3,3-trifluoro-1-propene (HCFO-1233yd) (Amorea® AS-300, manufactured by AGC). As non-fluorinated organic solvents, compounds consisting only of hydrogen atoms and carbon atoms, and compounds consisting only of hydrogen atoms, carbon atoms, and oxygen atoms are preferred, and examples include hydrocarbon organic solvents, alcohol organic solvents, ketone organic solvents, ether organic solvents, ester organic solvents, and glycol organic solvents.

[0211] Specific examples of hydrocarbon organic solvents include pentane, hexane, heptane, octane, hexadecane, isohexane, isooctane, isononane, cycloheptane, cyclohexane, bicyclohexyl, benzene, toluene, ethylbenzene, o-xylene, m-xylene, p-xylene, o-diethylbenzene, m-diethylbenzene, p-diethylbenzene, n-butylbenzene, sec-butylbenzene, and tert-butylbenzene.

[0212] Specific examples of alcoholic organic solvents include methanol, ethanol, 1-propanol, isopropyl alcohol, n-butanol, diacetone alcohol, isobutanol, sec-butanol, tert-butanol, pentanol, 3-methyl-1,3-butanediol, 1,3-butanediol, 1,3-butylene glycol, octanediol, 2,4-diethylpentanediol, butylethylpropanediol, 2-methyl-1,3-propanediol, 4-hydroxy-4-methyl-2-pentanone, 2-ethyl-1-hexanol, 3,5,5-trimethyl-1-hexanol, isodecanol, isotridecanol, 3-methoxy-3-methyl-1-butanol, 2-methoxybutanol, 3-methoxybutanol, cyclohexanol, furfuryl alcohol, tetrahydrofurfuryl alcohol, benzyl alcohol, and methylcyclohexanol.

[0213] Specific examples of ketone organic solvents include acetone, methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, cyclohexanone, 2-heptanone, 4-heptanone, 3,5,5-trimethyl-2-cyclohexen-1-one, and 3,3,5-trimethylcyclohexanone and isophorone.

[0214] Specific examples of ether-based organic solvents include diethyl ether, cyclopentyl methyl ether, tetrahydrofuran, and 1,4-dioxane.

[0215] Specific examples of ester-based organic solvents include methyl acetate, ethyl acetate, propyl acetate, isopropyl acetate, butyl acetate, isobutyl acetate, tert-butyl acetate, amyl acetate, isoamyl acetate, ethyl 3-ethoxypropionate, ethyl lactate, ethylene glycol monobutyl ether acetate, diethylene glycol monobutyl ether acetate, propylene glycol monomethyl ether acetate, dipropylene glycol methyl ether acetate, 3-methoxy-3-methylbutyl acetate, 3-methoxybutyl acetate, propylene glycol monomethyl acetate, propylene glycol dimethyl acetate, and ethylene glycol monoethyl ether acetate. Examples include tate, ethylene glycol monomethyl ether acetate, diethylene glycol monoethyl ether acetate, cyclohexanol acetate, propylene glycol diacetate, propylene glycol monomethyl ether propionate, propylene glycol monoethyl ether acetate, propylene glycol monobutyl ether acetate, propylene glycol monopropyl ether acetate, 1,3-butylene glycol diacetate, 1,4-butanediol diacetate, 1,6-hexanediol diacetate, γ-butyrolactone, triacetin, and 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate.

[0216] Specific examples of glycol-based organic solvents include ethylene glycol, ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, triethylene glycol monobutyl ether, tetraethylene glycol monobutyl ether, ethylene glycol monohexyl ether, diethylene glycol monohexyl ether, ethylene glycol mono-2-ethylhexyl ether, diethylene glycol mono-2-ethylhexyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, propylene glycol monopropyl ether, ethylene glycol monoisopropyl ether, ethylene glycol monoethyl ether, ethylene glycol monotert-butyl ether, ethylene glycol monopropyl ether, ethylene glycol monomethyl ether, diethylene glycol monoisopropyl ether, and diethylene glycol monobutyl ether. Examples include propylene glycol monomethyl ether, dipropylene glycol monoethyl ether, dipropylene glycol monobutyl ether, dipropylene glycol monopropyl ether, dipropylene glycol monomethyl ether, tripropylene glycol monobutyl ether, tripropylene glycol monomethyl ether, propylene glycol monophenyl ether, 1,3-butylene glycol, diethylene glycol monoethyl ether, tripropylene glycol methyl ether, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene glycol dibutyl ether, diethylene glycol diethyl ether, diethylene glycol dimethyl ether, dipropylene glycol dimethyl ether, diethylene glycol dibutyl ether, tetraethylene glycol dimethyl ether, triethylene glycol dimethyl ether, and polyethylene glycol dimethyl ether.

[0217] Other organic solvents include chlorinated organic solvents, nitrogen-containing compounds, sulfur-containing compounds, and siloxane compounds.

[0218] Specific examples of chlorinated organic solvents include dichloromethane, chloroform, carbon tetrachloride, 1,2-dichloroethane, chlorobenzene, o-chlorotoluene, m-chlorotoluene, p-chlorotoluene, m-dichlorobenzene, and 1,2,3-trichloropropane.

[0219] Specific examples of nitrogen-containing compounds include nitrobenzene, acetonitrile, benzonitrile, N,N-dimethylformamide, N,N-dimethylacetamide, N-methylpyrrolidone, and 1,3-dimethyl-2-imidazolidinone.

[0220] Specific examples of sulfur-containing compounds include carbon disulfide and dimethyl sulfoxide.

[0221] Specific examples of siloxane compounds include hexamethyldisiloxane, octamethyltrisiloxane, and decamethyltetrasiloxane.

[0222] The liquid medium contained in this composition may be one type or two or more types. When this composition contains a liquid medium, the content of the liquid medium is preferably 60 to 99.999% by mass, more preferably 80 to 99.99% by mass, and even more preferably 90 to 99.9% by mass, based on the total amount of the composition. When this composition is used in a wet coating method, the content of the liquid medium is preferably 90 to 99.99% by mass, more preferably 95 to 99.98% by mass, even more preferably 97 to 99.97% by mass, and particularly preferably 98 to 99.95% by mass, based on the total amount of the composition.

[0223] <Other Components> The composition may further contain other components besides the first compound, the second compound, and the liquid medium, to the extent that they do not impair the effects of the present disclosure. Examples of other components include additives, specifically catalysts such as acid catalysts and base catalysts that promote the hydrolysis and condensation reactions of reactive silyl groups.

[0224] Any suitable acid or base, transition metals (e.g., Ti, Ni, Sn, Zr, Al, B, etc.), sulfur-containing compounds having lone pairs of electrons in their molecular structure, nitrogen-containing compounds (e.g., sulfoxide compounds, aliphatic amine compounds, aromatic amine compounds, phosphate amide compounds, amide compounds, urea compounds), etc. can be used as catalysts. Examples of acid catalysts include acetic acid, formic acid, trifluoroacetic acid, hydrochloric acid, nitric acid, sulfuric acid, phosphoric acid, sulfonic acid, methanesulfonic acid, and p-toluenesulfonic acid. Examples of base catalysts include ammonia, sodium hydroxide, potassium hydroxide; and organic amines such as triethylamine and diethylamine.

[0225] Other components include metal compounds having hydrolyzable groups. When a surface treatment agent contains metal compounds having hydrolyzable groups, the slipperiness and antifouling properties of the surface layer can be further improved.

[0226] The content of other components that may be included in the surface treatment agent is preferably 10% by mass or less, and more preferably 1% by mass or less, relative to the total mass of the surface treatment agent. If the surface treatment agent contains the above-mentioned metal compound, the content of the above-mentioned metal compound is preferably 0.01 to 30% by mass, more preferably 0.01 to 10% by mass, and even more preferably 0.05 to 5% by mass, relative to the total mass of the surface treatment agent.

[0227] The total content of the first compound, the second compound, and other components (hereinafter also referred to as "solid content concentration") is preferably 0.001 to 40% by mass, more preferably 0.01 to 20% by mass, and even more preferably 0.1 to 10% by mass, based on the total mass of the surface treatment agent. The solid content concentration of the surface treatment agent is calculated from the mass before heating and the mass after heating in a convection dryer at 120°C for 4 hours.

[0228] [Surface Treatment Agent] In one embodiment, the surface treatment agent of the present disclosure (hereinafter also referred to as "the surface treatment agent") comprises the composition of the present disclosure. The surface treatment agent may also be the composition of the present disclosure. Preferred embodiments of the surface treatment agent are the same as preferred embodiments of the composition of the present disclosure.

[0229] This surface treatment agent is suitable for applications requiring sweat resistance, such as forming a surface layer on components that make up the touch surfaces of touch panels, eyeglass lenses, and displays of wearable devices. Furthermore, due to its excellent sweat resistance, this surface treatment agent is also suitable for use on glass-coated casings of portable devices such as smartphones and tablet terminals. This surface treatment agent is also suitable for use as an anti-fouling or waterproof coating agent.

[0230] [Article] In one embodiment, the article of the present disclosure (hereinafter also referred to as "the Article") has a surface layer formed using the surface treatment agent on the surface of a substrate. Preferably, the Article has a substrate and the above-mentioned surface layer.

[0231] The surface layer may be formed on a part of the surface of the substrate or on the entire surface of the substrate. The surface layer may spread as a film on the surface of the substrate or may be scattered as dots. In the surface layer, the first compound is contained in a state in which hydrolysis of some or all of the reactive silyl groups has progressed and the dehydration condensation reaction of the silanol groups has progressed.

[0232] The thickness of the surface layer is preferably 1 to 100 nm, and more preferably 1 to 50 nm. If the thickness of the surface layer is 1 nm or more, the effect of the surface layer is easily obtained. If the thickness of the surface layer is 100 nm or less, the utilization efficiency is high. The thickness of the surface layer can be calculated from the vibration period of the interference pattern obtained by the X-ray reflectivity method using an X-ray diffractometer for thin film analysis (product name "ATX-G", manufactured by RIGAKU Corporation).

[0233] The surface layer may be provided directly on the surface of the substrate, or a base layer may be provided between the substrate and the surface layer. From the viewpoint of further improving the water repellency and abrasion resistance of the surface layer, it is preferable that the article includes a substrate, a base layer disposed on the substrate, and a surface layer formed using the surface treatment agent disposed on the base layer.

[0234] An example of this article will be described with reference to the drawings. Figure 1 is a schematic cross-sectional view showing a first article, which is an example of this article. The first article is an article 20 having a base material 12, a base layer 14, and a surface layer 22 in that order, wherein the base layer 14 contains an oxide containing silicon, and the surface layer 22 is a surface layer formed using this surface treatment agent.

[0235] The material and shape of the base material 12 may be appropriately selected according to the intended use of the article 20. The type of base material is not particularly limited; for example, a base material for which sweat resistance is required can be used. Examples of base materials include base materials that may be used in contact with human fingers; base materials that may be held by human fingers during operation; and base materials that may be placed on other articles (e.g., a stand). Examples of materials for the base material 12 include glass, resin, sapphire, metal, ceramic, stone, and composite materials thereof. Glass may be chemically strengthened. Examples of base materials 12 for which water-repellent and oil-repellent properties are particularly required include base materials for touch panels, base materials for displays, base materials that constitute the housing of electronic devices, and eyeglass lenses. The base materials for touch panels and display base materials are translucent. "Translucent" means that the normal incidence visible light transmittance in accordance with JIS R3106:1998 (ISO 9050:1990) is 25% or more. Glass or transparent resin is preferred as the material for the base material for touch panels.

[0236] The substrate 12 may have surface treatments such as corona discharge treatment, plasma treatment, or plasma graft polymerization treatment applied to the surface on which the underlayer 14 is provided. Surface treatment further improves the adhesion between the substrate 12 and the underlayer 14, and as a result, the abrasion resistance of the surface layer 22 is further improved. As for the surface treatment, corona discharge treatment or plasma treatment is preferred because it further improves the abrasion resistance of the surface layer 22.

[0237] The base layer 14 is a layer containing an oxide that includes at least silicon, and may also contain other elements. By including silanol groups on the surface of the base layer 14, the hydrolyzable silyl groups of the compound undergo dehydration condensation, forming Si-O-Si bonds between the base layer 14 and the surface layer 22, which has superior abrasion resistance.

[0238] The silicon dioxide content in the base layer 14 is preferably 65% ​​by mass or more, more preferably 80% by mass or more, even more preferably 85% by mass or more, and particularly preferably 90% by mass or more. If the silicon dioxide content is above the lower limit of the above range, sufficient Si-O-Si bonds are formed in the base layer 14, and the mechanical properties of the base layer 14 are sufficiently ensured. The silicon dioxide content is the remainder obtained by subtracting the total content of other elements (or the sum of the amounts converted to oxides in the case of oxides) from the mass of the base layer 14.

[0239] From the standpoint of excellent wear resistance of the surface layer 22, it is preferable that the oxide in the base layer 14 further contains one or more elements selected from alkali metal elements, alkaline earth metal elements, platinum group elements, boron, aluminum, phosphorus, titanium, zirconium, iron, nickel, chromium, molybdenum, and tungsten. The inclusion of these elements strengthens the bond between the base layer 14 and the compound, improving wear resistance.

[0240] To improve the adhesion of this surface treatment agent and to improve the water-repellent, oil-repellent, and abrasion-resistant properties of article 20, the base layer 14 is preferably a silicon oxide layer containing alkali metal atoms. In the silicon oxide layer, the average concentration of alkali metal atoms in the region at a depth of 0.1 to 0.3 nm from the surface in contact with the surface layer 22 is 2.0 × 10⁻¹⁶. １９ atoms / cm ３ The above is preferable. On the other hand, in order to ensure sufficient mechanical properties of the underlying layer, the average value of the alkali metal atom concentration should be 4.0 × 10 ２２ atoms / cm ３ The following is preferable:

[0241] The base layer may be a single layer or multiple layers. The base layer may have irregularities on its surface. The thickness of the base layer 14 is preferably 1 to 200 nm, and more preferably 2 to 20 nm. If the thickness of the base layer 14 is above the lower limit of the above range, the effect of improving adhesion by the base layer 14 is likely to be sufficiently obtained. If the thickness of the base layer 14 is below the upper limit of the above range, the abrasion resistance of the base layer 14 itself will be increased. Methods for measuring the thickness of the base layer 14 include cross-sectional observation of the base layer 14 using an electron microscope (SEM, TEM, etc.), and methods using an optical interferometer, spectroscopic ellipsometer, step meter, etc.

[0242] Specific examples of methods for forming the underlayer 14 include a method of depositing a vapor deposition material having the desired underlayer 14 composition onto the surface of the substrate 12. One example of a vapor deposition method is the vacuum vapor deposition method. The vacuum vapor deposition method involves evaporating the vapor deposition material in a vacuum chamber and depositing it onto the surface of the substrate 12. The temperature during vapor deposition (for example, the temperature of the boat in which the vapor deposition material is placed when using a vacuum vapor deposition apparatus) is preferably 100 to 3,000°C, and more preferably 500 to 3,000°C. The pressure during vapor deposition (for example, the absolute pressure in the chamber in which the vapor deposition material is placed when using a vacuum vapor deposition apparatus) is preferably 1 Pa or less, and more preferably 0.1 Pa or less. When forming the underlayer 14 using a vapor deposition material, one vapor deposition material may be used, or two or more vapor deposition materials containing different elements may be used. Examples of evaporation methods for the vapor deposition material include the resistance heating method, in which the vapor deposition material is melted and evaporated on a resistance heating boat made of high melting point metal, and the electron gun method, in which an electron beam is irradiated onto the vapor deposition material to directly heat the material, melt the surface, and evaporate it. As a method for evaporating the deposition material, the electron gun method is preferred because it allows for localized heating, enabling the evaporation of high-melting-point substances, and because the temperature is low in areas not exposed to the electron beam, eliminating the risk of reaction with the container or contamination by impurities. As the deposition material used in the electron gun method, molten granules or sintered bodies are preferred because they are less likely to scatter even if an airflow is generated.

[0243] Another example of this article is a second article. The second article is an article 20 having a substrate 10 with a base layer and a surface layer 22 in that order, wherein the substrate 10 with the base layer contains a silicon-containing oxide, and the surface layer 22 is a surface layer formed using this surface treatment agent.

[0244] In the second article, since the substrate 10 with the underlayer has the same composition as the underlayer 14 in the first article, the surface layer 22 has excellent abrasion resistance even when the surface layer 22 is directly formed on the substrate 10 with the underlayer. The material of the substrate 10 with the underlayer in the second article can be any material having the same composition as the underlayer 14, for example, a glass substrate. Details of the material of the substrate 10 with the underlayer are the same as those of the substrate 12 and the underlayer 14, so the explanation is omitted here. Also, the composition of the surface layer 22 is the same as that of the first article, so the explanation is omitted here.

[0245] Specific examples of this article include optical components (for example, optical components used as part of the products listed below), touch panels, anti-reflective films, anti-reflective glass, and SiO2. ２ Examples include processed glass, tempered glass, sapphire glass, quartz substrates, and mold metals. Products include: car navigation systems, mobile phones, digital cameras, digital video cameras, personal digital assistants (PDAs), portable audio players, car audio systems, gaming devices, eyeglass lenses, camera lenses, lens filters, sunglasses, medical equipment (endoscopes, etc.), photocopiers, personal computers (PCs), liquid crystal displays, organic EL displays, plasma displays, touch panel displays, protective films, anti-reflective films, anti-reflective glass, nanoimprint templates, molds, etc.

[0246] [Method for Manufacturing Articles] One method for manufacturing articles is to use this surface treatment agent to form a surface layer on the surface of a substrate, thereby manufacturing an article having a substrate and a surface layer. Methods for forming the surface layer include dry coating and wet coating.

[0247] This surface treatment agent can be used directly in dry coating methods and is suitable for forming a surface layer with excellent adhesion by dry coating. Examples of dry coating methods include vacuum deposition, CVD, and sputtering. Vacuum deposition is preferably used because it suppresses the decomposition of this surface treatment agent and because of the simplicity of the equipment. For vacuum deposition, a pellet-like material may be used in which the first compound and the second compound, etc., are supported using this composition on a porous metal body made of a metal material such as iron or steel. The pellet-like material on which the above compounds are supported can be manufactured by impregnating the porous metal body with this composition containing a liquid medium and drying to remove the liquid medium.

[0248] This surface treatment agent (coating solution) containing a liquid medium can be suitably used in wet coating methods. Examples of wet coating methods include spin coating, wipe coating, spray coating, squeegee coating, dip coating, die coating, inkjet coating, flow coating, roll coating, casting, Langmuir-Bludget coating, and gravure coating.

[0249] To improve the abrasion resistance of the surface layer, operations to promote the reaction between the first and second compounds contained in this composition and the substrate may be performed as needed. Such operations include heating, humidification, and light irradiation. For example, heating a substrate on which a surface layer has been formed in a humid atmosphere can promote reactions such as the hydrolysis of hydrolyzable groups, the reaction between hydroxyl groups on the surface of the substrate and silanol groups, and the formation of siloxane bonds through the condensation reaction of silanol groups. After the formation of the surface layer, compounds in the surface layer that are not chemically bonded to other compounds or the substrate may be removed as needed. Methods of removal include, for example, pouring a solvent onto the surface layer or wiping it with a cloth soaked in a solvent.

[0250] The present invention will be described in detail below with reference to examples. Examples 1 to 12 are examples, and Examples 13 to 17 are comparative examples. However, the present invention is not limited to these examples. The amounts of each component in the table below are given on a mass basis.

[0251] [Compound 1-1A] <Synthesis of Compound A> 65 g of hexamethylcyclotrisiloxane was mixed with 101 g of THF (tetrahydrofuran) and stirred at 25°C until dissolved. The reaction mixture was then cooled to -30°C, and 100 mL of methyllithium (3.1 M in diethoxymethane) was added and the mixture was stirred at -30°C for 2 hours. Next, 100 g of chlorodimethylsilane was added and the mixture was stirred at -30°C for 1 hour, then the temperature was raised to 25°C and stirred for another hour. After removing the low-boiling point components by distillation, hexane and water were added for extraction, and then the mixture was purified by distillation to obtain 65 g of Compound A. The structure of Compound A was confirmed from the following NMR data. The structures of each compound described later were also confirmed in the same way using NMR data.

[0252]

[0253] (NMR data of compound A) 1 H NMR (400 MHz, CDCl3) δ 4.71 (p, J = 2.8 Hz, 1H), 0.50 - -0.23 (m, 27H).

[0254] <Synthesis of Compound B> Compound A (1.0 g) was mixed with dichloromethane (20 g) and 18-bromo-1-octadecene (1.0 g) and stirred at 25°C until homogeneous. Next, a toluene solution of platinum / 1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex (platinum content: 3% by mass, 4.1 mg) was added and stirred at 25°C for 2 hours. After removing the low-boiling components under reduced pressure, 1.5 g of compound B was obtained by flash column chromatography using silica gel (developing solvent: decane / dichloromethane).

[0255]

[0256] (NMR data of compound B) 1 H NMR (400 MHz, CDCl3) δ 3.41 (t, J = 6.9 Hz, 2H), 1.94 - 1.78 (m, 2H), 1.52 - 1.10 (m, 30H), 0.53 (t, J = 7.7 Hz, 2H), 0.39 - -0.24 (m, 27H).

[0257] <Synthesis of Compound C> 11-bromo-1-undecene (2.0 g) was mixed with THF (20 g) and magnesium (1.1 g) and stirred at 60°C for 2 hours. After removing the magnesium residue by filtration of the reaction mixture, the reaction mixture was cooled to 0°C, and compound B (1.5 g) and tetrachlorocopper(II) dilithium solution (0.1 M in THF, 0.05 g) were added and stirred at 0°C for 24 hours. After extraction with hydrochloric acid and decane, low-boiling point components were removed by vacuum distillation, and 1.1 g of compound C was obtained by flash column chromatography using silica gel (developing solvent: decane).

[0258]

[0259] (NMR data of compound C) 1 H NMR (400 MHz, CDCl3) δ 6.00 - 5.67 (m, 1H), 5.15 - 4.67 (m, 2H), 2.19 - 1.86 (m, 2H), 1.55 - 1.08 (m, 50H), 0.53 (dd, J = 10.0, 5.3 Hz, 2H), 0.39 - -0.24 (m, 27H).

[0260] <Synthesis of Compound 1-1A> Compound C (1.1 g) was dissolved in decane (10 g). Then, a toluene solution of platinum / 1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex (platinum content: 3% by mass, 4.1 mg), aniline (2.6 mg), and trimethoxysilane (0.60 g) were added, and the mixture was stirred at 50°C for 2 hours. By removing the solvent under reduced pressure, 1.3 g of compound 1-1A was obtained.

[0261]

[0262] (NMR data of compound 1-1A) 1 H NMR (400 MHz, CDCl3) δ 3.48 (s, 9H), 1.50 - 1.01 (m, 54H), 0.63 - 0.51 (m, 2H), 0.44 (t, J = 7.7 Hz, 2H), 0.39 - -0.24 (m, 27H).

[0263] [Compound 1-1B] Compound C (1.1 g) was dissolved in decane (10 g). Then, a toluene solution of platinum / 1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex (platinum content: 3% by mass, 4.1 mg), aniline (2.6 mg), and dimethoxysilyltrimethylsilicate (1.0 g) were added, and the mixture was stirred at 50°C for 2 hours. By removing the solvent under reduced pressure, 1.3 g of compound 1-1B was obtained.

[0264]

[0265] (NMR data of compound 1-1B) 1 H NMR (400 MHz, CDCl3) δ 3.72-3.21 (m, 15H), 1.58 - 1.04 (m, 54H), 0.85-0.43(m, 4H), 0.12- -0.15 (m, 27H).

[0266] [Compound 1-1C] Compound 1-1C was obtained according to the method described in International Publication No. 2023 / 017830. The number "18" in the formula represents the average value of the repeating units.

[0267]

[0268] [Compound 1-1D] <Synthesis of Compound D> Allyl magnesium chloride (approximately 11% tetrahydrofuran solution, approximately 1.0 mol / L) (20 mL), compound B (1.0 g), and tetrachlorocopper(II) dilithium solution (0.1 M in THF, 0.05 g) were added and stirred at 0°C for 24 hours. Hydrochloric acid and decane were added for extraction, and low-boiling point components were removed by reduced pressure distillation. Then, 0.7 g of compound D was obtained by flash column chromatography using silica gel (developing solvent: decane).

[0269]

[0270] (NMR data of compound D) 1H NMR (400 MHz, CDCl3) δ 6.00 - 5.69 (m, 1H), 5.21 - 4.64 (m, 2H), 2.11 - 1.85 (m, 2H), 1.55 - 1.08 (m, 34H), 0.63-0.45 (m, 2H), 0.39 - -0.24 (m, 27H).

[0271] <Synthesis of Compound 1-1D> Compound D (0.7 g) was dissolved in decane (10 g). Then, a toluene solution of platinum / 1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex (platinum content: 3% by mass, 4.1 mg), aniline (2.6 mg), and dimethoxysilyltrimethylsilicate (0.60 g) were added, and the mixture was stirred at 50°C for 2 hours. By removing the solvent under reduced pressure, 0.9 g of compound 1-1D was obtained.

[0272]

[0273] (NMR data of compound 1-1D) 1 H NMR (400 MHz, CDCl3) δ 3.72-3.43 (m, 15H), 1.58 - 1.04 (m, 38H), 0.85-0.43(m, 4H), 0.12- -0.15 (m, 27H).

[0274] [Compound 1-1E] <Synthesis of Compound E> Compound A (1.0 g) was mixed with dichloromethane (20 g) and 1,9-decadiene (5.0 g) and stirred at 25°C until homogeneous. Next, a toluene solution of platinum / 1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex (platinum content: 3% by mass, 4.1 mg) was added and stirred at 25°C for 2 hours. After removing the low-boiling point components under reduced pressure, 0.7 g of compound E was obtained by flash column chromatography using silica gel (developing solvent: decane / dichloromethane).

[0275]

[0276] (NMR data of compound E) 1H NMR (400 MHz, CDCl3) δ 6.02 - 5.74 (m, 1H), 5.19 - 4.72 (m, 2H), 2.15 - 1.80 (m, 2H), 1.55 - 1.08 (m, 12H), 0.63-0.45 (m, 2H), 0.39 - -0.24 (m, 27H).

[0277] <Synthesis of Compound 1-1E> Compound E (0.7 g) was dissolved in decane (10 g). Then, a toluene solution of platinum / 1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex (platinum content: 3% by mass, 4.1 mg), aniline (2.6 mg), and dimethoxysilyltrimethylsilicate (0.60 g) were added, and the mixture was stirred at 50°C for 2 hours. By removing the solvent under reduced pressure, 1.1 g of compound 1-1E was obtained.

[0278]

[0279] (NMR data of compound 1-1E) 1 H NMR (400 MHz, CDCl3) δ 3.72-3.43 (m, 15H), 1.61 - 1.07 (m, 16H), 0.88-0.43(m, 4H), 0.12- -0.15 (m, 27H).

[0280] [Compound 2-1A] Compound 2-1A was obtained according to the method described in International Publication No. 2018 / 056413. Note that "23", the number of repeating units in the formula, is the average value.

[0281]

[0282] [Compound 2-1B] Compound 2-1B was obtained according to the method described in International Publication No. 2021 / 251396. The average number of repeating units X1 was 14.

[0283]

[0284] [Compound 2-1C] <Synthesis of Compound F> Add methanol (20 g) and AE-3000 (general name: HFE-347pc-f) (20 g) to 2,2,4,4,6,6,8,8,10,10,10-Undecafluoro-3,5,7,9-tetraoxadecanoyl fluoride (5.0 g), stir at 20°C for 12 hours, then NaBH ４ (5g) was added and stirred at 20°C for 2 hours. After adding hydrochloric acid, the organic layer was extracted and the low-boiling components were removed by vacuum distillation. To the obtained crude solution, AE-3000 (20g), 2,6-lutidine (3.0g), and trifluoromethanesulfonic anhydride (5.0g) were added and stirred at 20°C for 2 hours. After adding hydrochloric acid, the organic layer was extracted and the low-boiling components were removed by vacuum distillation, and then 3.5g of compound F was obtained by flash column chromatography using silica gel (developing solvent: AC-6000 / AE-3000). AE-3000 is Asahi Clean® AE-3000 (manufactured by AGC Corporation), and AE-6000 is Asahi Clean® AE-6000 (manufactured by AGC Corporation). In the following formula, Tf is a trifluoromethylsulfonyl group (CF ３ SO ２ It means -).

[0285]

[0286] (NMR data of compound F) 1 H NMR (400 MHz, CDCl3) δ 5.03-4.55 (m, 2H).

[0287] <Synthesis of Compound G> 6.0 g of 18-bromo-1-octadecene was mixed with 30 g of THF (tetrahydrofuran) and 1.1 g of magnesium, and the mixture was stirred at 60°C for 2 hours. After filtering the reaction mixture to remove the magnesium residue, 3.5 g of compound F, 0.1 g of copper(II) chloride, and 15 g of AE-3000 were added, and the mixture was stirred at 50°C for 24 hours. After extraction with hydrochloric acid and removal of low-boiling components under reduced pressure, 2.1 g of compound G was obtained by flash column chromatography using silica gel (developing solvent: AC-6000 / AE-3000).

[0288]

[0289] (NMR data of compound G) 1 H NMR (400 MHz, CDCl3) δ 5.90-5.61 (m, 1H), 5.19 - 4.82 (m, 2H), 2.42 - 1.87 (m, 4H), 1.56 - 1.07 (m, 30H).

[0290] <Synthesis of Compound 2-1C> Compound G (0.5 g) was dissolved in decane (10 g). Then, a toluene solution of platinum / 1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex (platinum content: 3% by mass, 4.1 mg), aniline (2.6 mg), and trimethoxysilane (0.60 g) were added, and the mixture was stirred at 50°C for 2 hours. By removing the solvent under reduced pressure, 0.6 g of compound 2-1C was obtained.

[0291]

[0292] (NMR data of compound 2-1C) 1 H NMR (400 MHz, CDCl3) δ 3.58 (s, 9H), 2.24 (tt, J = 14.1, 7.0 Hz, 2H), 1.61 - 1.08 (m, 34H), 0.65 (t, J = 9.2 Hz, 2H).

[0293] [Compound 2-1D] Compound G (0.5 g) was dissolved in decane (10 g). Then, a toluene solution of platinum / 1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex (platinum content: 3% by mass, 4.1 mg), aniline (2.6 mg), and dimethoxysilyltrimethylsilicate (1.0 g) were added, and the mixture was stirred at 50°C for 2 hours. By removing the solvent under reduced pressure, 0.6 g of compound 2-1D was obtained.

[0294]

[0295] (NMR data of compound 2-1D) 1H NMR (400 MHz, CDCl3) δ 3.72-3.43 (m, 15H), 2.24 (tt, J = 14.1, 7.1 Hz, 2H), 1.60 - 1.14 (m, 34H), 0.72 (t, J = 8.9 Hz, 2H).

[0296] [Synthesis Example of Compound 1-1F] Compound 1-1F was synthesized using the method described in International Publication No. 2024 / 262627. The average value of n was 7.

[0297]

[0298] [Synthesis Example of Compound 2-1E] Compound 2-1E was synthesized using the method described in International Publication No. 2018 / 143433.

[0299]

[0300] [Examples 1 to 12] Each compound was mixed and stirred at 25°C under a nitrogen atmosphere so that the mass ratio of the amount of the first compound added to the amount of the second compound added was the ratio shown in the "Composition Ratio" column of Table 1, thereby obtaining the compositions (surface treatment agents) of Examples 1 to 10.

[0301] [Example 13] Compound 2-1E (0.5 mg) was added to compound 1-1F (10 g), then AE-3000 (50 g) was added to homogenize the mixture, and after stirring at 20°C for 3 hours, AE-3000 was removed by vacuum distillation to prepare the composition of Example 13.

[0302] [Example 14] Compound 2-1E (0.3 mg) was added to compound 1-1F (10 g), then AE-3000 (50 g) was added to homogenize the mixture, and the mixture was stirred at 20°C for 3 hours. After that, AE-3000 was removed by vacuum distillation to prepare the composition of Example 14.

[0303] [Examples 15-19] The first or second compound listed in Table 1 was used as a surface treatment agent.

[0304] [Manufacturing of goods] 30 g of silicon oxide was placed as a deposition source in the copper hearth inside the vacuum deposition apparatus (ULVAC KIKO "VTR-350M"). A glass substrate (chemically strengthened glass) was placed inside the vacuum deposition apparatus, and the inside of the vacuum deposition apparatus was 5 × 10 －３The system was evacuated until the pressure was below Pa. The hearth was heated to approximately 2,000°C, and silicon oxide was vacuum-deposited onto the surface of the substrate to produce a substrate with a silicon oxide layer approximately 20 nm thick. Next, evaluation samples (articles) were manufactured using a vacuum deposition apparatus. First, 0.17 g of each surface treatment agent was filled into a molybdenum boat inside the vacuum deposition apparatus (ULVAC, product name: VTR350M), and the inside of the vacuum deposition apparatus was filled to 1 × 10⁻⁶ －３ The pressure was reduced to below Pa. Next, the boat containing the surface treatment agent was heated at a heating rate of 10°C / min or less. When the deposition rate measured by a quartz crystal film thickness gauge exceeded 1 nm / second, the shutter was opened to begin film formation on the substrate surface. When the film thickness reached approximately 50 nm, the shutter was closed to complete film formation on the substrate surface with the silicon oxide layer. The substrate on which the compound or composition was deposited was heat-treated at 140°C for 30 minutes and washed with ethanol to obtain an evaluation sample (article) in which the substrate, silicon oxide layer, and surface layer were laminated in that order.

[0305] [Evaluation] The following evaluations were conducted using the obtained items. The results of the evaluation tests are shown in Table 1.

[0306] <Water Contact Angle> Approximately 2 μL of distilled water was dropped onto the surface layer of each example's article, and the initial water contact angle (°) was measured using a contact angle measuring device (product name "DM-500", manufactured by Kyowa Interface Science Co., Ltd.). The arithmetic mean of the contact angle measurements taken at five locations on the surface layer was taken, and the resulting average value was defined as the water contact angle. The 2θ method was used to calculate the water contact angle. A larger initial water contact angle indicates better water repellency of the surface layer. From the obtained initial water contact angles, the initial water contact angle of the surface layer of each example's article was evaluated based on the evaluation criteria below. The evaluation results for each example are shown in the table below. (Evaluation Criteria) A: Initial water contact angle greater than 105° B: Initial water contact angle 105° or less

[0307] <Water-repellent properties (water drop angle)> For each example, an 8 μL water droplet was placed on the surface layer of the object, and using a drop angle meter (Kyowa Interface Science Co., Ltd., custom-made), it was tilted at a speed of 4° per minute. The tilt angle when the water droplet moved 1 mm was measured and defined as the water drop angle. From the obtained water drop angles, the water-repellent properties of the surface layer of each example object were evaluated based on the evaluation criteria below. The evaluation results for each example are shown in the table below. (Evaluation Criteria) A: Water drop angle is 2 degrees or less B: Water drop angle is greater than 2 degrees and 3 degrees or less C: Water drop angle is greater than 3 degrees and 5 degrees or less D: Water drop angle is greater than 5 degrees

[0308] <Abrasion Resistance> Using a reciprocating traverse testing machine (manufactured by KNT Co., Ltd., custom-made), a flannel cloth conforming to JIS L0803 was used, and a test of 1.25 N / cm² was performed on the surface layer of each example article. ２ After applying a load and performing 1000 reciprocating friction cycles at a speed of 100 cycles per minute, the water contact angle after the friction test was measured using the method described above. Wear resistance was evaluated based on the degree of decrease in the water contact angle due to the friction test. The evaluation results for each example are shown in the table below. Degree of decrease in water contact angle = (Initial water contact angle) - (Water contact angle after friction test) (Evaluation criteria) A: Degree of decrease in water contact angle is 8 degrees or less B: Degree of decrease in water contact angle is greater than 8 degrees and 10 degrees or less C: Degree of decrease in water contact angle is greater than 10 degrees and 15 degrees or less D: Degree of decrease in water contact angle is greater than 15 degrees

[0309]

[0310] As shown in Table 1, it was confirmed that a surface layer with excellent water-repellent properties and abrasion resistance can be formed by using a composition containing the first compound and the second compound (Examples 1-14).

[0311] The articles of this disclosure have excellent sweat resistance. The articles of this disclosure include, as examples, optical articles, touch panels, anti-reflective films, anti-reflective glass, and SiO2, which are used as parts of the following products. ２It is useful as processed glass, tempered glass, sapphire glass, quartz substrates, mold metals, etc. Products: Car navigation systems, mobile phones, digital cameras, digital video cameras, personal digital assistants (PDAs), portable audio players, car audio systems, game consoles, eyeglass lenses, camera lenses, lens filters, sunglasses, medical equipment (endoscopes, etc.), photocopiers, personal computers (PCs), liquid crystal displays, organic EL displays, plasma displays, touch panel displays, protective films, anti-reflective films, anti-reflective glass, nanoimprint templates, molds, etc.

[0312] This application claims priority based on Japanese Patent Application No. 2025-055896, filed on 28 March 2025, and incorporates all of its disclosures herein.

[0313] 10 Substrate with undercoat 12 Substrate 14 Undercoat 20 Article 22 Surface layer

Claims

1. A composition comprising: a first compound selected from the group consisting of a compound represented by formula (1-1) and a compound represented by formula (1-2); and a second compound selected from the group consisting of a compound represented by formula (2-1) and a compound represented by formula (2-2). A ａ１ -L ａ１ -Q ａ１ -(T ａ１ ) ｍａ１ (1-1) (T ａ１ ) ｍａ１ -Q ａ１ -L ａ２ -Q ａ１ -(T ａ１ ) ｍａ１ (1-2) Provided that: A ａ１ is an alkyl group, or a group that contains at least one element selected from Si, Ge and Sn and has no reactive silyl group; L ａ１ is a chain group; L ａ２ is a chain group containing no fluorine atom; Q ａ１ is a single bond or a (ma1+1)-valent group; T ａ１ is a group containing a reactive silyl group; and ma1 is an integer of 1 or greater. (R ｆ１ ) ｎｂ１ -Q ｂ１ -(T ｂ１ ) ｍｂ１ (2-1) (T ｂ１ ) ｍｂ１ -Q ｂ２ -R ｆ２ -Q ｂ２ -(T ｂ１ ) ｍｂ１ (2-2) Provided that: R ｆ１ is a group that contains a fluoropolyether chain and has no reactive silyl group; R ｆ２ is a divalent fluoropolyether chain; Q ｂ１ is a (nb1+mb1)-valent linking group; Q ｂ２ is a (mb1+1)-valent linking group; T ｂ１ is a group containing a reactive silyl group; nb1 is an integer of 1 or greater; and mb1 is an integer of 1 or greater.

2. T in formulas (2-1) and (2-2) ｂ１ The composition according to claim 1, wherein the group is represented by the following formula (TB). ｂ１ -[Si(R ｂ１ ) ２ - Q ｂ３ ] ｒｂ１ -Si(R ｂ１ ) ３ (TB) However, R ｂ１ Each of these is independently a hydrolyzable group, a group having a hydrolyzable group, a hydroxyl group, or a hydrocarbon group, R ｂ１ At least one of them is a hydrolyzable group, a group having a hydrolyzable group, or a hydroxyl group, Q ｂ３ is an oxygen atom, or -CR ｂ２ ２ - and R ｂ２ is a hydrogen atom or hydrocarbon group, rb1 is an integer from 0 to 3, * ｂ１ Q ｂ１ Or Q ｂ２ This is the connection point.

3. The composition according to claim 1, wherein mb1 in formulas (2-1) and (2-2) is 1.

4. The first compound includes the compound represented by formula (1-1), and A in formula (1-1) ａ１ The composition according to claim 1, wherein the group is represented by formula (A1), formula (A2), or formula (A3). ａ２１ ３ M-(Q) ａ１１ ) ｚａ１ - (R ａＳｉ ) ｚａ２ - (A1) However, R ａ２１ Each of these independently comprises a hydrocarbon group, or R ｂ２１ ３ M-R ｂ２２ - and R ｂ２１ Each of these independently comprises a hydrocarbon group, or R ｃ２１ ３ M-R ｃ２２ - and R ｃ２１ Each of these independently comprises a hydrocarbon group, or R ｄ２１ ３ M-R ｄ２２ - and R ｄ２１ Each of these independently comprises a hydrocarbon group, or R ｅ２１ ３ M-R ｅ２２ - and R ｅ２１ Each of these is independently a hydrocarbon group, and R ｂ２２ , R ｃ２２ , R ｄ２２ , R ｅ２２ Each is independently an oxygen atom or an alkylene group having 1 to 6 carbon atoms, R ａ２４ Each of these independently comprises a hydrocarbon group or R ｂ２１ ３ M-R ｂ２２ - and ta11 is an integer from 1 to 5, R ａ２５ Each of these independently comprises a hydrocarbon group or R ｂ２１ ３ M-R ｂ２２ - and M is Si, and Q ａ１１ is -O-, -C(=O)-, or an alkylene group having 1 to 6 carbon atoms, za1 is 0 or 1, za2 is 0 or 1, R ａＳｉ is a group represented by the following formula (RSi). -(SiR ａ４１ ２ O) ｓａ４１ -SiR ａ４１ ２ - (RSi) wherein, R ａ４１ each independently represent a hydrocarbon group, and sa41 is a number of 0 or more.

5. The first compound comprises a compound represented by Formula (1-1), wherein L in Formula (1-1) ａ１ comprises a group represented by Formula (LD), according to claim 1, the composition: -(CR ａ１３ ２ ) ｓａ４ - (LD) with the proviso that R ａ１３ each independently represent a hydrogen atom, or a hydrocarbon group optionally having an ether bond between carbon atoms, and sa4 is an integer of 1 to 200.

6. T in formulas (1-1) and (1-2) ａ１ The composition according to claim 1, wherein the group is represented by the following formula (TA). ａ１ -[Si(R ａ１ ) ２ - Q ａ１３ ] ｒａ１ -Si(R ａ１ ) ３ (TA) However, R ａ１ Each of these is independently a hydrolyzable group, a group having a hydrolyzable group, a hydroxyl group, or a hydrocarbon group, R ａ１ At least one of them is a hydrolyzable group, a group having a hydrolyzable group, or a hydroxyl group, Q ａ１３ is an oxygen atom, or -CR ａ２ ２ - and R ａ２ is a hydrogen atom or hydrocarbon group, ra1 is an integer from 0 to 3, * ａ１ Q ａ１ This is the connection point.

7. The composition according to claim 1, wherein ma1 in formulas (1-1) and (1-2) is 1.

8. A surface treatment agent comprising the composition according to any one of claims 1 to 7.

9. The surface treatment agent according to claim 8, further comprising a liquid medium.

10. The surface treatment agent according to claim 8, which is an antifouling coating agent or a waterproof coating agent.

11. The surface treatment agent according to claim 9, which is an antifouling coating agent or a waterproof coating agent.

12. An article having a surface layer formed using the surface treatment agent described in claim 8 on the surface of a substrate.

13. The article according to claim 12, which is an optical component.

14. The article according to claim 12, wherein the surface layer is provided on the surface of a component that constitutes the surface of a touch panel that is touched by a finger.

15. A method for manufacturing an article, comprising forming a surface layer by a dry coating method using the surface treatment agent described in claim 8.

16. A method for manufacturing an article, comprising forming a surface layer by a dry coating method using the surface treatment agent described in claim 9.

17. A method for manufacturing an article, comprising forming a surface layer by a wet coating method using the surface treatment agent described in claim 9.

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