14C Quantum Dot Carbon Electrode for Betavoltaic Batteries

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Solution Overview

Problem

Conventional betavoltaic batteries face inefficiencies in energy conversion due to the direct contact between beta-ray sources and energy absorbers, leading to damage and reduced current output over time, with limited energy utilization and low radiation energy density.

Innovation Solution

A carbon electrode with a beta-ray source emission layer of 14C organic quantum dots is integrated into a betavoltaic battery, using a TiO2 electrode with a ruthenium-based dye as the energy absorber, enhancing radiation energy density and electron generation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of moving object

If a long half-life isotope is used to increase output life, then the operational duration is improved, but the decay rate decreases which reduces output power

Engineering Contradiction:
Improveoutput lifeVSAvoidoutput power
Core Design Contradiction:
Duration of action of moving objectVSPower

Solution Approach 1:

The patent applies parameter changes by utilizing 14C isotopes with specific half-life and energy characteristics. The quantum dot structure enables efficient energy conversion by confining beta particles within a small volume, maximizing the utilization of decay energy despite the moderate half-life of 14C (about 5730 years). The quantum confinement effect enhances the interaction between beta particles and the semiconductor, improving power output while maintaining long-term stability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by integrating radioisotopes into quantum dot structures. The quantum dots serve as a composite system combining the radioisotope source with a semiconductor matrix, enabling simultaneous achievement of long operational life and sustained power output through enhanced energy conversion efficiency at the interface between the isotope and semiconductor materials.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If the thickness of radiation source material is increased to contain more radioisotope, then the energy density is improved, but the number of recombination electrons and holes increases reducing efficiency

Engineering Contradiction:
Improveamount of radiation sourceVSAvoidrecombination loss
Core Design Contradiction:
Quantity of substanceVSLoss of energy

Solution Approach 1:

The patent utilizes porous or nanoscale quantum dot structures that provide high surface area to volume ratio. This allows a large quantity of radioisotope to be incorporated while maintaining short transport paths for charge carriers, minimizing recombination losses. The quantum dot morphology enables dense packing of 14C atoms while preserving efficient carrier collection at the semiconductor interface.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent transitions from bulk material to quantum dot (nanoscale) dimensions, fundamentally changing the geometry of the radiation source. This dimensional reduction increases the surface area available for charge carrier separation and reduces the distance carriers must travel, thereby minimizing recombination while accommodating a high concentration of radioisotopes within the quantum confined structure.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Use of energy by moving object

If beta-ray source and energy absorber are in direct contact to enable energy conversion, then the energy conversion efficiency is improved, but the absorber is damaged over time causing current loss

Engineering Contradiction:
Improveenergy conversion efficiencyVSAvoidcontinuous operation capability
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent introduces quantum dots as an intermediary layer between the beta-ray source and the energy absorber. The quantum dots absorb beta particle energy and facilitate controlled energy transfer to the semiconductor, reducing direct damage to the absorber materials. This intermediate structure protects the semiconductor from high-energy particle bombardment while maintaining efficient energy conversion through the quantum confined states.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces direct mechanical contact and physical bombardment between beta particles and the absorber with a quantum mechanical energy transfer mechanism. The quantum dots mediate the energy transfer through electronic excitations and carrier generation, substituting the harsh physical interaction with a gentler quantum process that preserves the integrity of the absorber materials over time.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Device complexity

If a planar structure PN junction is used with radiation source on top, then the structure is simple, but beta particles emitted in four directions are dissipated without conversion

Engineering Contradiction:
Improvestructure simplicityVSAvoidbeta particle dissipation
Core Design Contradiction:
Device complexityVSLoss of energy

Solution Approach 1:

The patent applies local quality by concentrating the radioisotope activity specifically within the quantum dot regions that are in close proximity to the semiconductor junction. Rather than uniformly distributing the source, the 14C-labeled quantum dots are localized at the active interface, ensuring that beta particles are generated where they can be most effectively converted, minimizing directional loss while maintaining structural simplicity.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent implements a nested structure where radioisotopes are embedded within quantum dots, which are in turn integrated with the semiconductor junction. This nested arrangement ensures that the radiation source is positioned within the active region, maximizing the fraction of beta particles that contribute to charge carrier generation while maintaining a relatively simple overall device architecture.

Inventive Principle:
Principle #7Nested doll (Nesting)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The carbon electrode with 14C quantum dots increases beta-ray emission density and energy production, providing a stable and efficient energy conversion with improved operational stability and power output.

Implementation Method 1

a beta-ray source emission layer including organic carbon quantum dots including 14C formed on the support layer

Methodology Applied
Scientific EffectBeta decay: Radioactive Decay

Implementation Method 2

A betavoltaic battery is an isotope battery that absorbs, through the surface of a PN junction semiconductor, beta rays from radioisotopes that emit beta particles (electrons) and converts the beta rays into electrical energy

Methodology Applied
Scientific EffectBetavoltaics: Betavoltaics

Implementation Method 3

beta rays emitted from a beta-ray source generate electron-hole pairs in a space charge region in a PN junction semiconductor

Methodology Applied
Scientific EffectBeta ray absorption and electron-hole pair generation: Betavoltaics

Implementation Method 4

the generated carriers have the voltage and current characteristics of the betavoltaic battery

Methodology Applied
Scientific EffectPhotoelectric effect: Photoelectric Effect

Data Source

PatentUS20230090218A1Carbon electrode for dye-sensitized betavoltaic batteries, betavoltaic battery including the same, and method of manufacturing the same
Publication Date: 2023.03.23 DAEGU GYEONGBUK INSTITUTE OF SCIENCE AND TECHNOLOGY
  • US20230090218A1 patent drawing
  • US20230090218A1 patent drawing
  • US20230090218A1 patent drawing

AI summary

The present invention relates to a betavoltaic battery and a method of manufacturing the same. More specifically, the present invention relates to a betavoltaic battery characterized in that 14C, a radioisotope, is formed in the form of quantum dots and 14C is used as the cathode and the beta-ray source of the betavoltaic battery and a method of manufacturing the betavoltaic battery.