17-4PH Metal Powder for Additive Manufacturing Hardening

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Solution Overview

Problem

Conventional precipitation hardening processes do not effectively work for metal parts produced by Direct Metal Laser Sintering using stainless steel 17-4PH powder, limiting the properties and applications of additively manufactured stainless steel objects.

Innovation Solution

A stainless steel powder with specific composition and particle size distribution, produced by atomization, is used in laser sintering, allowing for post-hardening and achieving mechanical properties similar to conventionally manufactured 17-4 PH stainless steel through rapid cooling and resolidification, thereby enabling precipitation hardening and omitting additional post-treatment steps like solution annealing and quenching.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional precipitation hardening process is applied to laser sintered stainless steel 17-4PH parts, then the material is expected to achieve increased hardness, but the process does not effectively work and the hardness is not significantly increased

Engineering Contradiction:
ImprovehardnessVSAvoideffectiveness of precipitation hardening
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The invention changes the chemical composition parameters of the stainless steel powder, specifically adjusting the content of alloying elements such as copper, nickel, and other precipitation-hardening elements within defined ranges. This compositional modification enables the material to respond effectively to conventional precipitation hardening processes after laser sintering, resolving the issue where the standard hardening process failed to work on conventionally composed powders

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite powder composition by blending stainless steel 17-4PH with specific amounts of other metal powders that contain elements beneficial for precipitation hardening. This composite approach ensures that the laser-sintered parts contain sufficient precipitation-hardening elements to achieve effective hardening treatment, thereby improving both the reliability and effectiveness of the post-processing step

Inventive Principle:
Principle #40Composite materials

2Productivity

If laser sintering is used to produce stainless steel parts, then rapid manufacturing capability is achieved, but the mechanical properties are inferior to conventionally manufactured parts

Engineering Contradiction:
Improverapid manufacturing capabilityVSAvoidmechanical properties
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

The invention performs preliminary action by pre-adjusting the chemical composition of the powder material before laser sintering. The powder is formulated with optimized alloy content and particle size distribution that are specifically designed to achieve desired mechanical properties after sintering and precipitation hardening, eliminating the need for extensive post-processing and achieving both rapid manufacturing and high mechanical properties

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention applies parameter changes to the powder characteristics including particle size distribution (D10, D50, D90 values), chemical composition (alloy element contents), and morphology. These parameter optimizations ensure that the laser-sintered parts achieve mechanical properties comparable to or exceeding conventionally manufactured parts while maintaining the rapid manufacturing advantage

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If conventional stainless steel 17-4PH powder is used for laser sintering, then the process is simple and direct, but additional post-treatment steps like solution annealing and quenching are required

Engineering Contradiction:
Improveprocess simplicityVSAvoidnumber of post-treatment steps
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The invention extracts and removes the need for solution annealing and quenching steps from the conventional processing sequence. By incorporating sufficient precipitation-hardening elements directly into the powder composition, the material can undergo direct precipitation hardening after laser sintering, eliminating the complex multi-step heat treatment process and simplifying the overall manufacturing workflow

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method produces three-dimensional objects with significantly increased hardness and mechanical properties comparable to conventionally manufactured stainless steel, enhancing strength, stiffness, and hardness, and expanding applications for additive manufacturing.

Implementation Method 1

Direct Metal Laser Sintering (DMLS) is a laser-based rapid prototyping and tooling process by means of which net shape parts are fabricated in a single process

Methodology Applied
Scientific EffectLaser heating: Laser

Implementation Method 2

layer-wise solidification of metal powder layers in portions of the layer corresponding to the cross-section of the three-dimensional part

Methodology Applied
Scientific EffectSintering: Sintering

Implementation Method 3

rapid cooling and resolidification, thereby enabling precipitation hardening

Methodology Applied
Scientific EffectRapid cooling and resolidification: Freezing

Implementation Method 4

the object produced can be post-hardened, in particular by means of precipitation hardening, to significantly increase the hardness

Methodology Applied
Scientific EffectPrecipitation hardening: Precipitation Hardening

Data Source

PatentEP1992709B1Metal powder for use in additive manufacturing method for the production of three-dimensional objects and method using such metal powder
Publication Date: 2021.09.15 EOS GMBH ELECTRO OPTICAL SYST
  • EP1992709B1 patent drawingFigure 1~2
  • EP1992709B1 patent drawingFigure 3a~3c
  • EP1992709B1 patent drawingFigure 4

AI summary

Metal powder for use in an additive production method of three-dimensional objects wherein the powder is solidified by means of a laser or electron beam or another heat source, characterized in that the powder comprises iron and the following components by weight percent (wt.-%) and wherein the powder particles have a median particle size d50 between 20µm and 100µm.