2D Material Heterostack Transfer Without Residue Contamination

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Solution Overview

Problem

Current semiconductor technologies face challenges in scaling down silicon-based transistors due to residue contamination and surface damage during cleaning processes, which affect the performance and yield of two-dimensional (2D) material layers used in semiconductor devices.

Innovation Solution

The use of van der Waals forces to form residue-free heterostacks of 2D material layers, which are transferred onto substrates without adhesives, using methods like electrochemical delamination and vacuum processing to maintain cleanliness and structural integrity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If traditional cleaning processes are used on silicon-based transistors, then device scaling is achieved, but residue contamination and surface damage occur

Engineering Contradiction:
Improvedevice scalingVSAvoidsurface cleanliness
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent employs an inert atmosphere environment during the transfer process to prevent oxidation and contamination of the 2D material layers. By conducting the transfer in a controlled inert environment, the surface cleanliness is maintained while enabling device scaling without traditional cleaning processes that cause damage.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Solution Approach 2:

The patent uses an intermediary transfer substrate to move 2D material layers from their growth substrate to the final device substrate. This intermediary approach allows the 2D materials to be transferred without direct contact with damaging cleaning chemicals, maintaining surface integrity while enabling scaling.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of manufacture

If adhesive-based transfer methods are used, then 2D material layers can be transferred, but residue contamination occurs on surfaces

Engineering Contradiction:
Improvetransfer capabilityVSAvoidsurface cleanliness
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent introduces a transfer substrate as an intermediary that temporarily holds the 2D material layers during transfer. This mediator enables the transfer process without requiring adhesives that would leave residue, achieving both ease of manufacture and surface cleanliness.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent extracts and eliminates the adhesive component from the transfer process entirely. By using mechanical transfer methods on a transfer substrate, the harmful adhesive substance is removed from the system, preventing residue contamination while maintaining transfer capability.

Inventive Principle:
Principle #2Taking out (Extraction)

3Productivity

If conventional transfer processes are used, then device fabrication continues, but 2D material layers suffer surface damage and contamination

Engineering Contradiction:
Improvefabrication continuityVSAvoidlayer integrity
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent maintains an inert atmosphere throughout the transfer and fabrication process to protect 2D material layers from oxidation and contamination. This enables continuous fabrication while preserving layer integrity, as the inert environment prevents chemical damage during handling and processing.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Solution Approach 2:

The transfer substrate serves as a protective intermediary that supports 2D material layers during transfer and subsequent fabrication steps. This mediator prevents direct exposure to damaging environments and processes, maintaining layer integrity while allowing fabrication to proceed.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach ensures substantially residue-free surfaces and intact layers, enhancing the performance and scalability of semiconductor devices by preventing contamination and maintaining the integrity of 2D material layers during transfer processes.

Implementation Method 1

The use of van der Waals forces to form residue-free heterostacks of 2D material layers, which are transferred onto substrates without adhesives

Methodology Applied
Scientific EffectVan der Waals force: Van der Waals Force

Implementation Method 2

using methods like electrochemical delamination and vacuum processing to maintain cleanliness and structural integrity

Methodology Applied
Scientific EffectElectrochemical delamination: Electrolysis

Implementation Method 3

using methods like electrochemical delamination and vacuum processing to maintain cleanliness and structural integrity

Methodology Applied
Scientific EffectVacuum: Vacuum

Data Source

PatentUS20250329534A1Semiconductor device with two-dimensional materials
Publication Date: 2025.10.23 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US20250329534A1 patent drawing
  • US20250329534A1 patent drawing
  • US20250329534A1 patent drawing

AI summary

The present disclosure describes a method that includes forming a first two-dimensional (2D) layer on a first substrate and attaching a second 2D layer to a carrier film. The method also includes bonding the second 2D layer to the first 2D layer to form a heterostack including the first and second 2D layers. The method further includes separating the first 2D layer of the heterostack from the first substrate and attaching the heterostack to a second substrate. The method further includes removing the carrier film from the second 2D layer.