2D Material Self-Assembly Patterning and Actuation

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Solution Overview

Problem

Current methods for structuring and patterning two-dimensional (2D) materials like graphene are inefficient, requiring expensive techniques such as electron beam or nanoimprint lithography, and lack methods for mechanical actuation in devices like MEMS and NEMS.

Innovation Solution

A directed self-assembly method using mechanical indentation and oscillations to form folded structures in 2D materials, allowing for scalable and controllable patterning and actuation of graphene and other 2D materials, which can operate at room temperature and in air, enabling the formation of structures from nanometer to macroscopic scales.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If expensive techniques such as electron beam or ion beam lithography are used for patterning 2D materials, then manufacturing precision is improved, but device complexity and cost increase

Engineering Contradiction:
Improvepatterning precisionVSAvoidpatterning process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The 2D material sheet performs self-assembly to form folded structures and ribbons autonomously after being configured with initiation sites, eliminating the need for complex electron beam or ion beam lithography processes. The material itself carries out the patterning function through spontaneous self-assembly driven by configurational energy minimization.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The method pre-configures the 2D material sheet with specific initiation sites (such as perforations, punctures, or pre-formed folds) that trigger subsequent self-assembly. This preliminary configuration step simplifies the overall process by preparing the material in advance rather than requiring complex real-time patterning during fabrication.

Inventive Principle:
Principle #10Preliminary action

2Device complexity

If standard optical processing limits are used for lithography, then device complexity is reduced, but manufacturing precision deteriorates

Engineering Contradiction:
Improvelithography process complexityVSAvoidlithography resolution
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

The invention replaces optical lithography systems with a mechanical self-assembly approach. Instead of using complex optical equipment to pattern materials, simple mechanical configuration steps (such as stamping or forming initiation sites) trigger autonomous self-assembly that achieves high resolution without requiring sophisticated optical processing equipment.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Manufacturing precision

If expensive patterning techniques are used to produce narrow graphene ribbons, then manufacturing precision is improved, but productivity decreases

Engineering Contradiction:
Improveribbon width controlVSAvoidproduction efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The 2D material autonomously forms narrow ribbons with precise width control through self-assembly after configuration, eliminating the need for slow, expensive electron beam lithography. This self-driven process dramatically increases production efficiency while maintaining the ability to produce sub-micrometer scale ribbons suitable for semiconducting applications.

Inventive Principle:
Principle #25Self-service

4Device complexity

If no mechanical actuation method is provided for 2D materials, then device complexity remains simple, but functionality in MEMS and NEMS is limited

Engineering Contradiction:
Improvemechanical actuation capabilityVSAvoiddevice application range
Core Design Contradiction:
Device complexityVSAdaptability or versatility

Solution Approach 1:

The invention introduces dynamic mechanical actuation capabilities to 2D materials by enabling them to undergo spontaneous self-assembly and form movable folded structures. This transforms static 2D material sheets into dynamically active components that can perform mechanical functions in MEMS and NEMS devices, significantly expanding their applicability.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables high-yield, scalable production of patterned 2D material structures with precise control over size and direction, suitable for electronic, optical, and mechanical devices, and allows for the integration of self-assembly as a functional component in devices, overcoming the limitations of existing techniques.

Implementation Method 1

spontaneous self-assembly of the 2D material sheet to form folded structures and ribbons

Methodology Applied
Scientific EffectSelf-assembly: Self-Assembly

Implementation Method 2

adhesion of the 2D material to itself and to the substrate

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 3

A mechanical force (P) is applied to the indentation die at the point where the indentation die makes contact with the 2D material

Methodology Applied
Scientific EffectMechanical force: Mechanical Force

Implementation Method 4

simultaneously imposing a lateral rapid oscillating load parallel to the surface (T) of the 2D material

Methodology Applied
Scientific EffectFriction: Friction

Implementation Method 5

lateral rapid oscillating load

Methodology Applied
Scientific EffectVibration: Vibration

Data Source

PatentUS11318637B2Method for structuring, patterning, and actuating devices using two-dimensional materials
Publication Date: 2022.05.03 THE PROVOST FELLOWS FOUNDATION SCHOLARS AND THE OTHER MEMBERS OF BOARD OF THE COLLEGE OF THE HOLY AND UNDIVIDED TRINITY OF QUEEN ELIZABETH NEAR DUBLIN
  • US11318637B2 patent drawing
  • US11318637B2 patent drawing
  • US11318637B2 patent drawing

AI summary

A method for patterning layers of 2D material by inducing self-assembly on a support substrate, the method comprising the steps of depositing a layer of 2D material on the support substrate; applying a force at a region consisting of a point, a line, or an a real region of the 2D material such that the 2D material forms a folded, self-contacting structure at that region.