2D Material Semiconductor Device Thickness Control

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Solution Overview

Problem

There is a need for improved methods to form two-dimensional (2D) material layers in semiconductor devices to enhance performance, particularly in field-effect transistors (FETs), as existing methods do not effectively control the mobility of carriers and achieve uniform thickness in multi-layer 2D material structures.

Innovation Solution

A method involving epitaxial chemical vapor deposition (CVD) is used to form a multi-layer 2D material structure over a carrier substrate, with iterative thickness monitoring using scanning probe microscopy (SPM) to achieve a desired mean thickness and uniformity, allowing for the controlled formation of additional 2D material sub-layers to increase carrier mobility.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional deposition methods are used to form 2D material layers, then the manufacturing process is simple, but the uniformity of thickness and carrier mobility cannot be effectively controlled

Engineering Contradiction:
Improveuniformity of thicknessVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent implements iterative thickness monitoring using scanning probe microscopy (SPM) to measure the actual thickness of deposited 2D material layers. Based on the measured thickness, the deposition process is repeated with adjusted parameters until the desired target thickness is achieved, creating a closed-loop feedback system that ensures precise thickness control and uniformity

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent performs preliminary characterization of the substrate surface and establishes deposition parameters before the actual deposition process. The target thickness is determined in advance based on the desired carrier mobility, allowing the deposition process to be optimized beforehand rather than requiring extensive post-processing adjustments

Inventive Principle:
Principle #10Preliminary action

2Reliability

If the number of 2D material sub-layers is increased to improve carrier mobility, then carrier mobility increases, but the thickness uniformity becomes more difficult to control

Engineering Contradiction:
Improvecarrier mobilityVSAvoidthickness uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent deposits a slight excess of 2D material beyond the theoretical minimum required for the target thickness, then uses SPM measurement and iterative removal or selective deposition to achieve the precise target thickness. This approach ensures that carrier mobility requirements are met while maintaining thickness uniformity through measurement and adjustment

Inventive Principle:
Principle #16Partial or excessive action

Solution Approach 2:

The patent adjusts deposition parameters such as deposition rate, temperature, and pressure based on the number of sub-layers being formed and the target thickness. By dynamically changing these parameters during the deposition process, the system maintains thickness uniformity even when forming multiple sub-layers to achieve higher carrier mobility

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the formation of semiconductor devices with increased carrier mobility and improved uniformity, demonstrated by enhanced current-voltage characteristics and increased ON/OFF ratios, while being compatible with sub-10 nm node transistor fabrication.

Implementation Method 1

epitaxial chemical vapor deposition (CVD) is used to form a multi-layer 2D material structure

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Implementation Method 2

iterative thickness monitoring using scanning probe microscopy (SPM)

Methodology Applied
Scientific EffectScanning probe microscopy: Scanning Probe Microscopy

Data Source

PatentUS10403744B2Semiconductor devices comprising 2D-materials and methods of manufacture thereof
Publication Date: 2019.09.03 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US10403744B2 patent drawing
  • US10403744B2 patent drawing
  • US10403744B2 patent drawing

AI summary

A method for manufacturing a semiconductor device comprising two-dimensional (2D) materials may include: epitaxially forming a first two-dimensional (2D) material layer over a substrate; calculating a mean thickness of the first 2D material layer; comparing the mean thickness of the first 2D material layer with a reference parameter; determining that the mean thickness of the first 2D material layer is not substantially equal to the reference parameter; and after the determining, epitaxially forming a second 2D material layer over the first 2D material layer.