3D Electrode Super Lattice for Battery Capacity
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Solution Overview
Problem
Existing electrochemical devices, such as lithium secondary batteries, face challenges in achieving high capacity, high output, and high energy density due to limitations in electrode design, including insufficient electron and ion conductivity of active materials, excessive use of conductive materials, and the weight and volume occupied by metal current collectors.
Innovation Solution
An electrode with a three-dimensional structure is developed, comprising a porous nonwoven web of polymer fibers with an active material composite and a second conductive material, forming a super lattice structure to minimize additives and enhance electroconductivity, using a light material current collector and optimizing porosity for improved ion transport and mechanical strength.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Strength
If a metal current collector is used, then the electrode has good mechanical strength and electrical conductivity, but the electrode weight and volume increase, reducing capacity per unit weight or volume
Solution Approach 1:
The patent removes the metal current collector from the electrode structure entirely, extracting this heavy component while maintaining electrode functionality through the self-supported three-dimensional network of active material particles connected by conductive materials
Solution Approach 2:
The electrode is segmented into discrete active material particles (1-50 μm diameter) that form a three-dimensional network, replacing the continuous metal current collector structure with a distributed particle-based architecture that eliminates the need for heavy metal support
2Quantity of substance
If the active material has high theoretical capacity, then the energy density can be improved, but the electron and ion conductivity remains insufficient
Solution Approach 1:
The patent creates a composite structure where active material particles are interconnected by conductive materials (carbon nanotubes, graphene, or conductive polymers), forming a composite network that combines the high capacity of active materials with the excellent conductivity of carbon-based materials
Solution Approach 2:
The conductive materials are selectively positioned at the interfaces between active material particles and within the three-dimensional network, providing localized conductivity enhancement exactly where electron and ion transport is needed, without diluting the overall active material content
3Reliability
If an excessive amount of conductive material is used to overcome low conductivity, then the conductivity is improved, but the energy density deteriorates
Solution Approach 1:
The patent uses conductive materials in optimized partial amounts (1-50 parts by weight relative to 100 parts active material), providing sufficient conductivity through the three-dimensional network structure without excessive addition that would reduce energy density, achieving the right balance through controlled dosing
4Quantity of substance
If additives such as conductive material and binder are minimized, then the energy density is improved, but the electroconductive network uniformity may deteriorate
Solution Approach 1:
The patent transitions from a two-dimensional planar electrode structure to a three-dimensional network architecture, where active material particles are arranged in three-dimensional space and interconnected by conductive materials, creating uniform electroconductive pathways in multiple directions and eliminating the need for excessive additives
Data Source
Figure 1a~1c
Figure 2~3
Figure 4~5
AI summary
Disclosed are an electrode having a three-dimensional structure, the electrode including: a porous nonwoven web including a plurality of polymer fibers that form an interconnected porous network; an active material composite positioned among the polymer fibers and including active material particles and a first conductive material; and a second conductive material positioned on an outer surface of the active material composite, wherein the interconnected porous network is filled homogeneously with the active material composite and the second conductive material to form a super lattice structure, and an electrochemical device including the electrode having a three-dimensional structure.