3D Electrophoretic Deposition for Graded Ceramics

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Solution Overview

Problem

Traditional electrophoretic deposition (EPD) processes are limited in controlling the shapes, compositions, densities, and microstructures of materials, often resulting in planar, homogenous structures and struggling to form structures from multiple materials, with hazardous waste generation and difficulty in achieving three-dimensional functionality graded materials.

Innovation Solution

The method involves using three-dimensional electrophoretic deposition to form functionality graded materials by orienting non-cubic particles in a common direction, employing aqueous solutions, and dynamic electrode patterning to create complex structures with gradients in composition, microstructure, and density, enabling the formation of ceramics, metals, or cermets with tailored properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If traditional electrophoretic deposition processes are used, then planar homogenous structures are formed, but control over shapes, compositions, densities, and microstructures is difficult or impossible

Engineering Contradiction:
Improvecontrol over shapes, compositions, densities, and microstructuresVSAvoidcomplexity of EPD process
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent transitions from traditional two-dimensional planar deposition to three-dimensional structured material formation by incorporating vertical layering and gradient composition control, enabling precise manipulation of material properties in all spatial dimensions

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Solution Approach 2:

The system employs dynamic control of deposition parameters including variable voltage application, controlled particle suspension composition, and adjustable deposition rates to achieve real-time optimization of microstructure and composition during the deposition process

Inventive Principle:
Principle #15Dynamics

2Adaptability or versatility

If traditional EPD processes are used, then simple planar structures are formed, but formation of structures from more than one material is extremely difficult

Engineering Contradiction:
Improveability to form structures from multiple materialsVSAvoidease of forming multi-material structures
Core Design Contradiction:
Adaptability or versatilityVSEase of manufacture

Solution Approach 1:

The patent divides the deposition process into sequential stages where different particle suspensions are deposited in separate steps to form distinct layers, each with controlled composition and properties, enabling multi-material structure formation

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The system creates composite materials by depositing multiple types of particles with different properties (e.g., ceramic particles, metal particles, polymers) in controlled sequences to form functionally graded composite structures with tailored properties

Inventive Principle:
Principle #40Composite materials

3Productivity

If organic solvent solutions are used in EPD, then deposition process works, but hazardous waste is generated as by-product

Engineering Contradiction:
Improvedeposition process efficiencyVSAvoidhazardous waste generation
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical parameter of the deposition medium from organic solvents to aqueous solutions, maintaining deposition efficiency while eliminating hazardous waste generation through substitution with environmentally benign water-based suspensions

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for the production of intricate, three-dimensionally structured materials with controlled gradients, overcoming the limitations of traditional EPD by enabling the creation of advanced materials like transparent ceramics and composite armor with enhanced properties, such as improved optical and mechanical performance.

Implementation Method 1

The electrophoretic deposition (EPD) process utilizes electric fields to deposit charged nanoparticles from a solution onto a substrate

Methodology Applied
Scientific EffectElectrophoretic deposition: Electrophoretic Deposition

Implementation Method 2

The particles of the deposited non-cubic material are oriented in a common direction

Methodology Applied
Scientific EffectParticle orientation in electric field: Electrophoresis

Data Source

PatentUS11718924B2Methods of three-dimensional electrophoretic deposition for ceramic and cermet applications and systems thereof
Publication Date: 2023.08.08 LAWRENCE LIVERMORE NAT SECURITY LLC
  • US11718924B2 patent drawing
  • US11718924B2 patent drawing
  • US11718924B2 patent drawing

AI summary

A method for forming a ceramic according to one embodiment includes electrophoretically depositing a plurality of layers of particles of a non-cubic material. The particles of the deposited non-cubic material are oriented in a common direction.