3D Interconnected Porous Graphene Thermal Interface Materials

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Solution Overview

Problem

Conventional thermal interface materials (TIMs) based on graphene composites suffer from poor thermal conductivity and anisotropic thermal transport due to defects in the graphene sheets and parallel stacking, limiting their effectiveness in heat dissipation across interfaces.

Innovation Solution

A three-dimensional interconnected porous graphene (3D-IPG) foam structure is used as a thermal interface material, constructed through high-temperature chemical vapor deposition, which provides flexible interconnection architectures and high interfacial thermal conductance by filling gaps between heat sources and sinks, enhancing both vertical and horizontal heat transport.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If graphene sheets are stacked in parallel to form thermal interface materials, then the material can be manufactured with simple structure, but the thermal conductivity becomes anisotropic and thermal transport in vertical direction is limited

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidthermal conductivity
Core Design Contradiction:
Ease of manufactureVSTemperature

Solution Approach 1:

The patent transforms the traditional two-dimensional parallel stacking of graphene sheets into a three-dimensional interconnected network structure. This dimensional change enables thermal transport in multiple directions including vertical transport, resolving the anisotropy problem while maintaining manufacturing feasibility through self-assembly processes

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Ease of manufacture

If chemical exfoliation is used to produce graphene paper, then graphene sheets can be obtained, but defects are generated in graphene sheets resulting in poor thermal conductivity

Engineering Contradiction:
Improvegraphene productionVSAvoidthermal conductivity
Core Design Contradiction:
Ease of manufactureVSTemperature

Solution Approach 1:

The patent extracts and removes the problematic chemical exfoliation step that generates defects. Instead, it uses physical methods such as mechanical exfoliation or deposition techniques to obtain high-quality graphene sheets that maintain their intrinsic high thermal conductivity while still enabling practical material fabrication

Inventive Principle:
Principle #2Taking out (Extraction)

3Ease of manufacture

If conventional composite-based thermal interface materials are used, then the material structure is simple and easy to manufacture, but the thermal conductivity is much lower than bulk graphene and does not display significant advantages

Engineering Contradiction:
Improvemanufacturing easeVSAvoidthermal conductivity
Core Design Contradiction:
Ease of manufactureVSTemperature

Solution Approach 1:

The patent creates a hierarchical composite structure where high-quality graphene sheets are interconnected in a 3D network within a matrix material. This composite approach leverages the superior thermal conductivity of graphene while maintaining the manufacturing advantages of composite materials, achieving both high performance and manufacturability

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The 3D-IPG foam significantly reduces thermal resistance and increases thermal conductivity, offering superior heat dissipation performance compared to conventional TIMs, with thermal interfacial resistance reduced by up to 75% and enhanced mechanical strength through the addition of nanomaterials and encapsulants.

Implementation Method 1

The TIM is made from a three-dimensional interconnected porous graphene (3D-IPG) foam structure constructed of three-dimensional interconnected graphene sheets... maintain a high interfacial thermal conductance by the 3D-IPG filling a gap between a heat source and a heat sink across the interface

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Data Source

PatentUS9605193B2Three dimensional interconnected porous graphene-based thermal interface materials
Publication Date: 2017.03.28 THE HONG KONG UNIV OF SCI & TECH
  • US9605193B2 patent drawing
  • US9605193B2 patent drawing
  • US9605193B2 patent drawing

AI summary

A thermal interface material provides thermal conduction or thermal dissipation across an interface, using a three-dimensional interconnected porous graphene (3D-IPG) foam structure. The 3D-IPG foam structure is constructed of three-dimensional interconnected graphene sheets formed as a plurality of monolayers, and having an flexible interconnection architecture. The flexible interconnection architectures allow the 3D-IPG to maintain a high interfacial thermal conductance by the 3D-IPG filling a gap between a heat source and a heat sink across the interface, and by capping small features up to nanoscale roughened surfaces.