3D Nano-Pattern Fabrication on Thermally Labile Substrates

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Solution Overview

Problem

Current nano-patterning methods, such as photolithography, require high temperatures and multiple steps, making them incompatible with heat-sensitive substrates and inefficient for fabricating complex three-dimensional nanostructures.

Innovation Solution

A method involving a polymer template with reacting sites for material precursors, where sequential exposure and oxidation steps are repeated to form a 3D nano-structure bound to a substrate, compatible with thermally labile substrates, using techniques like solvent vapor annealing and etching to maintain structural integrity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If photolithography is used for nano-patterning, then manufacturing precision is improved, but temperature increases causing damage to thermally sensitive substrates

Engineering Contradiction:
Improvenano-patterning precisionVSAvoidprocess temperature
Core Design Contradiction:
Manufacturing precisionVSTemperature

Solution Approach 1:

The patent replaces thermal-based photolithography processes with a chemical vapor deposition approach using metal organic precursors. The template is formed through chemical reactions at low temperatures, eliminating the need for high-temperature heating that damages thermally sensitive substrates while maintaining nano-patterning precision through controlled chemical reactions.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the fundamental process parameters from thermal energy (heat) to chemical energy (metal organic reactions). By using metal organic precursors that react at low temperatures, the process achieves nano-patterning without requiring the elevated temperatures typical of photolithography, thus protecting thermally sensitive substrates.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If multiple photolithography steps are used to define complex 3D structures, then manufacturing precision is improved, but device complexity increases

Engineering Contradiction:
Improve3D structure definition precisionVSAvoidnumber of process steps
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent merges multiple photolithography steps into a single template formation process. By using metal organic precursors that can be deposited and reacted in one step, the complex 3D structures are defined without requiring multiple sequential photolithography cycles, thus reducing process complexity while maintaining precision.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent performs preliminary template formation using metal organic reactions before the actual nano-structure fabrication. This preliminary action creates the complete 3D template pattern in advance, allowing subsequent processing steps to simply follow the pre-defined template rather than requiring multiple iterative patterning steps.

Inventive Principle:
Principle #10Preliminary action

3Manufacturing precision

If high temperature processes are used in photolithography, then manufacturing precision is improved, but adaptability to thermally labile substrates deteriorates

Engineering Contradiction:
Improvenano-patterning accuracyVSAvoidcompatibility with thermally labile substrates
Core Design Contradiction:
Manufacturing precisionVSAdaptability or versatility

Solution Approach 1:

The patent substitutes thermal processes with chemical vapor deposition using metal organic precursors. This replacement enables nano-patterning on thermally labile substrates by eliminating high-temperature heating, while maintaining manufacturing precision through controlled chemical reactions that occur at low temperatures.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent fundamentally changes the process temperature parameter from high temperature (photolithography) to low temperature (chemical vapor deposition). This parameter change enables the use of thermally labile substrates that would otherwise be damaged by conventional photolithography heating, while preserving nano-patterning accuracy.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the fabrication of complex 3D nano-structures on a wide range of substrates without high temperature processing, ensuring structural integrity and compatibility with heat-sensitive materials.

Implementation Method 1

exposing the template with any of the plurality of material precursors for a time period sufficient to bind the plurality of material precursors with at least a portion of the reacting sites

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

oxidizing the complex

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 3

the contacting is by solvent vapor annealing

Methodology Applied
Scientific EffectAnnealing: Annealing

Data Source

PatentUS12091745B2Three-dimensional nano-patterns
Publication Date: 2024.09.17 TECHNION RES & DEV FOUND LTD
  • US12091745B2 patent drawing
  • US12091745B2 patent drawing
  • US12091745B2 patent drawing

AI summary

A method for making 3D nano-structure comprising at least two materials by spatially controlling the growth of the materials, is provided. Further, a method for making 3D nano-structure bound to a thermally labile substrate is provided. Composites, comprising a substrate bound to a 3D nano-structure, wherein the 3D nano-structure is arranged in a pattern are provided.