3D Printed Core-Shell Filament for Stiffness and Damage Tolerance

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Solution Overview

Problem

Current 3D printing technologies face challenges in creating engineering materials with high damage tolerance and toughness, as high stiffness and toughness are typically mutually exclusive, and existing synthetic materials are not ideal for lattice structures, which require scalable fabrication of multi-material, heterogeneous architectures.

Innovation Solution

A 3D printed core-shell filament with a ductile polymer core and a stiff polymer shell, separated by a barrier layer, is developed using direct ink writing, where the stiff polymer has a Young's modulus higher than the ductile polymer, and the barrier layer inhibits diffusion and crack propagation, enabling the creation of lightweight, stiff, and tough structures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If high stiffness materials are used, then structural rigidity is improved, but damage tolerance and toughness deteriorate

Engineering Contradiction:
ImprovestiffnessVSAvoiddamage tolerance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The filament is segmented into distinct functional regions: a stiff polymer shell providing structural rigidity and a ductile polymer core providing toughness and damage tolerance. This segmentation allows each material to perform its optimal function without compromising the other, resolving the contradiction between stiffness and damage tolerance.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention uses composite materials by combining stiff polymer and ductile polymer in a core-shell architecture. The stiff shell provides the necessary structural rigidity while the ductile core provides toughness and energy absorption, creating a composite filament that achieves both high stiffness and high damage tolerance simultaneously.

Inventive Principle:
Principle #40Composite materials

2Strength

If multi-material heterogeneous architectures are fabricated, then mechanical properties are improved, but manufacturing complexity increases

Engineering Contradiction:
Improvemechanical propertiesVSAvoidmanufacturing complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The single-extrusion nozzle is designed to perform multiple functions: it simultaneously extrudes both the stiff polymer shell and ductile polymer core materials, controls the core-shell architecture formation, and creates the barrier layer. This multi-functionality simplifies manufacturing by consolidating what would otherwise require multiple separate processes into one universal extrusion system.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The manufacturing process uses a nested structure where the ductile polymer core is extruded first, then the barrier layer is formed around it, and finally the stiff polymer shell is extruded outward. This nested extrusion approach allows complex multi-material architecture to be created through a streamlined sequential process within a single nozzle system.

Inventive Principle:
Principle #7Nested doll (Nesting)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The core-shell filament design achieves enhanced stiffness, strength, and energy absorption, with improved mechanical properties compared to single-material filaments, particularly at specific diameter ratios, allowing for the fabrication of lightweight structures with superior damage tolerance.

Implementation Method 1

The first, second and third ink formulations are cured, thereby forming a ductile polymer from the first ink formulation, a barrier polymer from the second ink formulation, and a stiff polymer having a Young's modulus higher than that of the ductile polymer from the third ink formulation.

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Data Source

PatentUS11207831B23D printed core-shell filament and method of 3D printing a core-shell filament
Publication Date: 2021.12.28 PRESIDENT & FELLOWS OF HARVARD COLLEGE
  • US11207831B2 patent drawing
  • US11207831B2 patent drawing
  • US11207831B2 patent drawing

AI summary

A 3D printed core-shell filament comprises an elongated core radially surrounded by an outer shell with a barrier layer in between, where the elongated core comprises a ductile polymer and the outer shell comprises a stiff polymer having a Young's modulus higher than that of the ductile polymer. A lightweight lattice structure may comprise a plurality of the 3D printed core-shell filaments deposited in layers.