3D Printing Thermoplastic Polymer Dimensional Stability
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Solution Overview
Problem
3D printing techniques using polymeric build materials often result in significant dimensional changes, such as shrinkage or expansion, due to thermal cycles, leading to mechanical integrity issues and aesthetic problems like warping in the final product.
Innovation Solution
A build material composition of semi-crystalline or amorphous thermoplastic polymers with a predicted total dimension change of -4% to 9% is developed, compatible with fusing agents and radiation exposure processes, ensuring minimal shrinkage or expansion during the 3D printing process, using thermomechanical analysis to screen suitable materials.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Manufacturing precision
If conventional polymeric build materials are used in 3D printing with thermal cycles, then the printing process can be completed, but significant dimensional changes (shrinkage or expansion) occur leading to warping and mechanical integrity issues
Solution Approach 1:
The patent applies parameter changes by carefully controlling the cooling rate parameter during 3D printing to minimize dimensional changes. The method specifies cooling the build material from the printing temperature to a lower temperature at a controlled rate, which prevents excessive shrinkage or expansion that would otherwise occur with conventional thermal cycles. This parameter control directly addresses the dimensional accuracy and mechanical integrity issues.
Solution Approach 2:
The patent utilizes phase transitions by managing the thermal cycling of the build material through controlled heating and cooling. The build material undergoes phase transitions during the printing process (from solid to molten state during extrusion, then back to solid during cooling), and the controlled cooling rate manages these transitions to prevent warping and dimensional instability while maintaining mechanical integrity.
2Productivity
If conventional 3D printing processes are used, then objects can be produced, but warping and dimensional inaccuracies occur affecting the final product quality
Solution Approach 1:
The patent maintains productivity by keeping the overall 3D printing process intact while introducing a specific parameter change in the cooling rate. This allows continuous production capability to be preserved while the controlled cooling parameter prevents warping and dimensional inaccuracies, thus improving product quality without sacrificing production efficiency.
Solution Approach 2:
The patent converts the harmful effect of thermal contraction during cooling into a beneficial outcome by controlling the cooling rate. Instead of allowing uncontrolled rapid cooling that causes warping, the method uses a specific cooling rate range that harnesses the thermal contraction to achieve dimensional accuracy, thus converting a potential harm into a benefit for manufacturing precision.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The solution allows for the production of mechanically strong 3D objects with desired shapes and geometry, maintaining mechanical integrity and minimizing dimensional inaccuracies, without requiring adjustments to existing 3D printing equipment or processes.
Implementation Method 1
the fusing agent is capable of absorbing radiation and converting the absorbed radiation to thermal energy, which in turn coalesces/fuses the polymeric build material that is in contact with the fusing agent
Implementation Method 2
the patterned region (which, in some instances, is less than the entire layer) of the polymeric build material is coalesced/fused and hardened to become a layer of a 3D object
Implementation Method 3
at least partial melting may be accomplished using heat-assisted extrusion
Implementation Method 4
cooling the build material from the printing temperature to a lower temperature at a cooling rate that minimizes dimensional change in the 3D object
Data Source
AI summary
An example of a three-dimensional (3D) printing kit includes a build material composition and a fusing agent to be applied to at least a portion of the build material composition during 3D printing. The build material composition includes a semi-crystalline or amorphous thermoplastic polymer having a predicted total dimension change during 3D printing ranging from about −4% to about 9%. The fusing agent includes an energy absorber to absorb electromagnetic radiation to coalesce the semi-crystalline or amorphous thermoplastic polymer in the at least the portion. The fusing agent is a core fusing agent and the energy absorber has absorption at least at wavelengths ranging from 400 nm to 780 nm; or the fusing agent is a primer fusing agent and the energy absorber has absorption at wavelengths ranging from 800 nm to 4000 nm and has transparency at wavelengths ranging from 400 nm to 780 nm.


