3D Printing Solubilizing Agents for Ductility

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Solution Overview

Problem

Three-dimensional printing systems face limitations in producing functional parts with desired mechanical properties like mechanical strength and visual appearance due to the limited range of materials available, making it challenging for commercial production, especially in sectors like aviation and medicine.

Innovation Solution

The use of multi-fluid kits and systems that include a fusing agent, a solubilizing agent containing benzyl alcohol, and a detailing agent to enhance the elasticity and ductility of three-dimensional printed objects by selectively applying these agents during the printing process, allowing for better control over mechanical properties in three-dimensional printed objects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If traditional three-dimensional printing materials are used, then the printing process is simple, but the mechanical properties such as elasticity and ductility are limited

Engineering Contradiction:
Improvemechanical propertiesVSAvoidprinting system
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The printing system is segmented into multiple functional components: a fusing agent for bonding particles, a solubilizing agent containing benzyl alcohol for enhancing material properties, and a detailing agent for surface finishing. Each agent is applied selectively to achieve different mechanical properties in different regions of the printed object.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different chemical agents are applied to different regions of the powder bed material based on the desired local mechanical properties. The solubilizing agent with benzyl alcohol is applied where enhanced elasticity and ductility are needed, while the fusing agent is applied where structural integrity is prioritized.

Inventive Principle:
Principle #3Local quality

2Strength

If multiple agents are applied to enhance mechanical properties, then elasticity and ductility improve, but the process complexity increases

Engineering Contradiction:
Improvemechanical strengthVSAvoidmulti-fluid system
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The fusing agent and solubilizing agent are combined in a single multi-fluid printing system that can deposit both agents in one printing pass. The solubilizing agent formulation merges benzyl alcohol (10-40 wt%) with cosolvent (50-80 wt%) to achieve both particle fusion and property enhancement simultaneously.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The solubilizing agent serves multiple functions: it acts as a binding agent to fuse particles together, provides chemical solubilization to enhance ductility and elasticity, and can be applied selectively to different regions. This multi-functionality reduces the need for separate processing steps.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Adaptability or versatility

If solubilizing agent with benzyl alcohol is used, then ductility and elasticity increase, but tensile strength may be compromised

Engineering Contradiction:
Improveductility and elasticityVSAvoidtensile strength
Core Design Contradiction:
Adaptability or versatilityVSStrength

Solution Approach 1:

The concentration of benzyl alcohol in the solubilizing agent is precisely controlled at 10-40 wt% to optimize the balance between ductility enhancement and tensile strength maintenance. The cosolvent concentration is adjusted to 50-80 wt% to ensure proper solubilization without excessive softening of the material.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach results in three-dimensional printed objects with improved elasticity and ductility, reducing brittleness and enhancing mechanical properties, as demonstrated by reduced Young's modulus and increased strain at break, while maintaining tensile strength.

Implementation Method 1

The fusing agent includes water and an electromagnetic radiation absorber, wherein the electromagnetic radiation absorber absorbs radiation energy and converts the radiation energy to heat

Methodology Applied
Scientific EffectElectromagnetic radiation absorption and conversion to heat: Absorption (EM radiation)

Implementation Method 2

The solubilizing agent includes benzyl alcohol, an organic cosolvent, and water

Methodology Applied
Scientific EffectSolubilization: Solvation

Data Source

PatentUS20240141203A1Three-dimensional printing with solubilizing agents
Publication Date: 2024.05.02 PERIDOT PRINT LLC
  • US20240141203A1 patent drawing
  • US20240141203A1 patent drawing
  • US20240141203A1 patent drawing

AI summary

The present disclosure describes multi-fluid kits for three-dimensional printing, three-dimensional printing kits, and systems for three-dimensional printing. In one example, a multi-fluid kit for three-dimensional printing can include a fusing agent, a solubilizing agent, and a detailing agent. The fusing agent can include water and an electromagnetic radiation absorber. The electromagnetic radiation absorber can absorb radiation energy and convert the radiation energy to heat. The solubilizing agent can include benzyl alcohol, an organic cosolvent, and water. The detailing agent can include a detailing compound.