3D Printing Support Material for High-Temperature Polyamide Removal

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current support materials in additive manufacturing are inadequate for high-temperature part materials, as they often soften or deform under processing conditions, and existing water-soluble polymers are limited in their ability to provide effective support and easy removal from 3D parts, especially when creating hollow structures or requiring post-treatment for waste disposal.

Innovation Solution

A support material comprising more than 50% of a semi-crystalline polyamide with a melting point of at least 250°C and water uptake of at least 2% when immersed in water, which allows for effective support and easy detachment from high-temperature part materials by swelling and deformation upon exposure to moisture.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If water-soluble polymers are used as support materials, then easy removal from 3D parts is achieved, but they soften or deform under high-temperature processing conditions

Engineering Contradiction:
Improveease of removalVSAvoidsupport stability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent changes the key parameter of the support material from low melting point to high melting point (at least 250°C), while maintaining water solubility through specific polyamide composition (more than 50% semi-crystalline polyamide with at least 2% water uptake). This allows the material to remain stable during high-temperature printing yet removable through water exposure.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The support material is formulated as a composite composition containing more than 50% semi-crystalline polyamide by weight, combining the high-temperature stability of polyamide with controlled water uptake properties (at least 2%), creating a material that exhibits both thermal resistance and water solubility for easy removal.

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If high-temperature part materials are printed, then manufacturing capability for engineering plastics is improved, but support materials must withstand higher temperatures without deforming

Engineering Contradiction:
Improveprinting capabilityVSAvoidsupport stability
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent raises the melting point parameter of the support material to at least 250°C, enabling it to withstand the high processing temperatures required for engineering plastics like PEEK, while maintaining structural integrity during the printing process.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The support material uses a composite formulation with more than 50% semi-crystalline polyamide, which provides the necessary thermal stability for high-temperature printing applications while incorporating water-soluble characteristics for post-processing removal.

Inventive Principle:
Principle #40Composite materials

3Ease of manufacture

If soluble polymers are used as support material, then hollow structures can be generated, but post-treatment of waste water is required for disposal

Engineering Contradiction:
Improvehollow structure capabilityVSAvoidwaste water treatment
Core Design Contradiction:
Ease of manufactureVSLoss of substance

Solution Approach 1:

The patent optimizes the water uptake parameter of the polyamide support material to be at least 2%, enabling effective water-soluble removal while using a high-temperature stable base material, thus maintaining hollow structure capability with reduced environmental impact compared to traditional water-soluble polymers.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the printing of high-temperature engineering plastics by providing robust support and facilitating easy removal of the support structure from the 3D object, reducing post-processing burdens and improving the manufacturing efficiency of complex geometries.

Implementation Method 1

a support material comprising more than 50% wt. of a semi-crystalline polyamide (A) having a melting point of at least 250° C. and possessing a water uptake at saturation, by immersion in water at 23° C., of at least 2% wt.

Methodology Applied
Scientific EffectWater uptake: Absorption (physical)

Data Source

PatentUS11911954B2Method for manufacturing a three-dimensional object
Publication Date: 2024.02.27 SOLVAY SPECIALTY POLYMERS USA LLC
  • US11911954B2 patent drawing
  • US11911954B2 patent drawing
  • US11911954B2 patent drawing

AI summary

The invention pertains to a method for manufacturing a three-dimensional object with an additive manufacturing system, such as an extrusion-based additive manufacturing system, a selective laser sintering system, and/or an electrophotography-based additive manufacturing system, comprising providing a support material comprising more than 50% wt. of a semi-crystalline polyamide [polyamide (A)] having a melting point, as determined according to ASTM D3418, of at least 250° C. and possessing a water absorption at saturation, by immersion in water at 23° C., of at least 2% wt.