Anodic Aluminum Oxide Invisible Ink for Stable Luminescence

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Solution Overview

Problem

Existing invisible inks made from organic and inorganic luminescent materials suffer from poor stability, high production costs due to the use of rare earth elements, and environmental pollution from solvents.

Innovation Solution

An invisible ink composed of anodic aluminum oxide (AAO) powder and solvents, where the AAO powder is produced through an anodic oxidation process on aluminum substrates, followed by separation and pulverization, and then mixed with silicone oil and dispersants.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If organic luminescent materials are used in invisible ink, then the ink can be produced with simpler materials, but the stability deteriorates due to decomposition and fading under high temperature or long term illumination

Engineering Contradiction:
Improveease of manufactureVSAvoidstability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent replaces unstable organic luminescent materials with inorganic aluminum oxide particles that provide long-term stability and resistance to decomposition, effectively substituting short-lived organic compounds with durable inorganic materials that maintain luminescence properties over time and under various environmental conditions

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Reliability

If inorganic luminescent materials containing rare earth elements are used, then the stability is improved, but the production cost increases significantly due to low yield and expensive rare earth elements

Engineering Contradiction:
ImprovestabilityVSAvoidproduction cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent extracts and eliminates rare earth elements from the luminescent material composition, using pure aluminum oxide particles that can be produced through inexpensive anodization of aluminum substrates. This extraction of the expensive rare earth component while retaining the luminescent functionality directly addresses the cost-stability contradiction

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent substitutes expensive inorganic luminescent materials containing rare earth elements with inexpensive aluminum oxide particles derived from common aluminum substrates, achieving a cost-effective solution that maintains stability through the use of abundant, low-cost materials

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Reliability

If inorganic luminescent materials are used, then the stability is improved, but environmental pollution increases due to the use of harmful solvents and production processes

Engineering Contradiction:
ImprovestabilityVSAvoidenvironmental pollution
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent converts the typically harmful production process into an environmentally beneficial one by using anodization, which naturally forms aluminum oxide layers on aluminum substrates. This process utilizes oxygen from the air and electrical energy to create the luminescent material, eliminating the need for harmful chemical solvents and production processes while maintaining stability

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The AAO-based invisible ink exhibits stable luminescence properties, is resistant to decomposition, and has a lower production cost without the need for rare earth elements, while also minimizing environmental impact.

Implementation Method 1

An invisible ink or pigment is colorless and invisible under visible light until but visible under specific conditions such as UV radiation

Methodology Applied
Scientific EffectFluorescence: Fluorescence

Implementation Method 2

the AAO-based invisible ink exhibits stable luminescence properties

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Implementation Method 3

carrying out an anodic oxidation process on the aluminum substrate at least once to form an anodic aluminum oxide (AAO) layer on a surface of the aluminum substrate

Methodology Applied
Scientific EffectAnodic oxidation: Anodising

Data Source

PatentUS12325803B2Invisible ink and method of making the same
Publication Date: 2025.06.10 NAT CHENG KUNG UNIV
  • US12325803B2 patent drawing
  • US12325803B2 patent drawing
  • US12325803B2 patent drawing

AI summary

An invisible ink and a method of making the same are revealed. The invisible ink includes anodic aluminum oxide (AAO) powder and at least one solvent. The method of making the invisible ink includes the steps of taking an aluminum substrate and carrying out anodic oxidation on the aluminum substrate at least once to form an anodic aluminum oxide (AAO) layer on a surface of the aluminum substrate, separating the AAO layer from the aluminum substrate and pulverizing the separated AAO layer to get AAO powder, and adding the AAO powder into a solvent to obtain the invisible ink.