Abrasive Blasted Cathode for Wet Electrolytic Capacitor Adhesion

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Solution Overview

Problem

Conventional wet electrolytic capacitors face issues with mechanical robustness and electrical performance due to the detachment of coatings in the presence of aqueous electrolytes, leading to reduced capacitance and increased leakage current.

Innovation Solution

A method involving abrasive blasting of a metal substrate to create a micro-roughened surface with pits, followed by the application of a conductive coating, enhances the adhesion and surface area, thereby improving mechanical robustness and electrical performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a coating is applied on a smooth metal substrate surface, then the coating can be easily applied, but the coating becomes easily detached under certain conditions such as in the presence of aqueous electrolytes

Engineering Contradiction:
Improvecoating application easeVSAvoidcoating adhesion
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The metal substrate surface is pre-treated by abrasive blasting to create a micro-roughened surface with pits before coating application. This preliminary surface modification enhances coating adhesion by providing mechanical interlocking, preventing coating detachment in aqueous electrolytes while maintaining ease of coating application

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The abrasive blasting process creates a porous micro-roughened surface structure with pits on the metal substrate. This porous surface increases the surface area and provides anchoring points for the conductive coating, significantly improving coating adhesion and mechanical robustness

Inventive Principle:
Principle #31Porous materials

2Quantity of substance

If the cathode surface area is increased to improve capacitance, then the capacitance increases, but the capacitor volume increases

Engineering Contradiction:
Improvecathode capacitanceVSAvoidcapacitor volume
Core Design Contradiction:
Quantity of substanceVSVolume of stationary object

Solution Approach 1:

The micro-roughened porous surface created by abrasive blasting increases the effective surface area of the cathode without increasing the physical dimensions of the capacitor. The pits and roughness features provide additional surface area for charge storage, enabling higher capacitance in a compact volume

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The invention transitions from a smooth two-dimensional surface to a three-dimensional micro-roughened surface with pits and protrusions. This dimensional transformation increases the effective surface area available for capacitance while maintaining the same external capacitor dimensions, effectively utilizing vertical space

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Ease of manufacture

If conventional coatings are used in wet electrolytic capacitors, then the capacitor can be manufactured with standard materials, but the coatings detach leading to increased leakage current

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidleakage current
Core Design Contradiction:
Ease of manufactureVSObject-generated harmful factors

Solution Approach 1:

The metal substrate undergoes abrasive blasting pretreatment to create a micro-roughened surface before coating application. This preliminary action ensures that conventional coatings adhere properly, preventing detachment and the associated increase in leakage current while maintaining manufacturing simplicity

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The porous micro-roughened surface structure provides mechanical interlocking for the conductive coating, preventing coating detachment that would otherwise create conductive paths and increase leakage current in the wet electrolytic capacitor

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach results in increased cathode capacitance for a given size, reduced size for a given capacitance, and lower equivalent series resistance and leakage current, while maintaining mechanical robustness.

Implementation Method 1

blasting a metal substrate with a plurality of abrasive particles to form a micro-roughened surface having a plurality of pits

Methodology Applied
Scientific EffectAbrasion: Abrasion

Implementation Method 2

a conductive coating is formed on the micro-roughened surface

Methodology Applied
Scientific EffectDeposition: Deposition (physical)

Implementation Method 3

a porous anode body that contains a dielectric layer formed by anodic oxidation

Methodology Applied
Scientific EffectAnodic oxidation: Anodising

Data Source

PatentUS9129747B2Abrasive blasted cathode of a wet electrolytic capacitor
Publication Date: 2015.09.08 KYOCERA AVX COMPONENTS CORP
  • US9129747B2 patent drawing
  • US9129747B2 patent drawing
  • US9129747B2 patent drawing

AI summary

A wet electrolytic capacitor that includes a porous anode body containing a dielectric layer, an electrolyte, and a cathode containing a metal substrate on which is disposed a conductive coating is provided. Prior to application of the conductive coating, the metal substrate is blasted with abrasive particles to enhance the ability of the substrate to adhere to the coating. The micro-roughened metal substrate can be treated after blasting so that substantially all of the abrasive particles are removed. This is accomplished by contacting the metal substrate with an extraction solution to remove the particles, and also by selectively controlling the nature of the abrasive particles so that they are dispersible (e.g., soluble) in the solution.