ACC Solid Compositions for Stable Water-Soluble Granules

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Solution Overview

Problem

Existing formulations of 1-amino-1-cyclopropanecarboxylic acid (ACC) are not available in stable water-soluble granule or wettable powder forms, which are preferred by farmers for their storage stability and ease of application.

Innovation Solution

Formulations of ACC in water-soluble granules and wettable powders comprising specific fillers, wetting agents, binders, and organosilicon surfactants, such as lactose, non-ionic ethoxylated sorbitan, polyvinylpyrrolidone, and polyalkyleneoxide modified heptamethyltrisiloxane, to create stable and easily dissolvable solid compositions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If ACC is formulated as liquid formulations, then storage and application benefits are achieved, but solid formulation requirements cannot be met

Engineering Contradiction:
Improveformulation adaptabilityVSAvoidhandling and transport
Core Design Contradiction:
Adaptability or versatilityVSEase of operation

Solution Approach 1:

The patent transforms ACC from liquid to solid state by changing physical parameters through formulation with fillers, binders, and surfactants. This creates water-soluble granules and wettable powders that maintain chemical activity while providing solid formulation benefits for handling, transport, and storage.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite solid formulations by combining ACC with fillers (such as diatomaceous earth, silica, calcium carbonate), binders, and surfactants. These composite materials provide both the chemical activity of ACC and the physical properties of stable solid formulations that are easy to handle and transport.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If water-soluble granule formulations are used, then storage stability and ease of dissolving are improved, but stable ACC granule formulation does not exist

Engineering Contradiction:
Improveease of dissolvingVSAvoidstorage stability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent uses fillers, binders, and surfactants as intermediary substances that enable ACC to form stable water-soluble granules. These intermediaries facilitate both storage stability and ease of dissolving by creating a matrix that protects ACC while allowing controlled release and dissolution in water.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the physical and chemical parameters of ACC through formulation to achieve both storage stability and water solubility. By controlling particle size, moisture content, and composition ratios of ingredients, the formulation achieves simultaneous optimization of stability and dissolvability.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If ACC is synthesized and used directly, then ethylene precursor function is achieved, but consistent thinning and coloration require specific formulations

Engineering Contradiction:
Improvethinning consistencyVSAvoidformulation complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent optimizes formulation parameters including pH control (using acids or bases), moisture content (5-20%), and ingredient ratios to ensure consistent ACC release and ethylene production. These parameter controls provide reliable thinning and coloration effects while maintaining manageable formulation complexity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops composite formulations with specific ratios of ACC, fillers, binders, and surfactants that work synergistically to provide consistent agricultural effects. The composite structure ensures uniform distribution and controlled release of ACC, leading to reliable thinning and fruit coloration outcomes.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The formulations provide stable, resilient, and easily dissolvable ACC granules and powders, maintaining ACC concentration and activity under various storage conditions, suitable for agricultural applications.

Implementation Method 1

one or more organosilicon surfactants selected from the group consisting of a polyalkyleneoxide modified heptamethyltrisiloxane and a polyether trisiloxane

Methodology Applied
Scientific EffectSurface tension reduction: Surfactant

Implementation Method 2

one or more wetting agents selected from the group consisting of a non-ionic ethoxylated sorbitan, a polyoxyethylene glycol alkyl ether and an anionic dioctyl sulfosuccinate

Methodology Applied
Scientific EffectWetting: Wetting

Data Source

PatentUS12356992B21-amino-1-cyclopropanecarboxylic acid solid compositions
Publication Date: 2025.07.15 VALENT BIOSCIENCES CORP
  • US12356992B2 patent drawing

AI summary

The present invention is directed to a water-soluble granule compositions comprising 1-amino-1-cyclopropanecarboxylic acid (“ACC”), a filler selected from the group consisting of lactose, dextrose, sucrose or a mixture thereof, one or more wetting agents selected from the group consisting of a non-ionic ethoxylated sorbitan, a polyoxyethylene glycol alkyl ether and an anionic dioctyl sulfosuccinate, one or more binders selected from the group consisting of polyvinylpyrrolidone and a lignosulfonate and one or more organosilicon surfactants selected from the group consisting of a polyalkyleneoxide modified heptamethyltrisiloxane and a polyether trisiloxane.