Acetoacetate Polymer Coated Filter for Permanent Aldehyde Removal

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Solution Overview

Problem

Current air filtration technologies are inadequate for effectively and permanently removing gaseous aldehydes like formaldehyde and acetaldehyde from indoor air and tobacco smoke, as they often rely on physical adsorption rather than chemical reaction, and existing materials can be hazardous or ineffective in maintaining the removal over time.

Innovation Solution

A filter support material coated with a polymeric composition containing acetoacetate residues and a metallic oxidizing agent or oxidation catalyst, selected from condensation polymers, addition polymers, epoxy resins, polysiloxanes, cellulose, and cellulose esters, which chemically reacts with aldehydes to form stable bonds, ensuring permanent removal.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If physical adsorption is used to remove formaldehyde, then the filter structure is simple and cost-effective, but the removal is not permanent and effectiveness decreases over time

Engineering Contradiction:
Improvepermanent removal effectivenessVSAvoidfilter composition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent uses a composite material consisting of a porous support filter coated with a polymeric amine layer. This composite structure combines the mechanical support function of the porous substrate with the chemical reactivity of the polymeric amine coating, enabling permanent chemical removal of formaldehyde while maintaining filter structural integrity

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical parameters of the filter by coating it with a polymeric amine, transforming it from a purely physical adsorption medium to a chemical reaction medium. This parameter change enables the filter to permanently remove formaldehyde through chemical bonding rather than temporary physical adsorption

Inventive Principle:
Principle #35Parameter changes

2Reliability

If polymeric amine coating is used to chemically react with formaldehyde, then permanent removal is achieved, but the amine is consumed by carbon dioxide in air reducing effectiveness

Engineering Contradiction:
Improvealdehyde removal effectivenessVSAvoidfilter service life
Core Design Contradiction:
ReliabilityVSDuration of action of moving object

Solution Approach 1:

The patent applies local quality by creating a specialized coating layer with specific chemical properties on the surface of the porous support. The polymeric amine coating is localized on the filter surface where it can selectively react with aldehydes passing through the filter, while the bulk support structure remains inert and unaffected by carbon dioxide

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent converts the potential harm of polymeric amine consumption by carbon dioxide into a benefit by designing a system where the coating is applied in such a way that aldehyde removal is the primary and dominant reaction. The coating's reactivity with carbon dioxide is minimized through proper formulation and application, allowing the filter to maintain effectiveness over extended service periods

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Reliability

If strong oxidizing agents are used to treat fibers, then aldehyde removal capability is enhanced, but the treated fibers become hazardous to handle

Engineering Contradiction:
Improvealdehyde removal capabilityVSAvoidhandling hazard
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical parameters by using a polymeric amine coating instead of treating the fiber bulk with strong oxidizing agents. This parameter change allows the filter to achieve aldehyde removal capability through a safer chemical mechanism that does not require hazardous materials

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces a polymeric amine coating as an intermediary layer between the air stream and the fiber support. This intermediary coating provides the chemical reactivity needed for aldehyde removal without requiring the fibers themselves to be treated with hazardous strong oxidizing agents, thus eliminating handling hazards while maintaining removal capability

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a lightweight, cost-effective, and safe filter medium that chemically reacts with aldehydes, offering efficient and permanent removal of formaldehyde and other gaseous pollutants from air and tobacco smoke, maintaining effectiveness over time without the hazards associated with previous technologies.

Implementation Method 1

a polymeric composition containing acetoacetate residues and a metallic oxidizing agent or oxidation catalyst

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

chemically reacts with aldehydes to form stable bonds, ensuring permanent removal

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentEP2099323B1Acetoacetate polymer coated aldehyde removal filter
Publication Date: 2015.05.27 EASTMAN CHEM CO
  • EP2099323B1 patent drawing
  • EP2099323B1 patent drawing
  • EP2099323B1 patent drawing

AI summary

Disclosed are filter elements constructed of a filter support material coated with an acetoacetate-functional polymeric composition that reacts with and removes aldehydes, especially formaldehyde, present in gases such as air. Also disclosed are methods for the removal of aldehydes utilizing the coated filter support materials.