Acetoacetate Urethane Adhesive for Structural Bonding

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Solution Overview

Problem

Existing adhesives for direct glazing in the automobile industry lack sufficient elasticity and mechanical strength, making them unsuitable for structural bonding applications.

Innovation Solution

A reactive composition based on a multifunctional acetoacetate compound and a multifunctional urethane (meth)acrylate oligomer, combined with a catalyst and a selected amount of filler, which exhibits excellent tensile strength and elongation at break.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If silane modified polymers are used as adhesives, then toxicological profile is improved, but mechanical properties deteriorate

Engineering Contradiction:
Improvetoxicological profileVSAvoidmechanical properties
Core Design Contradiction:
Object-affected harmful factorsVSStrength

Solution Approach 1:

The patent combines silane modified polymers with reactive elastomers to create a composite adhesive system. This composite approach allows the adhesive to benefit from the low toxicity of silane polymers while gaining the enhanced mechanical properties and elasticity from the elastomeric component, thereby resolving the contradiction between toxicological safety and mechanical performance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical composition parameters of the adhesive by incorporating specific elastomeric components with defined molecular weights and functionality. This parameter change enables the adhesive to achieve both low toxicity and high mechanical strength, transforming the adhesive from a single-component system with limited properties to a multi-component system with optimized performance.

Inventive Principle:
Principle #35Parameter changes

2Strength

If polyurethane based adhesives are used, then bonding performance is improved, but safety deteriorates due to hazardous isocyanate component

Engineering Contradiction:
Improvebonding performanceVSAvoidhazardous isocyanate component
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent extracts and removes the hazardous isocyanate component from the adhesive formulation while retaining the beneficial bonding performance through alternative chemistry. By using silane modified polymers and reactive elastomers that cure via moisture or catalyst-driven mechanisms rather than isocyanate reactions, the adhesive achieves high bonding strength without the safety risks associated with isocyanates.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent introduces silane modified polymers as intermediary substances that enable crosslinking and bond formation without requiring isocyanates. These silane polymers act as mediators that provide the necessary reactivity and mechanical properties traditionally achieved through isocyanate-based polyurethane chemistry, but through a safer chemical pathway.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of operation

If existing adhesives are used for direct glazing, then application is simplified, but mechanical strength and elasticity are insufficient

Engineering Contradiction:
Improveapplication simplicityVSAvoidmechanical strength and elasticity
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The patent creates a multi-functional adhesive system that simultaneously provides structural bonding strength, elasticity, and ease of application. The adhesive can be applied in a paste-like form similar to conventional adhesives, but upon curing develops the mechanical properties needed for structural bonding, thereby combining the ease of operation of simple adhesives with the strength of structural adhesives.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The reactive composition achieves a tensile strength of no less than 2 MPa and an elongation at break of no less than 100%, making it suitable for structural bonding applications such as direct glazing.

Implementation Method 1

Michael addition chemistry, for example based on the reaction system containing acetoacetate and (meth)acrylate has been researched and used in some bonding applications

Methodology Applied
Scientific EffectMichael addition chemistry: Chemical Bonding

Implementation Method 2

Michael addition chemistry, for example based on the reaction system containing acetoacetate and (meth)acrylate has been researched and used in some bonding applications

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentEP4495202A1Reactive composition comprising acetoacetates and (METH)acrylates
Publication Date: 2025.01.22 HENKEL KGAA
  • EP4495202A1 patent drawing
  • EP4495202A1 patent drawing
  • EP4495202A1 patent drawing

AI summary

The present invention relates to a reactive adhesive composition based on acetoacetate compound, and to its use in structural bonding applications. In particular, the reactive composition comprises (a) a multifunctional acetoacetate compound, (b) a multifunctional urethane (meth)acrylate oligomer, (c) a catalyst, and (d) a filler, wherein the filler is present in an amount of from 20% by weight to less than 75% by weight of the total weight of the reactive composition.