Acicular Titanium Oxide Toner Masking Chargeability

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Solution Overview

Problem

Conventional white electrostatic charge image developing toners with high titanium oxide content suffer from insufficient masking effects when overlaid on color grounds due to reduced electric chargeability, limiting the loadable amount of spherical titanium oxide.

Innovation Solution

Incorporating acicular titanium oxide particles with an average aspect ratio between 3 to 30, which enhances masking effects by reducing gaps between toner particles and improving covering rate, thereby achieving higher masking performance compared to spherical titanium oxide at equal amounts.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If spherical titanium oxide is added in high content to improve masking effects, then masking performance is improved, but electric chargeability deteriorates

Engineering Contradiction:
Improvetitanium oxide contentVSAvoidelectric chargeability
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The invention changes the shape parameter of titanium oxide from spherical to acicular (needle-like), which fundamentally alters how the pigment particles pack and interact with light and electric fields. This shape transformation allows achieving high masking effects with lower titanium oxide content, thereby preserving electric chargeability while improving masking performance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite toner system combining acicular titanium oxide particles with specific binder resins and charge control agents. This composite approach optimizes the interaction between pigment and binding materials, enabling high titanium oxide dispersion and effective charge control even at elevated pigment concentrations, thus resolving the contradiction between masking and chargeability.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If spherical titanium oxide is used to achieve high masking effects, then masking performance is improved, but the loadable amount is limited due to reduced electric chargeability

Engineering Contradiction:
Improveloadable amount of titanium oxideVSAvoidelectric chargeability
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

By transforming the shape parameter of titanium oxide from spherical to acicular form, the invention enables higher loadable amounts of titanium oxide in the toner composition. The needle-like structure provides better packing efficiency and light scattering properties, allowing increased pigment content without proportionally increasing the negative impact on electric chargeability.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS10409184B2Electrostatic charge image developing toner comprising acicular titanium oxide
Publication Date: 2019.09.10 KONICA MINOLTA INC
  • US10409184B2 patent drawing

AI summary

An electrostatic charge image developing toner includes a white pigment being acicular titanium oxide having an average aspect ratio within a range of 3 to 30.