Acid Dye Composition for Level Polyamide Dyeing in Aqueous Media

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Solution Overview

Problem

Current acid dyes are not effectively used for dyeing polyamide fibers in aqueous media, particularly for achieving high fastness and level dyeings on natural and synthetic polyamides like wool and nylon.

Innovation Solution

Development of specific acid dyes with the general formula (I), containing anionic substituents such as sulpho groups, which are used in combination with conventional processes to produce compounds suitable for dyeing polyamide fibers, offering high fastness and level dyeings in aqueous media.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional acid dyes are used for dyeing polyamide fibers, then dyeing can be performed, but high fastness and level dyeings cannot be achieved in aqueous media

Engineering Contradiction:
ImprovefastnessVSAvoidapplicability to aqueous media dyeing
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent modifies the chemical structure of acid dyes by introducing specific anionic substituents (sulpho groups) at defined positions in the molecular structure. This parameter change in molecular composition enables the dye to function effectively in aqueous media while maintaining high fastness properties on polyamide fibers, resolving the contradiction between fastness and media adaptability.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If specific structural modifications are made to achieve high fastness, then fastness improves, but dyeing process simplicity may deteriorate

Engineering Contradiction:
ImprovefastnessVSAvoiddye structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies local quality by introducing sulpho groups at specific local positions (R1 and/or R2) in the dye molecule rather than uniformly modifying the entire structure. This localized modification achieves the desired fastness improvement while minimizing overall structural complexity and maintaining compatibility with conventional dyeing processes.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The dyes provide excellent light and wet fastness, level dyeings, and are compatible with existing acid dyes, suitable for various dyeing processes including Inkjet printing, achieving consistent hues and high exhaustion rates on polyamide fibers.

Implementation Method 1

The dyes of the formula (I) and their salts are particularly suitable for dyeing or printing fibrous material consisting of natural or synthetic polyamides

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

both the amine functions of compounds of the formula (II) which are known from the literature are conventionally diazotized and coupled onto totally two equivalents of a compound of the formula (III)

Methodology Applied
Scientific EffectDiazotization: Chemical Bonding

Implementation Method 3

both the amine functions of compounds of the formula (II) which are known from the literature are conventionally diazotized and coupled onto totally two equivalents of a compound of the formula (III)

Methodology Applied
Scientific EffectAzo coupling: Chemical Bonding

Data Source

PatentEP2307509B1Use of acid dyes
Publication Date: 2012.02.29 CLARIANT FIANCE (BVI) LTD
  • EP2307509B1 patent drawing
  • EP2307509B1 patent drawing
  • EP2307509B1 patent drawing

AI summary

Use acid dyes for dyeing organic substrates of the general formula (I) wherein the substituents have the meaning as indicated in the claims.