Acid Gas Separation Membrane with Segmented Hydrophobic Layers

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Solution Overview

Problem

In membrane separation methods for separating acid gas from gaseous mixtures containing acid gas and water vapor, the permeation of water vapor through facilitated transport membranes with hydrophilic resins lowers the dew point of residual process gas, making it difficult to recover heat energy efficiently.

Innovation Solution

An acid gas separation membrane is developed, comprising an acid gas separation layer with a hydrophilic resin and an acid gas carrier, a hydrophobic porous membrane layer, a porous membrane protective layer, and a first layer with specific Gurley numbers to enhance acid gas permeability while suppressing water vapor permeation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a facilitated transport membrane containing a hydrophilic resin is used to separate acid gas from a gaseous mixture, then acid gas permeability is improved, but water vapor permeation increases which lowers the dew point of residual process gas and makes heat energy recovery difficult

Engineering Contradiction:
Improveacid gas permeabilityVSAvoidheat energy recovery efficiency
Core Design Contradiction:
ProductivityVSLoss of energy

Solution Approach 1:

The membrane is divided into multiple functional layers: a first layer (hydrophobic porous layer) to suppress water vapor permeation, a second layer (facilitated transport layer with hydrophilic resin and acid gas carrier) to enable acid gas permeation, and a third layer (hydrophobic porous layer) to further suppress water vapor permeation. This segmentation allows each layer to perform its specific function, resolving the contradiction between acid gas permeability and water vapor suppression.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different layers of the membrane have different local properties: the first and third layers are hydrophobic to repel water vapor, while the second layer is hydrophilic to facilitate acid gas transport. This local quality differentiation enables the membrane to simultaneously achieve high acid gas permeability and low water vapor permeation, maintaining dew point for heat recovery.

Inventive Principle:
Principle #3Local quality

2Loss of energy

If water vapor permeation is suppressed to maintain dew point for heat recovery, then heat energy recovery efficiency is improved, but acid gas permeability may be reduced

Engineering Contradiction:
Improveheat energy recovery efficiencyVSAvoidacid gas permeability
Core Design Contradiction:
Loss of energyVSProductivity

Solution Approach 1:

The membrane is segmented into hydrophobic layers (first and third layers) for water vapor suppression and a hydrophilic facilitated transport layer (second layer) for acid gas permeation. This segmentation ensures that water vapor suppression does not compromise acid gas permeability, as each layer is optimized for its specific function.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The membrane uses a composite structure combining hydrophobic porous materials (for water vapor suppression) with hydrophilic resin and acid gas carrier (for acid gas permeation). This composite material approach allows the membrane to simultaneously achieve both functions: suppressing water vapor to maintain dew point while maintaining high acid gas permeability through the facilitated transport mechanism.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The membrane achieves excellent acid gas permeability and effective suppression of water vapor permeation, enabling efficient separation of acid gas and facilitating the recovery of heat energy from residual process gas.

Implementation Method 1

using a facilitated transport membrane containing a hydrophilic resin

Methodology Applied
Scientific EffectFacilitated transport:

Implementation Method 2

a hydrophobic porous membrane layer supporting the acid gas separation layer

Methodology Applied
Scientific EffectHydrophobic effect: Hydrophobe

Implementation Method 3

separates acid gas from a gaseous mixture containing the acid gas and water vapor through permeation

Methodology Applied
Scientific EffectPermeation: Permeation

Data Source

PatentEP3441132B1Acidic gas separation membrane and acidic gas separation method using same, acidic gas separation module, and acidic gas separation device
Publication Date: 2025.04.23 SUMITOMO CHEM CO LTD
  • EP3441132B1 patent drawingFigure 1~2
  • EP3441132B1 patent drawingFigure 3~4
  • EP3441132B1 patent drawingFigure 5~6

AI summary

Provided is an acid gas separation membrane that includes an acid gas separation layer containing a hydrophilic resin and an acid gas carrier, a hydrophobic porous membrane layer supporting the acid gas separation layer, a porous membrane protective layer protecting the acid gas separation layer, and a first layer having a Gurley number of less than or equal to 0.5 times a Gurley number of the hydrophobic porous membrane layer and the porous membrane protective layer, the Gurley number of the first layer being greater than or equal to 0.1 s and less than or equal to 30 s. Also provided is an acid gas separation method using the acid gas separation membrane, as well as an acid gas separation module and an acid gas separation apparatus that each include the acid gas separation membrane.