Heat Integration in Acid Gas Removal Solvent Regeneration

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Solution Overview

Problem

Existing acid gas removal processes, such as the Selexol® process, face inefficiencies due to low feed temperatures in the hot solvent regeneration loop and energy losses in heat exchangers, leading to increased energy consumption and reduced process efficiency.

Innovation Solution

Utilizing overhead waste process heat to increase the feed temperature of the hot solvent regeneration loop by separating and heating slip streams from rich solvent streams, which are then combined with heated rich solvent streams to enhance the temperature and efficiency of the regeneration process, thereby reducing energy losses and improving heat integration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If conventional heat exchange processes are used in the hot solvent regeneration loop, then the process can operate with standard equipment, but energy losses increase and process efficiency decreases

Engineering Contradiction:
Improveenergy losses in heat exchangersVSAvoidprocess efficiency
Core Design Contradiction:
Loss of energyVSProductivity

Solution Approach 1:

The patent combines multiple heat exchange functions into an integrated system where the bridge heat exchanger merges the hot solvent stream with the slip stream, and the stripper gas heat exchanger merges heated slip stream with rich solvent stream. This merging of heat exchange pathways eliminates energy losses by ensuring all available heat is utilized in the regeneration process.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent converts the previously wasted overhead process heat into a beneficial resource by routing it through the bridge heat exchanger and stripper gas heat exchanger to preheat solvent streams. The waste heat that would have been lost is now utilized to increase feed temperature and reduce reboiler duty, transforming an energy loss into a process advantage.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Use of energy by moving object

If the feed temperature to the hot solvent regeneration loop is increased, then energy consumption is reduced, but additional heating equipment and process complexity are required

Engineering Contradiction:
Improveenergy consumptionVSAvoidprocess complexity
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The bridge heat exchanger and stripper gas heat exchanger perform multiple functions: they transfer heat from waste streams to solvent streams, preheat feed to the regeneration loop, and utilize overhead waste process heat. This multi-functionality allows the system to achieve higher feed temperatures and reduced energy consumption without requiring separate dedicated heating equipment for each function.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The system uses its own overhead waste process heat to preheat the solvent streams entering the regeneration loop. The heat exchangers are positioned within the process itself, allowing the process to self-heat using internally generated waste heat, thereby reducing external energy requirements and minimizing the need for additional heating equipment.

Inventive Principle:
Principle #25Self-service

3Loss of energy

If overhead waste process heat is utilized to increase feed temperature, then energy savings are achieved, but additional heat exchangers and process steps are required

Engineering Contradiction:
Improveenergy savingsVSAvoidnumber of heat exchangers
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The bridge heat exchanger and stripper gas heat exchanger serve as intermediaries that transfer heat from the waste process heat streams to the solvent streams requiring heating. These intermediary heat exchangers enable the utilization of waste heat without requiring direct mixing or complex heat integration, achieving energy savings while maintaining process simplicity through standardized heat exchange equipment.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach increases the temperature of the hot solvent regeneration loop, enhances the performance of downstream units, reduces the reboiler duty, and achieves energy savings of up to 20% by optimizing heat recovery and reducing stripping gas requirements.

Implementation Method 1

at least one absorber including an absorbent material that absorbs acid gas. Acid gas can be removed from the feed gas by absorption to produce a first rich solvent stream including solvent and acid gas

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 2

At least one slip stream can be separated from the first rich solvent stream, and the at least one slip stream can be heated by heat exchange to produce at least one heated slip stream

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 3

At least a portion of the first rich solvent stream can be passed to a bridge heat exchanger to produce a heated rich solvent stream

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Data Source

PatentUS7785399B2Heat integration for hot solvent stripping loop in an acid gas removal process
Publication Date: 2010.08.31 UOP LLC
  • US7785399B2 patent drawing
  • US7785399B2 patent drawing

AI summary

Systems and processes utilize one or more methods of providing overhead waste process heat to increase the feed temperature of the hot solvent stripping regeneration loop in an acid gas removal process. A heated rich solvent stream can be the primary feed for the hot solvent stripping regeneration loop, and one or more slip streams can be heated and then combined with the heated rich solvent stream to form a combined rich solvent stream prior to further processing in downstream units to remove acid gas from the solvent. A first slip stream can be heated in a stripper gas heat exchanger by heat exchange with a stripped gas stream. A second slip stream can be heated in a regenerator exchanger by heat exchange with an acid gas stream. A third slip stream can be heated in a recycle gas exchanger by heat exchange with a compressed recycle gas stream.