Acid-Sensitive Emulsifier for Subterranean Wellbore Cleaning

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Solution Overview

Problem

Conventional invert emulsion drilling fluids are difficult to break and remove from wellbores, requiring substantial cleaning and storage, which complicates subsequent cementing and completion operations.

Innovation Solution

The use of an invert emulsion fluid system comprising an oleaginous fluid, a non-oleaginous fluid, and an amine surfactant emulsifier, which can be broken by an acid treatment, allowing for efficient removal and reducing storage needs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional invert emulsion drilling fluids are used, then hole stability and lubrication properties are improved, but the fluids become difficult to break and remove from wellbores

Engineering Contradiction:
Improvehole stabilityVSAvoidease of removal
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent applies parameter changes by modifying the chemical composition parameters of the emulsion system. Specifically, it uses a distinct internal phase composition (water, alcohol, surfactant) different from conventional formulations, and controls the emulsifier concentration at 0.1-10% by weight. These parameter changes enable the emulsion to maintain stability during drilling while becoming easily breakable upon contact with formation water or acid treatments.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by creating an invert emulsion system with multiple integrated components: oleaginous external phase, distinct internal phase (water-alcohol-surfactant), and emulsifier. This composite structure provides both the desired hole stability and lubrication properties while incorporating inherent breakability through the specific interaction between the internal phase surfactants and formation water or acid.

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional invert emulsion drilling fluids are used, then lubrication properties are improved, but substantial cleaning and storage are required

Engineering Contradiction:
Improvelubrication propertiesVSAvoidcleaning and storage requirements
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies self-service by designing an emulsion system that automatically breaks and removes itself through natural interactions with formation water or acid treatments. The distinct internal phase composition causes the emulsion to self-demulsify upon contact with formation water, eliminating the need for complex mechanical cleaning equipment and extensive storage facilities. The system essentially cleans itself through the chemical interaction with the formation environment.

Inventive Principle:
Principle #25Self-service

3Reliability

If conventional invert emulsion drilling fluids are used, then hole stability is improved, but additional cleaning treatments are required

Engineering Contradiction:
Improvehole stabilityVSAvoidoperational efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent applies preliminary action by pre-configuring the emulsion with a distinct internal phase composition that is specifically designed to be incompatible with formation water and acid. This preliminary design ensures that when the drilling fluid contacts formation water or undergoes acid treatment, the emulsion automatically breaks without requiring additional cleaning agents or extended treatment processes. The breakability is built into the formulation from the outset.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables cleaner wellbores with reduced additional cleaning treatments, facilitates 'flow to host' applications, and recovers trapped components, enhancing operational efficiency and cost-effectiveness.

Implementation Method 1

an amine surfactant emulsifier

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 2

contacting at least a portion of the treatment fluid with the acid or acid source; and breaking the invert emulsion

Methodology Applied
Scientific EffectProtonation:

Data Source

PatentUS11186763B2Acid sensitive emulsifier for use in subterranean treatment operations
Publication Date: 2021.11.30 HALLIBURTON ENERGY SERVICES INC
  • US11186763B2 patent drawing
  • US11186763B2 patent drawing
  • US11186763B2 patent drawing

AI summary

Methods and systems for using an invert emulsion fluid that is beneficial in the drilling, completing and working over of subterranean wells are provided. In some embodiments, the method includes: preparing a treatment fluid including an invert emulsion, wherein the invert emulsion further includes an aqueous dispersed phase, an oleaginous continuous phase, and an amine surfactant emulsifier and placing the treatment fluid in a wellbore penetrating at least portion of a subterranean formation.