Laundry Dye Stability via Acidic Buffer Coating

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Solution Overview

Problem

Acid and direct dyes incorporated into laundry detergent are unstable in granular detergent compositions, leading to a short shelf life and instability even when segregated from the bulk detergent powder.

Innovation Solution

Incorporating an acidic component, such as a water-soluble acidic polymer, into the dye composition to enhance stability, which acts as a binder, coating, or co-granulant, providing a buffer capacity that maintains the dye's stability by requiring at least 10 ml of 0.01 M sodium hydroxide to bring the pH to 9 when dissolved in water.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If dyes are incorporated into laundry detergent at low levels to provide shading benefit, then the aesthetic performance is improved, but the stability of the dye deteriorates

Engineering Contradiction:
Improvedye stabilityVSAvoiddye composition stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

An acidic component is introduced as an intermediary substance between the dye and the basic detergent environment. This acidic component acts as a buffer that maintains pH control, preventing the basic conditions from degrading the dye while allowing the detergent to function. The acidic component mediates the interaction between the incompatible elements (dye and basic detergent) by creating a protective chemical environment.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The pH parameter of the detergent composition is deliberately modified by incorporating an acidic component. This parameter change creates a localized acidic or neutral environment around the dye molecules, protecting them from degradation by the overall basic detergent formulation. The buffer capacity ensures the pH remains within a stable range during storage.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If the product has a short shelf life, then small batches can be made and rapidly sold, but manufacturing efficiency deteriorates

Engineering Contradiction:
Improveproduct shelf lifeVSAvoidmanufacturing efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The acidic component provides beforehand cushioning by preemptively counteracting the degradation mechanisms that would otherwise limit shelf life. By incorporating this protective element into the formulation, the product is pre-buffered against pH-related dye degradation, allowing it to maintain stability throughout extended storage periods without requiring special handling or rapid turnover.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

3Quantity of substance

If dyes are segregated from the bulk detergent powder, then dye concentration is maintained, but stability deteriorates

Engineering Contradiction:
Improvedye concentrationVSAvoiddye stability
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The acidic component serves as a protective intermediary that surrounds and protects segregated dye particles. Even when the dye is physically separated from the bulk detergent matrix, each dye particle or small aggregate is associated with acidic components that create a protective microenvironment, preventing degradation while maintaining the concentration benefits of segregation.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The acidic component significantly improves the storage properties and stability of the dyes, extending the shelf life of the detergent and maintaining dye performance over time.

Implementation Method 1

buffer capacity wherein when 1.00 gm of the granules are dissolved in 50 ml of demineralised water to provide an acidic solution at least 10 ml of a 0.01 M solution of sodium hydroxide is required to bring the pH of the acidic solution to 9

Methodology Applied
Scientific EffectBuffer capacity:

Data Source

PatentEP1926809B2Composition of enhanced stability and a process for making such a composition
Publication Date: 2019.08.28 UNILEVER PLC
  • EP1926809B2 patent drawing
  • EP1926809B2 patent drawing
  • EP1926809B2 patent drawing

AI summary

The invention relates to a laundry detergent shading composition that has been coated with a polymer that serves to promote the stability of the dye.