Acidic Liquid Cleaning Compositions with Organic Acids

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Solution Overview

Problem

Conventional light duty liquid cleaning compositions often fail to provide effective antibacterial efficacy while maintaining low toxicity and ease of rinsing, and may leave residues on surfaces, making them unsuitable for delicate and food-contact surfaces.

Innovation Solution

The development of acidic liquid cleaning compositions that combine specific amounts of anionic surfactants, zwitterionic surfactants, and organic acids, such as lactic acid, which exhibit antibacterial activity with a log10 reduction of at least 3 in microbes within 30 seconds, while being stable for over a year at room temperature and having low toxicity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional light duty liquid cleaning compositions are used, then they provide basic cleaning ability, but they fail to provide effective antibacterial efficacy and may leave residues on surfaces

Engineering Contradiction:
Improveantibacterial efficacyVSAvoidresidue on surfaces
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent applies parameter changes by adjusting the pH of the cleaning composition to an acidic range (pH 2-4) and optimizing the concentration of surfactants and organic acids. This parameter modification enables the composition to achieve effective antibacterial efficacy while ensuring complete rinsing without residues on surfaces, resolving the contradiction between reliability and harmful factors.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite formulation combining anionic surfactants (1-20 wt%), zwitterionic surfactants (1-15 wt%), and organic acids (1-10 wt%) such as lactic acid, citric acid, or acetic acid. This composite material approach creates a synergistic effect that provides both antibacterial activity and ease of rinsing, eliminating residues while maintaining reliable antibacterial performance.

Inventive Principle:
Principle #40Composite materials

2Reliability

If acidic formulations are used to enhance antibacterial efficacy, then antibacterial activity improves, but toxicity may increase

Engineering Contradiction:
Improveantibacterial activityVSAvoidtoxicity
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent carefully controls the pH parameter within the range of 2-4 and limits organic acid content to 1-10 wt%, which maintains effective antibacterial activity while ensuring low toxicity. This parameter optimization allows the composition to be safe for use on food-contact surfaces and animate surfaces including human skin, resolving the contradiction between antibacterial reliability and toxicity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs readily biodegradable organic acids with short environmental persistence, such as lactic acid, citric acid, and acetic acid. These substances provide effective antibacterial action during use but rapidly degrade in the environment, minimizing toxic accumulation and allowing safe reuse on sensitive surfaces without long-term harmful effects.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Productivity

If strong cleaning agents are used to improve cleaning performance, then cleaning ability enhances, but ease of rinsing deteriorates

Engineering Contradiction:
Improvecleaning performanceVSAvoidease of rinsing
Core Design Contradiction:
ProductivityVSEase of operation

Solution Approach 1:

The patent optimizes the concentration parameters of surfactants (anionic 1-20 wt%, zwitterionic 1-15 wt%) and adjusts pH to 2-4, creating a formulation that delivers strong cleaning performance while maintaining excellent rinsability. The acidic pH and specific surfactant combination ensure complete removal from surfaces without requiring extensive rinsing, resolving the contradiction between productivity and ease of operation.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These compositions achieve enhanced cleaning performance, reduced residue left on surfaces, and are safe for use on delicate and food-contact surfaces, including human skin, with minimal rinsing required, demonstrating superior antibacterial efficacy and low toxicity.

Implementation Method 1

The cleaning compositions of the invention include a surfactant mix that includes anionic surfactants, zwitterionic surfactants, and amphoteric surfactants

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Implementation Method 2

enhanced cleaning performance, reduced residue left on surfaces

Methodology Applied
Scientific EffectEmulsification: Emulsion

Implementation Method 3

which exhibit antibacterial activity with a log10 reduction of at least 3 in microbes within 30 seconds

Methodology Applied
Scientific EffectAntibacterial activity:

Implementation Method 4

acidic liquid cleaning compositions with low toxicity and antibacterial efficacy on surfaces

Methodology Applied
Scientific EffectAcid action:

Data Source

PatentUS7718595B2Light duty liquid cleaning compositions and methods of manufacture and use thereof comprising organic acids
Publication Date: 2010.05.18 COLGATE PALMOLIVE CO

AI summary

The invention encompasses liquid cleaning compositions, for example, dish washing liquids, and methods of their manufacture and use, which possess enhanced cleaning ability. The cleaning compositions of the invention include acidic light duty liquid cleaning compositions with low toxicity and antibacterial efficacy on surfaces, for example, hard surfaces.