Acidic Surfactant Blend for Low-Foam CIP Cleaning

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Solution Overview

Problem

Alkaline cleaning compositions used in 'cleaning in place' (CIP) processes absorb carbon dioxide rapidly, leading to underpressure and potential implosion in systems, and existing solutions are high in foaming, which affects cleaning efficacy and requires time-consuming CO2 removal.

Innovation Solution

A CIP method using a concentrate comprising alkyl glycosides, nonionic alkylene oxide adducts, and an acid with a pH value of less than 2.0, which when diluted, has a pH of less than 6.5, providing a low-foaming solution effective for cleaning in carbon dioxide environments without requiring CO2 replacement.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If alkaline cleaning compositions are used for cleaning in place processes, then cleaning effectiveness is improved, but carbon dioxide absorption causes underpressure and potential implosion

Engineering Contradiction:
Improvecleaning effectivenessVSAvoidunderpressure and implosion risk
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the pH parameter from alkaline to acidic (pH < 2.0) to eliminate the harmful effect of carbon dioxide absorption while maintaining cleaning effectiveness through the synergistic combination of acidic protease and surfactants

Inventive Principle:
Principle #35Parameter changes

2Object-generated harmful factors

If foam depressors are added to control foaming, then foam reduction is achieved, but cleaning result is detrimentally affected

Engineering Contradiction:
Improvefoam formationVSAvoidcleaning result
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent changes the pH parameter to acidic conditions and selects specific surfactant types (nonionic and anionic surfactants with particular HLB values) to achieve low foaming inherently without adding foam depressors, thereby maintaining cleaning effectiveness

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite surfactant system combining nonionic surfactants (HLB 8-16) and anionic surfactants (HLB 10-20) with acidic protease to achieve both low foaming and effective cleaning without foam depressors

Inventive Principle:
Principle #40Composite materials

3Object-affected harmful factors

If CO2 removal is performed before cleaning, then implosion risk is eliminated, but cleaning time is extended

Engineering Contradiction:
Improveimplosion riskVSAvoidcleaning time
Core Design Contradiction:
Object-affected harmful factorsVSLoss of time

Solution Approach 1:

The patent changes the pH parameter to acidic conditions, which prevents carbon dioxide absorption in the first place, thereby eliminating the need for CO2 removal steps and reducing total cleaning time while maintaining safety

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution ensures effective and fast cleaning with minimal foam, allowing for secure cleaning of objects and equipment without pre-replacing CO2, and maintains beer foam stability, facilitating efficient rinsing and maintaining cleaning performance.

Implementation Method 1

If industrial systems have to be cleaned containing carbon dioxide the alkaline cleaning compositions tend to absorb the carbon dioxide very rapidly causing an underpressure in the closed system

Methodology Applied
Scientific EffectAcid-base reaction: Chemical Bonding

Implementation Method 2

a) an alkyl glycoside having the general formula I... b) a nonionic alkylene oxide adduct

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Data Source

PatentEP2059580B1Acidic composition based on a surfactant blend
Publication Date: 2012.02.22 ECOLAB INC

AI summary

The present invention refers to a concentrate for use in a cleaning and/or washing process comprising c) an alkyl glycoside having the general formula (I) R1OGn; whereby G is a saccharide residue and n is 1, 2, 3, 4 or 5 and R1 is an alkyl group or alkylene group having 1 to 20 carbon atoms, and d) a nonionic alkylene oxide adduct, wherein the concentrate has a pH value of less than 6,5, as well as to a solution obtained by diluting the concentrate and to a process of cleaning objects using the concentrate and/or solution.