Gas Analyzer Using Acoustic Refractive Index for Continuous Composition

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Solution Overview

Problem

Current gas analysis methods, such as gas chromatography, face challenges in accurately measuring hydrogen concentration when hydrogen is used as a carrier gas and suffer from increased measurement errors with inert gases, and are limited by batch processing, preventing continual measurements. Additionally, semiconductor-based instruments provide high accuracy but with slow response speeds.

Innovation Solution

A gas analysis method and analyzer that compute the concentration of methane, hydrogen, and carbon dioxide in a mixture gas using refractive index and sonic speed measurements, employing specific relational expressions to account for measurement errors and enable continuous monitoring with high accuracy.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If gas chromatography is used for gas composition analysis, then measurement accuracy can be maintained, but continual measurement cannot be performed due to batch processing limitations

Engineering Contradiction:
Improvemeasurement accuracyVSAvoidmeasurement speed
Core Design Contradiction:
Measurement precisionVSProductivity

Solution Approach 1:

The patent replaces the mechanical batch processing system of gas chromatography with an acoustic measurement system using ultrasonic speed of sound measurements. This substitution enables continuous real-time measurement while maintaining accuracy through mathematical calculation of gas composition based on acoustic properties, eliminating the batch processing limitation.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Measurement precision

If semiconductor sensors are used for hydrogen measurement, then measurement accuracy is high, but response speed becomes slow

Engineering Contradiction:
Improvemeasurement accuracyVSAvoidresponse speed
Core Design Contradiction:
Measurement precisionVSSpeed

Solution Approach 1:

The patent replaces the slow semiconductor sensor system with an acoustic measurement system that uses ultrasonic transducers. This mechanical-to-acoustic substitution provides rapid response times while maintaining measurement accuracy through calculation of gas composition from speed of sound measurements, overcoming the slow response limitation of semiconductor sensors.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Ease of operation

If inert gas such as helium or argon is used as carrier gas in gas chromatography, then measurement can be performed, but measurement error increases

Engineering Contradiction:
Improvemeasurement capabilityVSAvoidmeasurement error
Core Design Contradiction:
Ease of operationVSMeasurement precision

Solution Approach 1:

The patent extracts the carrier gas from the measurement system entirely by using acoustic measurements in the presence of the sample gas itself. This eliminates the need for inert carrier gases like helium or argon, thereby removing the source of measurement error while maintaining the ability to perform measurements.

Inventive Principle:
Principle #2Taking out (Extraction)

4Ease of operation

If hydrogen is used as carrier gas in gas chromatography, then measurement can be performed, but hydrogen concentration in the sample cannot be measured

Engineering Contradiction:
Improvemeasurement capabilityVSAvoidhydrogen concentration measurement
Core Design Contradiction:
Ease of operationVSMeasurement precision

Solution Approach 1:

The patent removes the carrier gas requirement from the measurement system by using direct acoustic measurements. This extraction of the carrier gas function allows hydrogen concentration in the sample to be accurately measured through speed of sound calculations without the interference that occurs when hydrogen is used as carrier gas in chromatography.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for high-accuracy, continuous detection of gas compositions with rapid response times, overcoming the limitations of existing methods by reliably measuring carbon dioxide and other components in mixture gases, particularly those produced through methanation reactions.

Implementation Method 1

a refractive index measurement unit (11) configured to measure a refractive index of the gas to be analyzed

Methodology Applied
Scientific EffectRefraction: Refraction

Implementation Method 2

a sonic speed measurement mechanism (15) configured to measure a sonic speed of the gas to be analyzed

Methodology Applied
Scientific EffectSpeed of sound: Speed of Sound

Data Source

PatentEP3454059B1Gas analysis method and gas analyzer
Publication Date: 2020.02.05 RIKEN KEIKI KK
  • EP3454059B1 patent drawingFigure 1~2
  • EP3454059B1 patent drawing
  • EP3454059B1 patent drawing

AI summary

Disclosed are a gas analysis method and a gas analyzer which enable, with high accuracy, continual analysis of compositions of a gas to be analyzed or a mixture gas predominantly composed of a methane gas and containing either one or both of a hydrogen gas and a carbon dioxide gas. On the basis of a refractive index equivalent output value and a sonic speed equivalent output value for a particular gas physical property of the gas to be analyzed, the concentration value of the carbon dioxide gas is computed by a particular relational expression. The concentration value of the methane gas and the concentration value of the hydrogen gas are computed on the basis of the value of the particular gas physical property; the value of the particular gas physical property of each component gas of the gas to be analyzed; and the volume fraction of each component gas.