Acridine Derivative Dopant for OLED Efficiency and Lifespan

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Solution Overview

Problem

Current organic electro-luminescence devices lack materials that enhance color purity, luminous efficiency, power efficiency, and heat resistance, and require high operating voltages with limited lifespan.

Innovation Solution

An acridine derivative compound with an aryl or heteroaryl moiety linked to an acridine and amine moiety is used in the organic material layers of the device, specifically in hole injection, hole transport, and light emitting layers, to improve performance and efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional organic materials are used in the organic material layer, then the device structure is simple, but the color purity, luminous efficiency, and power efficiency are insufficient

Engineering Contradiction:
Improvedevice structure simplicityVSAvoidcolor purity
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent uses a composite material system consisting of a host material and a dopant material in the light emitting layer. The host material (e.g., Alq3, BCP, or TPBi) provides structural framework and charge transport, while the dopant material (acridine derivative compounds with specific formulas) provides the desired color emission. This composite approach enables both structural simplicity and high color purity by separating the structural and functional roles of different materials.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If conventional organic materials are used, then the device is easy to manufacture, but the luminous efficiency and power efficiency are limited

Engineering Contradiction:
Improvemanufacturing easeVSAvoidluminous efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The patent optimizes key parameters including the dopant concentration (0.1-10 wt% in the light emitting layer), the molecular structure of acridine derivative compounds (with specific R1-R6 substituents), and the energy level alignment between host and dopant materials. These parameter optimizations enable high luminous efficiency (over 5 cd/A) and power efficiency while maintaining ease of manufacture through conventional vacuum deposition techniques.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If conventional materials are used in the organic material layer, then the device can be manufactured with standard materials, but the heat resistance and lifespan are reduced

Engineering Contradiction:
Improvematerial availabilityVSAvoiddevice lifespan
Core Design Contradiction:
Ease of manufactureVSDuration of action of stationary object

Solution Approach 1:

The patent employs small-molecule organic materials (host and dopant) that can be deposited as thin films through vacuum deposition. These materials, while simple to manufacture, are designed with specific molecular structures (acridine derivatives with aromatic substituents) that provide enhanced thermal stability and resistance to degradation, thereby extending device lifespan without compromising manufacturability.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

4Ease of manufacture

If conventional electron transport materials are used, then the device operates with standard materials, but the operating voltage remains high

Engineering Contradiction:
Improvematerial standardizationVSAvoidoperating voltage
Core Design Contradiction:
Ease of manufactureVSUse of energy by moving object

Solution Approach 1:

The patent introduces separate functional layers with specialized materials optimized for specific functions: hole injection layer (e.g., HIL), hole transport layer (e.g., NPB, TAPC), light emitting layer (host+dopant), electron transport layer (e.g., Alq3, TPBi), and electron injection layer (e.g., LiF, Cs). This local optimization of material properties in each layer enables low operating voltage by ensuring efficient charge injection and transport at each interface, while maintaining overall device simplicity.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The acridine derivative compound enhances luminance, power efficiency, and heat resistance, allowing for low operating voltage and extended lifespan of the organic electro-luminescence device while maximizing performance and color purity.

Implementation Method 1

When a voltage is applied between the two electrodes, holes from the anode and electrons from the cathode are injected into the organic material layer

Methodology Applied
Scientific EffectCharge transport: Conduction (electrical)

Implementation Method 2

An organic light emitting phenomenon indicates conversion of electric energy into light energy by means of an organic material

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 3

excitons which are generated in the host are transported to the dopant, thus emitting a light having a high efficiency

Methodology Applied
Scientific EffectEnergy transfer:

Data Source

PatentUS8597802B2Acridine derivative and organic electroluminescence device including the same
Publication Date: 2013.12.03 SOLUS ADVANCED MATERIALS CO LTD
  • US8597802B2 patent drawing
  • US8597802B2 patent drawing
  • US8597802B2 patent drawing

AI summary

Disclosed are an acridine derivative and an organic electro-luminescence device including the same. Specifically, the disclosed acridine derivative compound has an aryl moiety or a heteroaryl moiety, linked to an acridine moiety and an amine moiety, and the disclosed organic electro-luminescence device including the acridine derivative compound requires a low operating voltage, shows high efficiency, and is enhanced in life-span.