Acrylamide-Based Mesoporous Polymer for Hydrogen Storage

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Solution Overview

Problem

Conventional gas storage materials for hydrogen lack sufficient storage efficiency and stability, failing to effectively adsorb and desorb gas when needed.

Innovation Solution

A novel acrylamide-based polymer with a specific repeating unit structure, capable of forming mesoporous polymers through radical polymerization, which allows for high-efficiency gas storage and stable gas release due to its mesoporosity and crystallinity, is used as a gas storage material.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If conventional gas storage materials (zeolite, carbon nanotube, MOFs, metal hydrides) are used, then gas storage capacity is achieved, but storage efficiency is insufficient and stability is poor

Engineering Contradiction:
Improvegas storage capacityVSAvoidstorage stability
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The invention employs a porous polymer structure with controlled pore size and distribution to achieve both high gas storage capacity and stable adsorption-desorption behavior. The porous framework provides numerous adsorption sites while maintaining structural integrity for reliable cyclic operation.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The gas storage material utilizes a composite structure combining organic polymer components with functional groups that enhance both capacity and stability. The composite architecture integrates different molecular motifs to simultaneously optimize storage density and operational reliability.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If conventional gas storage materials are used, then some gas storage capacity is achieved, but gas release effectiveness is poor when needed

Engineering Contradiction:
Improvegas storage capacityVSAvoidgas release rate
Core Design Contradiction:
Quantity of substanceVSProductivity

Solution Approach 1:

The porous polymer structure incorporates dynamic adsorption sites that facilitate rapid gas uptake and release. The flexible pore architecture allows for efficient mass transport, enabling the material to respond quickly to pressure changes and deliver gas on demand.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The invention optimizes pore size, surface area, and functional group distribution to enhance gas diffusion kinetics. By adjusting structural parameters such as pore diameter and wall thickness, the material achieves both high storage capacity and fast release rates.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If mesoporous polymer structure is implemented, then gas storage efficiency is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvegas storage efficiencyVSAvoidpolymer structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The polymer is designed with repeating units containing specific functional groups (aromatic rings, alkyl chains, heteroatoms) that self-assemble into mesoporous structures. This modular approach simplifies synthesis while achieving complex porous architectures through controlled self-organization.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The polymer monomers are designed to self-assemble into mesoporous structures during polymerization, eliminating the need for complex post-synthesis processing. The molecular structure inherently directs the formation of pores through non-covalent interactions and phase separation.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The acrylamide-based polymer demonstrates superior gas storage efficiency, stably adsorbing and desorbing hydrogen, with storage capacities up to 0.05 to 5.0 wt% at various pressures and temperatures, and can be used in the form of electrospun fibers for enhanced surface area and efficiency.

Implementation Method 1

the gas storage material can stably adsorb and desorb gas

Methodology Applied
Scientific EffectPhysisorption: Physisorption

Implementation Method 2

the gas storage material can stably adsorb and desorb gas

Methodology Applied
Scientific EffectDesorption: Desorption

Data Source

PatentUS9051181B2Gas storage material and method for gas storage
Publication Date: 2015.06.09 LG CHEM LTD
  • US9051181B2 patent drawing
  • US9051181B2 patent drawing
  • US9051181B2 patent drawing

AI summary

The present invention relates to a gas storage material comprising a novel mesoporous polymer, that shows superior gas storage efficiency and can stably adsorb and desorb gas, and method for gas storage using thereof.The gas storage material comprises an acrylamide-based polymer.