Acrylate Rubber Adhesive Blend for Non-Polar Surfaces

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Solution Overview

Problem

Existing pressure-sensitive adhesives fail to achieve high adhesion and heat resistance on new, hard, non-polar surfaces such as those used in the automotive industry, particularly painted surfaces with high scratch and solvent resistance.

Innovation Solution

A blend of polyacrylate and synthetic rubber with specific resins, produced using a solvent process, which combines intrinsically incompatible components to create a pressure-sensitive adhesive with enhanced adhesion and cohesion on difficult-to-bond surfaces and improved heat resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If new types of paint with high cross-linking and low surface energy are used to achieve scratch and solvent resistance, then adhesion of conventional adhesives deteriorates

Engineering Contradiction:
Improvescratch resistanceVSAvoidadhesion
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies composite materials by creating a pressure-sensitive adhesive composed of multiple components: polyacrylate (providing heat resistance and cohesion), synthetic rubber (providing adhesion to non-polar surfaces), and resins (enhancing bonding properties). This composite formulation allows the adhesive to simultaneously achieve strong adhesion to low-surface-energy painted surfaces and maintain high heat resistance, resolving the contradiction between substrate strength and adhesive reliability

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent employs parameter changes by carefully controlling the glass transition temperature (Tg) of the polyacrylate component within a specific range (-50°C to +100°C) and optimizing the molecular weight and composition ratios of all adhesive components. These parameter optimizations enable the adhesive to maintain appropriate tackiness and bonding performance despite the low surface energy of modern painted substrates

Inventive Principle:
Principle #35Parameter changes

2Reliability

If polyacrylate and synthetic rubber are blended to improve adhesion on non-polar surfaces, then compatibility between components deteriorates

Engineering Contradiction:
Improveadhesion on non-polar surfacesVSAvoidcomponent compatibility
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent uses resins as intermediary substances that facilitate compatibility between the intrinsically incompatible polyacrylate and synthetic rubber components. The resins act as a mediating phase that enables proper mixing and distribution of the two polymers, ensuring homogeneous adhesive composition while maintaining the distinct functional contributions of each component

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent resolves compatibility issues by optimizing the molecular weight, glass transition temperature, and composition ratios of the polyacrylate and synthetic rubber components. By carefully controlling these parameters, the adhesive achieves proper phase distribution and compatibility between the blended polymers, enabling stable formulation with improved adhesion performance

Inventive Principle:
Principle #35Parameter changes

3Temperature

If conventional adhesive formulations are used to maintain heat resistance, then adhesion on painted surfaces deteriorates

Engineering Contradiction:
Improveheat resistanceVSAvoidadhesion on painted surfaces
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent applies composite materials by formulating a pressure-sensitive adhesive that combines polyacrylate (providing heat resistance through its thermal stability and controlled glass transition temperature), synthetic rubber (providing adhesion to painted surfaces), and resins (enhancing overall bonding). This composite structure allows the adhesive to simultaneously achieve strong adhesion to modern painted substrates and maintain high heat resistance, resolving the contradiction between substrate strength and adhesive reliability

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent employs parameter changes by optimizing the glass transition temperature of the polyacrylate component and the composition ratios of all adhesive components. These parameter optimizations enable the adhesive to maintain appropriate tackiness for bonding to low-surface-energy surfaces while preserving the heat resistance characteristics necessary for automotive applications

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The adhesive exhibits superior adhesion and heat resistance, outperforming previous adhesives by maintaining strong bonding and cohesion on hard, non-polar surfaces, including those with high scratch and solvent resistance, while also showing improved long-term stability.

Implementation Method 1

The adhesive exhibits superior adhesion and heat resistance, outperforming previous adhesives by maintaining strong bonding and cohesion on hard, non-polar surfaces

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

The adhesive exhibits superior adhesion and heat resistance, outperforming previous adhesives by maintaining strong bonding and cohesion on hard, non-polar surfaces

Methodology Applied
Scientific EffectCohesion: Cohesion

Implementation Method 3

A blend of polyacrylate and synthetic rubber with specific resins, produced using a solvent process, which combines intrinsically incompatible components

Methodology Applied
Scientific EffectSolvation: Solvation

Data Source

PatentEP2885364B1Adhesive agent having adhesive blend of acrylate and styrene block copolymer
Publication Date: 2019.04.10 LOHMANN GMBH & CO KG

AI summary

The present invention relates to a carrier-based bonding adhesive agent, which is equipped for bonding adhesion on one or both sides or a carrier-free bonding adhesive agent, in the form of an adhesive strip or stamped part having a bonding adhesive consisting substantially of a blend of polyacrylate and a synthetic rubber as well as one or more adhesive resins. By comparison with previously known adhesive systems such an adhesive exhibits a significant improvement in adhesion on hard, non-polar surfaces such as for example new paint surfaces in the automobile industry.