Acrylic Acid Catalyst Water Content Control

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Solution Overview

Problem

There is a lack of effective methods for storing catalysts used in producing acrylic acid, leading to potential performance failures due to inadequate storage conditions, particularly in newly constructed industrial reactors where catalysts may be stored for extended periods.

Innovation Solution

A catalyst comprising molybdenum and vanadium with a controlled water content range of 0.01 to 0.53 mass % is developed, along with a method for producing acrylic acid using this catalyst, ensuring maintained catalytic performance even after storage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the catalyst is stored for extended periods (1-10 years) in industrial reactors, then the catalyst may be needed for emergency spare use, but the catalytic performance may deteriorate due to inappropriate storage conditions and hygroscopicity

Engineering Contradiction:
Improvecatalytic performanceVSAvoidstorage period
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The invention controls the water content parameter of the catalyst within a specific range (0.01-5 mass%) to maintain catalytic performance during long-term storage. This parameter control prevents hygroscopicity-related deterioration while allowing extended storage periods for emergency spare use.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The catalyst is prepared with predetermined water content before storage to prevent performance deterioration. By establishing the appropriate water content level in advance (0.01-5 mass%), the catalyst is protected against hygroscopicity issues that would otherwise occur during long-term storage.

Inventive Principle:
Principle #10Preliminary action

2Ease of manufacture

If the catalyst is stored without controlled water content, then storage is simpler, but the catalyst fails to achieve desired performance after storage

Engineering Contradiction:
Improvestorage simplicityVSAvoidcatalytic performance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

By specifying a concrete water content range (0.01-5 mass%), the invention transforms the storage process from a simple empirical operation into a controlled process with defined parameters. This maintains catalytic performance while providing clear storage guidelines.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The catalyst maintains its performance equivalent to that at production completion, even after extended storage, by adjusting the water content within the specified range, preventing hygroscopicity-related issues and ensuring reliable spare use.

Implementation Method 1

the catalyst used for producing methacrylic acid from methacrolein, which is the similar reaction, is a chemical substance called a heteropoly acid, and the hygroscopicity thereof is widely known

Methodology Applied
Scientific EffectHygroscopicity: Absorption (physical)

Data Source

PatentUS10940464B2Catalyst for producing acrylic acid and method for producing acrylic acid
Publication Date: 2021.03.09 NIPPON KAYAKU CO LTD

AI summary

The present invention clarifies the characteristic of the hygroscopicity of the catalyst for producing acrylic acid and finds out a relationship between the water amount of the catalyst and the catalytic performance as the catalyst for producing acrylic acid, and provides an excellent catalyst. Provided is a catalyst for producing acrylic acid, which contains molybdenum and vanadium as essential active components, in which the amount of water contained in the catalyst is 0.01 mass % or more and 0.53 mass % or less.