Antistatic Acrylic Adhesive for Optical Components

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Solution Overview

Problem

Conventional antistatic pressure-sensitive adhesive sheets for protecting optical components face issues with static electricity generation during peeling, which can degrade the orientation of liquid crystals and increase the risk of staining due to bleeding of antistatic agents, and require improved removability and reduced distortion during peeling.

Innovation Solution

A pressure-sensitive adhesive composition comprising a (meth)acryl-based polymer with an alkyl group of 1 to 14 carbon atoms, an alkali metal salt, and an organopolysiloxane with a polyoxyalkylene side chain, where the total amount of the alkali metal salt and organopolysiloxane is between 0.15 to 4 parts by weight based on 100 parts of the polymer, enhancing ionic conduction and reducing bleeding and staining risks.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If a low-molecular-weight surfactant is added to a pressure-sensitive adhesive to suppress electrostatic build-up, then antistatic properties are improved, but the surfactant easily bleeds out to the surface causing staining of the protected material

Engineering Contradiction:
Improveelectrostatic build-upVSAvoidstaining
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The patent changes the molecular weight parameter of the surfactant from low-molecular-weight to high-molecular-weight (polymer-type), and adjusts the HLB value to 3-13. This parameter change reduces the bleeding tendency while maintaining antistatic properties, resolving the contradiction between electrostatic suppression and staining prevention

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite pressure-sensitive adhesive system combining polymer-type surfactant with specific adhesive polymers (acrylic, polyurethane, or silicone-based). This composite approach allows the surfactant to function antistatically while the polymer matrix prevents excessive bleeding, simultaneously achieving electrostatic control and staining prevention

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If an antistatic agent is added to a pressure-sensitive adhesive sheet to prevent static electricity, then electrostatic protection is improved, but the antistatic agent bleeds out during aging or high-temperature treatment causing partial lifting of the film

Engineering Contradiction:
Improvestatic electricityVSAvoidfilm adhesion
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent changes the surfactant from low-molecular-weight to polymer-type with high molecular weight and specific HLB value (3-13), which significantly reduces bleeding during aging and high-temperature treatment. This prevents the film lifting issue while maintaining antistatic protection

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces conventional low-molecular-weight surfactants with polymer-type surfactants that have superior thermal stability and reduced bleeding. This substitution eliminates the need for frequent reapplication or additional stabilizing measures, improving long-term reliability

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Object-affected harmful factors

If a pressure-sensitive adhesive sheet is used to protect optical components, then protection from scratching or staining is improved, but static electricity generated during peeling degrades liquid crystal orientation and produces defects

Engineering Contradiction:
Improvescratching or stainingVSAvoidstatic electricity during peeling
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The patent modifies the adhesive composition by incorporating polymer-type surfactant with HLB value 3-13, which provides antistatic properties. This reduces static electricity generation during peeling while maintaining the protective function against scratching and staining

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite pressure-sensitive adhesive system that integrates polymer-type surfactant with protective adhesive polymers. This composite material simultaneously provides mechanical protection and electrostatic control, preventing both physical damage and liquid crystal degradation during peeling

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively prevents static electrification during peeling, reduces the risk of staining, and ensures good removability of the pressure-sensitive adhesive sheet from optical components, maintaining the integrity of liquid crystal displays.

Implementation Method 1

enhancing ionic conduction and reducing bleeding and staining risks

Methodology Applied
Scientific EffectIonic conduction: Conduction (electrical)

Implementation Method 2

effectively prevents static electrification during peeling

Methodology Applied
Scientific EffectElectrostatic discharge prevention: Electrostatics

Data Source

PatentUS9328264B2Pressure-sensitive adhesive composition, pressure-sensitive adhesive layer, and pressure-sensitive adhesive sheet
Publication Date: 2016.05.03 NITTO DENKO CORP
  • US9328264B2 patent drawing
  • US9328264B2 patent drawing
  • US9328264B2 patent drawing

AI summary

Provided is a pressure-sensitive adhesive composition that makes it possible to prevent electrification of a non-antistatic protected material during peeling, is reduced in the risk of staining the protected material, and has good removability, and to provide a pressure-sensitive adhesive layer, a pressure-sensitive adhesive sheet. Specifically provided is a pressure-sensitive adhesive composition which comprises: a (meth)acryl-based polymer including, as a main component, a (meth)acryl-based monomer component having an alkyl group of 1 to 14 carbon atoms; an alkali metal salt; and an organopolysiloxane having a polyoxyalkylene side chain, wherein the (meth)acryl-based polymer has an acid value of 1.0 or less, and the total amount of the alkali metal salt and the organopolysiloxane is from 0.15 to 4 parts by weight, based on 100 parts by weight of the (meth)acryl-based polymer.