Alcohol-Stabilized Acrylic Acid Derivative Composition Against Polymerization

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Solution Overview

Problem

Acrylic acid derivatives are unstable against external stimuli such as heat, light, and oxygen, leading to easy polymerization into oligomers or polymers.

Innovation Solution

A composition comprising at least 90% (w/w) of a compound of formula (I) with R3 being C1-4-alkyl and C1-6-alcohol, which stabilizes the acrylic acid derivative by ensuring coexistence with alcohol, preventing polymerization.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If acrylic acid derivative is stored or processed under external stimuli (heat, light, oxygen), then polymerization reaction occurs easily forming oligomers or polymers, but the derivative loses its stability and becomes unusable

Engineering Contradiction:
Improvestability of acrylic acid derivativeVSAvoidpolymerization reaction under external stimuli
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent introduces a polymerization inhibitor as an intermediary substance that mediates between the acrylic acid derivative and external stimuli (heat, light, oxygen). The inhibitor preferentially reacts with free radicals generated by external stimuli, preventing them from initiating polymerization of the acrylic acid derivative. This allows the derivative to maintain stability during storage and processing without requiring complete isolation from environmental factors.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If polymerization inhibitor is added to stabilize acrylic acid derivative, then stability against polymerization is improved, but the composition becomes more complex with additional components

Engineering Contradiction:
Improvestability of acrylic acid derivativeVSAvoidcomplexity of composition
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent optimizes the concentration parameter of the polymerization inhibitor within a specific range (0.01-5 wt%, preferably 0.1-1 wt%) to achieve effective stabilization while minimizing composition complexity. By precisely controlling the inhibitor concentration, the patent finds an optimal balance where sufficient stability is provided without excessive amounts of additional components, thus maintaining relative simplicity of the overall composition.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition maintains the stability of acrylic acid derivatives under various conditions, preventing polymerization and maintaining the derivative in a stable form.

Implementation Method 1

the acrylic acid derivative is stabilized

Methodology Applied
Scientific EffectStabilization:

Implementation Method 2

preventing polymerization and maintaining the derivative in a stable form

Methodology Applied
Scientific EffectPreventing polymerization:

Data Source

PatentEP4053099B1Acrylic acid derivative-containing composition, and method for stabilizing acrylic acid derivative
Publication Date: 2026.01.28 DAIKIN INDUSTRIES LTD
  • EP4053099B1 patent drawing
  • EP4053099B1 patent drawing
  • EP4053099B1 patent drawing

AI summary

An object of the present invention is to provide a method for stabilizing an acrylic acid derivative, and a composition containing an acrylic acid derivative in which the acrylic acid derivative is stabilized. The present invention provides a composition comprising: (A) an acrylic acid derivative represented by Formula (I) : (wherein R1 and R2 are the same or different, and each represents alkyl, fluoroalkyl, aryl that may have one or more substituents, halogen, or hydrogen; R3 represents alkyl, fluoroalkyl, aryl that may have one or more substituents, or hydrogen; and X represents fluoroalkyl, alkyl, halogen, or hydrogen); and (B) alcohol, wherein the content of acrylic acid derivative (A) is 30%(w/w) or more.