Acrylic Paint-Protective Coating for Removable, Non-Marking Protection

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Solution Overview

Problem

Existing paint-protective coatings face challenges in efficiently protecting non-flat objects with complex shapes, as they either suffer from improper application leading to peeling or lack sufficient removability and non-marking properties when applied as liquid compositions.

Innovation Solution

A paint-protective coating material formed from a liquid coating composition, comprising a polymerization product of acrylic monomers, with specific storage moduli and glass transition temperatures, ensuring good removability and non-marking properties across a broad temperature range.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a paint-protective sheet is applied to protect paint layers, then protection is provided, but improper application leads to wrinkles and peeling

Engineering Contradiction:
Improveprotection effectivenessVSAvoidapplication difficulty
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent uses a liquid coating composition that is applied and dried to form a protective coating, eliminating the need for mechanical sheet application. This liquid application method avoids wrinkles and peeling issues associated with sheet-based protection, especially on complex three-dimensional shapes.

Inventive Principle:
Principle #29Pneumatics and hydraulics

Solution Approach 2:

The patent specifies precise storage modulus parameters at different temperatures (G′(70) = 0.40-1.30 MPa, G′(23) = 250-800 MPa, G′(−30) ≤ 2300 MPa) to ensure the coating material has appropriate flexibility and adhesion across varying temperatures, preventing peeling while maintaining protection.

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If a liquid protective coating composition is applied directly to the paint layer, then the protective coat is free of substrate and can be removed, but it lacks sufficient removability and causes marking

Engineering Contradiction:
ImproveremovabilityVSAvoidmarking on paint layer
Core Design Contradiction:
Ease of operationVSObject-generated harmful factors

Solution Approach 1:

The patent carefully controls the storage modulus parameters to create a coating that is soft enough to remove without marking (G′(70) ≤ 1.30 MPa) but maintains sufficient structural integrity during application and protection (G′(23) ≥ 250 MPa). This parameter optimization resolves the contradiction between removability and non-marking properties.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The coating uses a copolymer composed of multiple monomer units (acrylic monomer, carboxylic acid monomer, hydroxyl group-containing monomer, and amine group-containing monomer) to achieve balanced properties: adhesion to paint layer, flexibility for removal, and protection functionality, eliminating the need for substrate support.

Inventive Principle:
Principle #40Composite materials

3Ease of operation

If the protective coating is made softer to improve removability, then removal becomes easier, but protection effectiveness decreases

Engineering Contradiction:
Improveremoval easeVSAvoidprotection strength
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The patent specifies storage modulus at different temperatures to achieve temperature-dependent behavior: the coating is softer at high temperatures (G′(70) ≤ 1.30 MPa) for easy removal, but maintains sufficient strength at room temperature (G′(23) ≥ 250 MPa) for effective protection, resolving the contradiction between removability and protection strength.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating material provides balanced removability and non-marking properties, effectively protecting paint layers on complex-shaped objects without leaving traces, even at varying temperatures.

Implementation Method 1

The paint-protective coating material has a storage modulus at 70° C. of 0.40 MPa or higher and 1.30 MPa or lower, has a storage modulus at 23° C. of 250 MPa or higher and 800 MPa or lower, and preferably has a storage modulus at −30° C. of 2300 MPa or less

Methodology Applied
Scientific EffectViscoelasticity: Viscoelasticity

Data Source

PatentUS12384933B2Paint-protective coating material and coating composition
Publication Date: 2025.08.12 NITTO DENKO CORP
  • US12384933B2 patent drawing
  • US12384933B2 patent drawing

AI summary

Provided is a paint-protective coating material formed from a liquid coating composition. The coating composition comprises, as its base polymer, a polymer (A) that is a polymerization product of monomers comprising an acrylic monomer. The paint-protective coating material has a storage modulus at 70° C. of 0.40 MPa or higher and 1.30 or lower, a storage modulus at 23° C. of 250 MPa or higher and 800 MPa or lower, and a storage modulus at −30° C. of 2300 MPa or less.