Acrylic Fine Particles Cross-linking Agent Functional Groups

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Solution Overview

Problem

Acrylic fine particles with high cross-linking density exhibit poor compatibility with polar solvents, leading to agglomeration and non-uniform dispersion, which affects the quality of diffusing films and coatings.

Innovation Solution

The development of acrylic fine particles through polymerization of a monomer with a cross-linking agent containing (meth)acrylate and a first cross-linking agent with multiple (meth)acryloyloxy groups and functional groups like —OH or —COOH, which improves compatibility with solvents and binders, maintaining high cross-linking and dispersibility.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If acrylic fine particles have high cross-linking density, then solvent resistance is improved, but compatibility with polar solvents deteriorates causing agglomeration

Engineering Contradiction:
Improvesolvent resistanceVSAvoidcompatibility with polar solvents
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent applies local quality by introducing functional groups (—OH, —COOH) at specific locations on the cross-linking agent molecules. These functional groups are positioned to interact with polar solvents and binder resins, while the (meth)acryloyloxy groups maintain cross-linking density. This localized functional differentiation allows the particles to exhibit both high solvent resistance and improved compatibility with polar solvents, preventing agglomeration while maintaining structural integrity.

Inventive Principle:
Principle #3Local quality

2Strength

If acrylic fine particles use cross-linking agents with multi-functional groups, then cross-linking density increases, but dispersibility in coating solutions decreases

Engineering Contradiction:
Improvecross-linking densityVSAvoiddispersibility
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The patent changes the chemical parameters of the cross-linking agent by incorporating functional groups (—OH, —COOH) that can form hydrogen bonds and interact with polar solvents. This parameter modification allows the particles to maintain high cross-linking density through (meth)acryloyloxy groups while the functional groups improve wettability and dispersibility in coating solutions by reducing interfacial tension and enhancing compatibility with the liquid medium.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If acrylic fine particles are synthesized for high solvent resistance, then chemical resistance improves, but uniform dispersion in coating solutions becomes difficult

Engineering Contradiction:
Improvechemical resistanceVSAvoiduniform dispersion
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent creates a composite structure at the molecular level by combining (meth)acryloyloxy groups for cross-linking with functional groups (—OH, —COOH) for solvent interaction. This composite approach allows the acrylic fine particles to simultaneously achieve high chemical resistance through dense cross-linking and uniform dispersion through improved solvent compatibility, as the functional groups act as interfaces that mediate between the hydrophobic polymer matrix and polar coating solutions.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting acrylic fine particles demonstrate excellent solvent resistance, heat resistance, and dispersibility, enhancing the optical performance and efficiency of diffusing films.

Implementation Method 1

acrylic fine particles are formed by polymerization of a monomer with a cross-linking agent

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Data Source

PatentUS8785577B2Acrylic fine particles and diffusing film including the same
Publication Date: 2014.07.22 LOTTE ADVANCED MATERIALS CO LTD
  • US8785577B2 patent drawing
  • US8785577B2 patent drawing
  • US8785577B2 patent drawing

AI summary

Acrylic fine particles formed by polymerization of a (meth)acrylate containing monomer with a cross-linking agent are disclosed. The cross-linking agent includes a first cross-linking agent having at least three (meth)acryloyloxy groups and at least one functional group —OH, —COOH, or a combination thereof, and the acrylic fine particles can have a coefficient of variation (C.V.) of about 20 to about 60%. The acrylic fine particles can have high heat resistance and solvent resistance and also enhanced compatibility with a binder and a solvent. Accordingly, the acrylic fine particles can exhibit remarkably increased dispersibility when used in a diffusing film or the like, and thus are suitable for use as a diffusing agent.