Acrylic Polyester Resin Coating for Environmental and Durability Trade-offs

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Solution Overview

Problem

Traditional coating compositions using volatile solvents face environmental concerns and often result in coatings with poor adhesion, longevity, and durability, especially when transitioning to aqueous or powder forms for polyester materials.

Innovation Solution

A coating composition derived from an acrylic polyester resin, formed by grafting an acrylic polymer onto a polyester material polymerized with a polyacid and polyol component, including 2,2,4,4-tetraalkylcyclobutane-1,3-diol, and a crosslinking material, which improves hydrolytic stability and resistance properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If traditional volatile solvent carriers are used for polyester coatings, then application and drying are simplified, but environmental impact increases and coating performance deteriorates

Engineering Contradiction:
Improvecoating application simplicityVSAvoidenvironmental impact
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The invention changes the solvent parameter from volatile organic solvents to water-based aqueous carriers, eliminating harmful volatile emissions while maintaining coating applicability. The polyester resin is specifically formulated with hydrophilic groups and controlled molecular weight to ensure solubility and proper rheology in water-based systems.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite material systems including polyester resins combined with acrylic modifiers, silane crosslinkers, and water-based carriers. This composite approach enables the coating to achieve both environmental compatibility and adequate adhesion performance that neither component could provide alone.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If polyester materials are used in aqueous compositions, then environmental impact is reduced, but solubility and coating performance become inadequate

Engineering Contradiction:
Improveenvironmental impactVSAvoidcoating adhesion and durability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The polyester resin parameters are specifically modified including molecular weight control (1,000-10,000 g/mol), incorporation of hydrophilic groups (carboxyl, hydroxyl), and balanced hydrophobic-hydrophilic ratio to achieve solubility in water while maintaining film integrity and adhesion properties.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The coating formulation uses composite systems with polyester-resin-acrylic modifiers-silane crosslinkers in water. The acrylic modifiers improve water compatibility and flexibility, while silane crosslinkers provide durability and adhesion, creating a composite material that overcomes the limitations of pure polyester in aqueous systems.

Inventive Principle:
Principle #40Composite materials

3Object-affected harmful factors

If polyester coatings are applied in water-based systems, then environmental safety improves, but coating rheology and in-use properties deteriorate

Engineering Contradiction:
Improveenvironmental safetyVSAvoidcoating rheology and application properties
Core Design Contradiction:
Object-affected harmful factorsVSEase of operation

Solution Approach 1:

The resin parameters including molecular weight, functional group content, and viscosity are optimized to achieve proper coating rheology. The polyester resin is formulated with controlled molecular weight (1,000-10,000 g/mol) and balanced functionality to provide adequate flow, leveling, and adhesion in water-based applications without sagging or poor film formation.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enhances the longevity and resistance of the coatings, achieving improved adhesion and durability while reducing environmental impact by using a solvent-free or low-volatile solvent system.

Implementation Method 1

an acrylic polyester resin, obtainable by grafting an acrylic polymer with a polyester material

Methodology Applied
Scientific EffectGrafting: Chemical Bonding

Implementation Method 2

the polyester material being obtainable by polymerizing: i) a polyacid component, with ii) a polyol component

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Implementation Method 3

the coating composition comprising: (a) an acrylic polyester resin... (b) a crosslinking material

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Data Source

PatentUS12104073B2Product coated with an aqueous or powder coating composition comprising an acrylic polyester resin
Publication Date: 2024.10.01 PPG INDUSTRIES OHIO INC
  • US12104073B2 patent drawing
  • US12104073B2 patent drawing
  • US12104073B2 patent drawing

AI summary

There is disclosed a product coated on at least a portion thereof with a coating. The product may be an automotive product, a household or office appliance, furniture item or tool, a powered industrial product, a consumer electronics article, an architectural product or a product protected by an intumescent coating. The coating may be derived from an aqueous coating composition or a powder coating composition and may comprise an acrylic polyester resin, obtainable by grafting an acrylic polymer with a polyester material, the polyester material being obtainable by polymerizing a polyacid component, with a polyol component including a 2,2,4,4-tetraalkylcyclobutane-1,3-diol. Also disclosed are methods of application, and uses.