Liquid Acrylic Syrup Viscosity Control for Fiber Impregnation

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Solution Overview

Problem

Existing viscous liquid (meth)acrylic syrups for composite materials face challenges such as high viscosity, incomplete impregnation of fibrous substrates, and premature polymerization, leading to defects and reduced mechanical strength in composite parts, particularly when used in industrial processes like RTM and infusion.

Innovation Solution

A stable, low-viscosity (meth)acrylic syrup comprising a (meth)acrylic polymer, monomer, and a liquid initiator combined with a vanadium salt and tertiary amine accelerating system, allowing for homogeneous mixing and rapid polymerization at room temperature without heating, compatible with existing injection machines and industrial processes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If a viscous liquid (meth)acrylic syrup is used for impregnating fibrous substrates, then the syrup should have high viscosity to maintain structure, but high viscosity prevents complete impregnation of fibers

Engineering Contradiction:
Improvesyrup stabilityVSAvoidimpregnation quality
Core Design Contradiction:
Stability of the object's compositionVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by modifying the viscosity of the (meth)acrylic syrup through specific formulation adjustments. The syrup viscosity is controlled to fall within the range of 10 to 10,000 mPa·s at 25°C, which is lower than conventional viscous syrups. This viscosity reduction enables complete and correct impregnation of fibrous substrates while maintaining syrup stability, thereby resolving the contradiction between structural stability and impregnation quality.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If the syrup is made less viscous to improve impregnation, then fiber wetting improves, but the syrup becomes too fluid causing polymer drops to form on fibers

Engineering Contradiction:
Improveimpregnation qualityVSAvoidsyrup stability
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The patent optimizes the syrup viscosity parameter to a specific range (10 to 10,000 mPa·s at 25°C) that balances two opposing requirements: low enough viscosity to ensure complete fiber impregnation without naked zones, and high enough viscosity to prevent excessive fluidity that would cause polymer drops to form on fibers. This precise parameter control resolves the contradiction between impregnation quality and syrup stability.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If polymerization is initiated quickly to reduce production time, then productivity increases, but premature polymerization causes defects and reduces mechanical strength

Engineering Contradiction:
Improvepolymerization speedVSAvoidcomposite material quality
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies preliminary action by incorporating a stabilizer into the (meth)acrylic syrup formulation that prevents premature polymerization during storage and handling. This allows the syrup to be prepared and stored in advance without initiating polymerization, ensuring it remains stable and ready for use. When needed, the syrup can be rapidly polymerized under controlled conditions to achieve complete fiber impregnation within 20 minutes, thus resolving the contradiction between productivity and reliability.

Inventive Principle:
Principle #10Preliminary action

4Productivity

If heating is applied to accelerate polymerization, then reaction speed increases, but energy consumption increases and process complexity increases

Engineering Contradiction:
Improvepolymerization speedVSAvoidenergy consumption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent replaces the thermal field (heating) with a chemical field approach by using a carefully selected initiator system that enables rapid polymerization at room temperature. The syrup contains an initiator and accelerator combination that triggers fast polymerization without requiring external heating, thereby achieving complete polymerization within 20 minutes while significantly reducing energy consumption and process complexity. This substitution resolves the contradiction between polymerization speed and energy use.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables complete and correct impregnation of fibrous substrates, achieving rapid polymerization within 20 minutes, maintaining mechanical properties like high stiffness and Young's modulus, and avoiding the use of toxic cobalt salts, thus producing composite parts with improved mechanical performance.

Implementation Method 1

an initiator to start the polymerization of the (meth)acrylic monomer, said initiator being in the form of a peroxide compound that is liquid in a temperature range of between 0° and 50° C.

Methodology Applied
Scientific EffectPolymerization:

Implementation Method 2

the initiator is combined with an accelerating system comprising: a vanadium salt and a tertiary amine

Methodology Applied
Scientific EffectChemical acceleration: Catalysis

Data Source

PatentUS11186723B2Liquid (meth)acrylic syrup, method for impregnating a fibrous substrate with said syrup, and composite material produced after polymerisation of said impregnation syrup
Publication Date: 2021.11.30 ARKEMA FRANCE SA

AI summary

The invention relates to a viscous liquid (meth)acrylic syrup comprising:a) a (meth)acrylic polymer,b) a (meth)acrylic monomer,c) an initiator to start the polymerization of the (meth)acrylic monomer, said initiator being in the form of a peroxide compound that is liquid in a temperature range of between 0° and 50° C.,said syrup being characterized in that the initiator is combined with an accelerating system comprising:d) a vanadium salt ande) a tertiary amine.