Activatable SEL Sensor Stage with Diffusion Barrier

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Solution Overview

Problem

Current surface-enhanced luminescence (SEL) techniques face challenges in cost reduction and customization of sensitivity due to oxidation issues with cation metal-based materials, such as silver, which affect the performance and longevity of SEL stages.

Innovation Solution

The use of cation metal-based materials, specifically silver, is inhibited from oxidation by a diffusion barrier and capping layer until activation, allowing selective activation of isolated masses to enhance sensitivity, reducing costs and improving performance through controlled diffusion and oxidation prevention.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If cation metal-based materials (silver) are used to enhance sensing sensitivity, then sensing performance is improved, but oxidation occurs leading to reduced reliability and longevity

Engineering Contradiction:
Improvesensing sensitivityVSAvoidperformance stability
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

A diffusion barrier layer is introduced as an intermediary between the silver-based material and the external environment. This barrier layer prevents oxygen from reaching the silver, thereby preventing oxidation while allowing the silver to maintain its SERS-enhancing properties when activated.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The diffusion barrier is applied to the silver-based material before the material is activated. This preliminary protective action prevents oxidation from occurring in the first place, preserving the material's integrity until it is ready for use.

Inventive Principle:
Principle #10Preliminary action

2Reliability

If diffusion barrier and capping layer are applied to prevent oxidation, then reliability is improved, but device complexity increases

Engineering Contradiction:
Improveoxidation preventionVSAvoidlayer structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The diffusion barrier is implemented as a thin film layer that conformally coats the silver-based material. This thin film approach provides effective oxidation protection while minimizing the addition of bulk complexity to the device structure.

Inventive Principle:
Principle #30Flexible shells and thin films

3Adaptability or versatility

If selective activation of isolated masses is implemented, then customization of sensitivity is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvesensitivity customizationVSAvoidactivation process complexity
Core Design Contradiction:
Adaptability or versatilityVSEase of manufacture

Solution Approach 1:

The silver-based material is divided into multiple isolated masses or regions, each surrounded by its own diffusion barrier. This segmentation allows individual regions to be selectively activated or deactivated, enabling customization of sensing sensitivity for different application requirements.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces the cost of SEL stages, enhances sensitivity by preventing premature oxidation, and allows for customized performance by selectively activating silver-based materials, leading to improved radiation scattering and reflection in SEL applications.

Implementation Method 1

The use of cation metal-based materials, specifically silver, is inhibited from oxidation by a diffusion barrier and capping layer until activation

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Implementation Method 2

Surface enhanced luminescence (SEL) techniques, such as surface-enhanced Raman spectroscopy (SERS), utilize a surface, substrate or stage that enhances sensing sensitivity

Methodology Applied
Scientific EffectSurface enhanced luminescence:

Implementation Method 3

surface-enhanced Raman spectroscopy (SERS)

Methodology Applied
Scientific EffectRaman spectroscopy:

Data Source

PatentEP3446107B1Activatable surface enhanced raman spectroscopy sensor stage
Publication Date: 2021.03.31 HEWLETT PACKARD DEVELOPMENT COMPANY LP
  • EP3446107B1 patent drawingFigure 1~4
  • EP3446107B1 patent drawingFigure 5~8
  • EP3446107B1 patent drawingFigure 9~11

AI summary

An activatable SEL sensor stage may include a substrate, cation metal-based material masses supported by the substrate and isolated from one another and dielectric capping layer over the cation metal-based material masses to inhibit oxidation of the cation metal-based material masses.