Active Intelligent Additives for Food Packaging

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Solution Overview

Problem

Existing antimicrobial and indicator technologies for polymers require multiple steps and are costly due to sensitivity to temperature and mechanical processing, and potential toxicity issues with silver compounds, limiting their application in food packaging and other environments.

Innovation Solution

Development of active and intelligent additives with a sensitive compound encapsulated in an inorganic matrix, providing thermal and mechanical stability, capable of releasing electrons and/or photons in the presence of chemical compounds, allowing for easy incorporation into polymeric matrices and providing antimicrobial and analytical functions without direct contact with microorganisms.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If chitosan is applied to polymeric film by plasma activation, then antimicrobial activity is achieved, but processing complexity and cost increase due to multiple steps

Engineering Contradiction:
Improveantimicrobial activityVSAvoidprocessing steps
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines the antimicrobial chitosan layer and the polymeric film into a single integrated structure, where chitosan is incorporated directly into the film matrix during fabrication rather than applied as a separate post-processing step. This merging of functions reduces processing complexity while maintaining antimicrobial activity.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The chitosan is incorporated into the polymeric film during the film fabrication process itself, before the final product is completed. This preliminary incorporation eliminates the need for subsequent plasma activation or coating steps, simplifying the overall processing while ensuring uniform distribution and stable antimicrobial properties.

Inventive Principle:
Principle #10Preliminary action

2Reliability

If silver sulfate is used for antimicrobial activity, then microbial growth is inhibited, but toxicity concerns arise limiting food packaging applications

Engineering Contradiction:
Improveantimicrobial activityVSAvoidtoxicity
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent employs chitosan, a biodegradable and non-toxic natural polymer, as a alternative to persistent silver compounds. Chitosan provides effective antimicrobial activity while being safe for food contact applications, eliminating the toxicity concerns associated with silver sulfate without requiring complex disposal or safety protocols.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent changes the chemical nature of the antimicrobial agent from metallic silver compounds to organic chitosan derivatives. This parameter change in the chemical composition maintains the antimicrobial function while fundamentally altering the safety profile to be non-toxic and biocompatible, enabling food packaging applications.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If multiple processing steps are used for additive application, then functional properties are achieved, but manufacturing cost and time increase

Engineering Contradiction:
Improvefunctional propertiesVSAvoidmanufacturing efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent merges the additive incorporation and film fabrication processes into a single integrated operation. The active compounds are mixed with the polymeric matrix during extrusion or casting, eliminating separate coating, deposition, or activation steps. This consolidation maintains all necessary functional properties while significantly improving manufacturing efficiency and reducing production time.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The active compounds are incorporated into the polymeric matrix during the initial film fabrication process, before the product is completed. This preliminary action ensures uniform distribution of functional additives throughout the material, achieving the desired properties in a single processing pass without requiring subsequent treatment steps, thereby maximizing productivity.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The additives effectively inhibit microbial growth and indicate analyte presence through color change and electrical property modifications, extending the shelf life of perishable foodstuffs and ensuring food quality without additional processing steps and toxicity concerns.

Implementation Method 1

capable of releasing electrons and/or photons in the presence of chemical compounds, specifically amino compounds, amide compounds, oxygen reducing compounds, water or vapors thereof

Methodology Applied
Scientific EffectElectron release: Redox Reactions

Implementation Method 2

capable of releasing electrons and/or photons in the presence of chemical compounds

Methodology Applied
Scientific EffectPhoton release: Chemiluminescence

Implementation Method 3

indicate the presence of analytes (by way of color change and/or quantification of the electrons having been generated)

Methodology Applied
Scientific EffectColor change: Photochromism

Data Source

PatentUS10144817B2Active and intelligent additive, polymer and article
Publication Date: 2018.12.04 BRASKEM SA
  • US10144817B2 patent drawing
  • US10144817B2 patent drawing
  • US10144817B2 patent drawing

AI summary

The present invention relates to active and intelligent additives having hybrid characteristics, that are compatible with polymers, are thermally and mechanically stable, are capable of releasing electrons and/or photons in the presence of chemical compounds, specifically amino compounds, amide compounds, oxygen reducing compounds, water or vapors thereof. The active and intelligent additives incorporate themselves into polymer matrices allowing the obtainment of active and intelligent polymeric articles. These active and intelligent polymeric articles may act as inhibitors of growth of microorganisms and fungi, as well as indicators of the presence of gasses, either in the atmosphere or caused by the decomposition of foodstuffs, for example.