Active Material Oxygen Compounds Power Generator

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Solution Overview

Problem

Thermoelectric and thermionic power generators face low conversion efficiency and require a temperature gradient, as well as a relatively constant thermal source for effective operation.

Innovation Solution

An active material comprising oxygen-containing compounds like MgO, ZnO, and ZrO2, combined with thickener additives such as agar agar and methylcellulose, and plasticizer additives like silicone, which can generate current between electrodes without initial charging and is sensitive to temperature, allowing for thermal energy conversion into electric energy even at isothermal conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If thermoelectric or thermionic power generators are used to convert thermal energy into electrical energy, then power generation is achieved, but conversion efficiency is low and a temperature gradient is required

Engineering Contradiction:
Improveconversion efficiencyVSAvoidtemperature gradient requirement
Core Design Contradiction:
Loss of energyVSTemperature

Solution Approach 1:

The patent changes the physical-chemical parameters of the active material by using oxygen-containing compounds with specific particle sizes (10 nm to 40 μm) and combining them with thickener and plasticizer additives. This creates a material that can generate current through ionic conduction without requiring a temperature gradient, thereby improving conversion efficiency and eliminating the temperature constraint

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite active material consisting of oxygen-containing compounds (such as MgO, ZnO, ZrO2) combined with thickener additives (agar agar, xanthan gum, methylcellulose) and plasticizer additives. This composite structure enables ionic conduction and current generation without requiring a temperature gradient, resolving the contradiction between power generation capability and temperature gradient requirement

Inventive Principle:
Principle #40Composite materials

2Loss of energy

If thermoelectric or thermionic power generators are used, then thermal energy conversion to electrical energy is achieved, but a relatively constant thermal source is required

Engineering Contradiction:
Improveenergy conversion capabilityVSAvoidthermal source flexibility
Core Design Contradiction:
Loss of energyVSAdaptability or versatility

Solution Approach 1:

The patent changes the operating principle from electron/thermionic conduction to ionic conduction by selecting appropriate oxygen-containing compounds. This allows the device to function with variable thermal sources without requiring a constant temperature gradient, thereby improving adaptability to different thermal source conditions while maintaining energy conversion capability

Inventive Principle:
Principle #35Parameter changes

3Temperature

If traditional thermoelectric materials are used, then a temperature gradient is maintained, but current generation is limited

Engineering Contradiction:
Improvetemperature gradientVSAvoidcurrent generation
Core Design Contradiction:
TemperatureVSPower

Solution Approach 1:

The patent changes the conduction mechanism from electronic to ionic by using oxygen-containing compounds with specific particle size ranges. This enables significantly higher current generation (6-10 times increase) without relying on temperature gradient maintenance, thereby resolving the contradiction between temperature gradient requirement and current generation capability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The composite active material combining oxygen-containing compounds with specific particle sizes and organic additives creates a system that supports high ionic conductivity. This enables superior current generation performance without the limitations of traditional thermoelectric materials that require temperature gradients

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The active material significantly increases current generation by a factor of 6-10 when temperature is raised from 20 to 80°C, overcoming the limitations of traditional power generators by eliminating the need for a temperature gradient and improving energy conversion efficiency.

Implementation Method 1

capable to be applied on one electrode and to generate current when comprised between at least two electrodes without initial charging and dependently on the temperature

Methodology Applied
Scientific EffectThermal energy conversion:

Implementation Method 2

The active material significantly increases current generation by a factor of 6-10 when temperature is raised from 20 to 80°C

Methodology Applied
Scientific EffectTemperature-dependent current generation:

Data Source

PatentUS11393968B2Active material and electric power generator containing it
Publication Date: 2022.07.19 TERMO IND SA
  • US11393968B2 patent drawing
  • US11393968B2 patent drawing
  • US11393968B2 patent drawing

AI summary

The invention relates to an active material comprising at least one oxygen containing compound selected from the group consisting of MgO, ZnO, ZrOCl2, ZrO2, SiO2, Bi2O3, Al2O3 and TiO2, at least one thickener additive selected from the group consisting of agar agar, xanthan gum, methylcellulose, and arabic gum, and at least one plasticizer additive, wherein the particle size of the at least one oxygen-based compound has an average diameter in the range from 10 nm to 40 μm. The invention concerns also an electric power generator (EPG) comprising at least a first electrode (11) and a second electrode (12), wherein the electric power generator comprises the active material between said electrodes (11,12).