Active Resin Composition for Void-Free BGA Underfilling

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Solution Overview

Problem

The challenge in surface mounting of BGA parts is the difficulty in removing flux residue, which leads to corrosion and voids in the under-filling resin, especially with large-scale BGA devices, resulting in reduced product quality and yield due to incomplete filling and thermal decomposition issues.

Innovation Solution

An active resin composition comprising epoxy resin, blocked carboxylic acid compounds, and a curing agent that initiates curing at high temperatures, allowing for fluxless mounting and vacuum treatment to prevent voids and corrosion, facilitating reliable bonding and enhanced thermal stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional flux is used for surface mounting, then soldering quality is improved, but flux residue causes corrosion and requires additional washing steps

Engineering Contradiction:
Improvesoldering qualityVSAvoidproduction efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The invention extracts and eliminates the flux component from the surface mounting process by using an underfill resin with built-in activating agents that perform both bonding and protective functions, thereby removing the source of flux residue and corrosion problems

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The underfill resin is designed to perform multiple functions simultaneously: it acts as a bonding agent, provides corrosion protection through its activating agents, and eliminates the need for separate flux application and washing steps, thereby improving both reliability and productivity

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Productivity

If wash-less flux is used to eliminate washing steps, then productivity is improved, but decomposition gas damages BGA parts

Engineering Contradiction:
Improveproduction efficiencyVSAvoidBGA part integrity
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The invention changes the chemical parameters of the underfill resin by incorporating specific activating agents (carboxylic acid compounds) that prevent decomposition gas generation while maintaining the wash-less process benefits, thereby protecting BGA parts from damage

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention converts the potential harmful effect of thermal curing into a beneficial process by using the curing heat to activate the underfill resin's bonding and protective functions without generating decomposition gas that would damage BGA parts

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Reliability

If large-scale BGA parts are mounted, then device performance is enhanced, but flux residue removal becomes difficult causing corrosion

Engineering Contradiction:
Improvedevice performanceVSAvoidflux removal difficulty
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The invention extracts the flux substance from the process entirely and replaces it with an underfill resin system that provides equivalent or superior functionality without creating removable residue, making the process equally suitable for large-scale BGA parts

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The underfill resin acts as an intermediary material that performs the bonding function traditionally achieved by flux, but with the added benefit of built-in corrosion protection and no residue formation, facilitating easier manufacturing of large-scale devices

Inventive Principle:
Principle #24Intermediary (Mediator)

4Reliability

If under-filling resin is applied to fill spaces, then bonding is improved, but voids and unfilled portions reduce product quality

Engineering Contradiction:
Improvebonding qualityVSAvoidfilling completeness
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The invention changes the rheological parameters of the underfill resin by adjusting its viscosity and flow characteristics, enabling complete filling of spaces around BGA parts without trapping voids, thereby achieving both strong bonding and manufacturing precision

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution eliminates the need for flux removal, ensures bubble-free and void-free curing, enhances device reliability, and maintains high thermal stability, even with large-scale BGA parts, improving production efficiency and product quality.

Implementation Method 1

a curing agent which can initiate curing reaction at 150° C. or higher

Methodology Applied
Scientific EffectCuring reaction: Chemical Bonding

Implementation Method 2

a compound having a carboxylic acid group (e.g., rosin)... an activating agent contained in the flux residue

Methodology Applied
Scientific EffectActivating agent action: Oxidation

Implementation Method 3

performing a vacuum treatment and/or heating at a temperature lower than the curing reaction-initiating temperature

Methodology Applied
Scientific EffectVacuum treatment: Vacuum

Implementation Method 4

heating at a temperature lower than the curing reaction-initiating temperature of the applied active resin composition

Methodology Applied
Scientific EffectThermal heating: Heating

Data Source

PatentUS9072205B1Surface mounting method utilizing active resin composition
Publication Date: 2015.06.30 SANEI KAGAKU KK
  • US9072205B1 patent drawing
  • US9072205B1 patent drawing
  • US9072205B1 patent drawing

AI summary

A surface mounting method includes applying an active resin composition to at least part of a surface of a printed wiring substrate; mounting a surface mount device on the substrate; performing reflow soldering; applying an under-filling resin into a space of interest; before and/or after applying the under-filling resin, performing a vacuum treatment and/or heating at a temperature lower than the curing reaction-initiating temperature of any of the applied active resin composition and the under-filling resin; and subsequently, thermally curing the resin composition and the under-filling resin. The active resin composition contains an epoxy resin in an amount of 100 parts by weight, a blocked carboxylic acid compound in an amount of 1-50 parts by weight and/or a carboxylic acid compound in an amount of 1-10 parts by weight, and a curing agent which can initiate curing reaction at 150° C. or higher, in an amount of 1-30 parts by weight.