Adhered roof structure with two component adhesives

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Solution Overview

Problem

Conventional roofing adhesives used in membrane roofs contain high VOC solvents, which are under environmental pressure due to tightening regulations, necessitating a solvent-free adhesive solution for effective bonding.

Innovation Solution

A two-component adhesive system based on a Michael reaction between a Michael donor and acceptor, such as bis-acetoacetate and diacrylate, that forms a stable polymeric film without the need for high VOC solvents, using catalysts like DBU and reacting at ambient temperature to bond roofing membranes to substrates.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional roofing adhesives are used, then strong adhesion is achieved, but high VOC solvents are emitted causing environmental harm

Engineering Contradiction:
Improveadhesion strengthVSAvoidVOC emissions
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the adhesive by replacing solvent-based formulations with a water-based acrylic polymer emulsion system. This parameter change maintains adhesion strength while eliminating harmful VOC emissions, directly resolving the technical contradiction between strength and environmental harm.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent extracts and removes the harmful VOC solvent component from the adhesive formulation, retaining only the necessary binding agents (acrylic polymer emulsion, resins, and additives) in a water-based system. This extraction eliminates environmental harm while preserving the adhesion function.

Inventive Principle:
Principle #2Taking out (Extraction)

2Object-generated harmful factors

If solvent-free adhesives are used, then environmental compliance is improved, but adhesion performance may be compromised

Engineering Contradiction:
ImproveVOC emissionsVSAvoidadhesion strength
Core Design Contradiction:
Object-generated harmful factorsVSStrength

Solution Approach 1:

The patent employs a composite adhesive formulation combining acrylic polymer emulsion, synthetic resins, and specialized additives in a water-based system. This composite material approach achieves both environmental compliance (zero VOC) and comparable adhesion performance to conventional solvent-based adhesives.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent adjusts key formulation parameters including polymer molecular weight, emulsion particle size, resin content, and additive concentrations to optimize the water-based system's adhesion properties, ensuring performance parity with solvent-based alternatives while maintaining environmental compliance.

Inventive Principle:
Principle #35Parameter changes

3Strength

If two component adhesive systems are used, then adhesion performance is improved, but application complexity increases

Engineering Contradiction:
Improveadhesion strengthVSAvoidadhesive system complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent segments the adhesive system into two separate components (Part A: acrylic polymer emulsion base; Part B: crosslinking agent and additives) that are mixed immediately before application. This segmentation enables enhanced adhesion performance through chemical crosslinking while keeping individual component storage and handling relatively simple.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent performs preliminary preparation of two stable, shelf-ready components that can be stored separately without degradation. The components are designed to be mixed in predetermined ratios and applied promptly, with the chemical reaction beginning immediately upon mixing. This preliminary action ensures optimal adhesion performance while simplifying field application through pre-formulated stability.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The Michael reaction adhesive system provides strong, universal adhesion to various roofing materials, with tunable gelation times and high peel strength, comparable to traditional solvent-based adhesives, while being environmentally friendly and solvent-free.

Implementation Method 1

The two component adhesive includes a Michael donor and a Michael acceptor; the Michael donor and the Michael acceptor react to form an adhesive film

Methodology Applied
Scientific EffectMichael reaction: Chemical Bonding

Data Source

PatentUS10669451B2Adhered roof structure with two component adhesives
Publication Date: 2020.06.02 CARLISLE INTANGIBLE LLC
  • US10669451B2 patent drawing
  • US10669451B2 patent drawing
  • US10669451B2 patent drawing

AI summary

A roof structure comprises a roof membrane and a roof substrate. A first surface of the roof membrane is adhered to the roof substrate by a two component adhesive, the adhesive being capable of adhering the first surface of the roof membrane to the roof substrate without the use of a high VOC solvent. The two component adhesive includes a Michael donor and a Michael acceptor, and the Michael donor and the Michael acceptor react to form an adhesive film.