Pressure-Sensitive Adhesive Composition for Optical Elements

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Solution Overview

Problem

Existing pressure-sensitive adhesive compositions for protective films struggle to achieve a balance between high-speed and low-speed peel strengths while maintaining antistatic properties and preventing contamination of adherends, especially when used for optical elements like polarizing plates.

Innovation Solution

A pressure-sensitive adhesive composition incorporating a polymer with an alkylene oxide chain, a nitrogen-containing reactive compound, and hydroxyl group-containing monomers, along with an aliphatic isocyanate cross-linking agent and an ionic compound, which provides balanced peel strengths and excellent electrostatic discharge characteristics without leaving contaminants.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If conventional pressure-sensitive adhesive compositions are used to provide antistatic properties, then static electricity suppression is improved, but low-speed peel strength deteriorates to extremely low levels

Engineering Contradiction:
Improvestatic electricityVSAvoidlow-speed peel strength
Core Design Contradiction:
Object-affected harmful factorsVSStrength

Solution Approach 1:

The patent changes the chemical parameters of the adhesive composition by incorporating specific ionic compounds (quaternary ammonium salts, phosphonium salts, sulfonium salts) with controlled concentrations (0.01-5 parts by weight based on 100 parts by weight of polymer). This parameter adjustment provides antistatic properties while maintaining proper peel strength, resolving the contradiction between static electricity suppression and adhesive strength.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite pressure-sensitive adhesive composition combining polymer base materials with specific ionic compound additives. This composite structure integrates the adhesive properties of the polymer with the antistatic properties of the ionic compounds, achieving both low-speed peel strength and static electricity suppression simultaneously.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If pressure-sensitive adhesive components are added to provide antistatic function, then electrostatic discharge characteristics are improved, but contamination of adherend worsens

Engineering Contradiction:
Improveelectrostatic dischargeVSAvoidcontamination
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The patent applies local quality by using specific ionic compounds with controlled molecular structures and concentrations that provide antistatic function at the surface level without causing bulk contamination. The ionic compounds are selected and dosed to achieve electrostatic discharge protection while minimizing transfer and contamination of the adherend.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent employs ionic compounds that function as temporary antistatic agents during the protective film's service life. These compounds provide electrostatic discharge protection when needed but are designed to minimize long-term contamination, effectively serving as a controlled, limited-duration functional additive.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Speed

If conventional adhesive compositions are used for rapid peeling, then high-speed peel strength is improved, but low-speed peel strength deteriorates

Engineering Contradiction:
Improvepeeling speedVSAvoidlow-speed peel strength
Core Design Contradiction:
SpeedVSStrength

Solution Approach 1:

The patent creates a dynamic adhesive system where the pressure-sensitive adhesive composition can adapt its bonding characteristics based on peeling speed. The composition maintains strong adhesion during slow peeling (providing proper protective function) while allowing controlled release during rapid peeling, achieving a balance between high-speed and low-speed peel strength requirements.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent adjusts the chemical composition parameters including polymer type, molecular weight distribution, and ionic compound concentration to create an adhesive system with speed-dependent bonding characteristics. This parameter optimization enables the adhesive to exhibit appropriate strength at both high and low peeling speeds.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves proper high-speed and low-speed peel strengths, maintains surface resistance, and prevents contamination of adherends, making it suitable for various applications including optical elements like polarizing plates.

Implementation Method 1

the pressure-sensitive adhesive sheet formed using the pressure-sensitive adhesive composition according to one exemplary embodiment of the present invention exhibits a proper level of surface resistance and excellent electrostatic discharge characteristics

Methodology Applied
Scientific EffectElectrostatic discharge: Electrostatic Discharge

Implementation Method 2

A pressure-sensitive adhesive composition according to claims 1 to 8 includes a polymer, an aliphatic isocyanate cross-linking agent and an ionic compound

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Data Source

PatentEP3147337B1Adhesive composition
Publication Date: 2021.12.01 LG CHEM LTD
  • EP3147337B1 patent drawing
  • EP3147337B1 patent drawing
  • EP3147337B1 patent drawing

AI summary

The present invention relates to a pressure-sensitive adhesive composition, a protective film, an optical element, and a display device. A pressure-sensitive adhesive sheet formed using the pressure-sensitive adhesive composition according to the present invention can have proper high-speed and low-speed peel strengths and simultaneously can exhibit an excellent balance between the high-speed and low-speed peel strengths. The pressure-sensitive adhesive sheet formed using the pressure-sensitive adhesive composition according to one exemplary embodiment of the present invention exhibits a proper level of surface resistance and excellent electrostatic discharge characteristics, and has no contaminants with respect to an adherend even when the pressure-sensitive adhesive sheet is peeled from the adherend after the pressure-sensitive adhesive sheet is attached to the adherend for a long period of time. Such a pressure-sensitive adhesive sheet formed using the pressure-sensitive adhesive composition according to one exemplary embodiment of the present invention can be applied to various fields of applications. For example, the pressure-sensitive adhesive sheet can be used as a protective film for optical members such as polarizing plates.