Pressure-Sensitive Adhesive Composition for Low Stratum Corneum Exfoliation

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Solution Overview

Problem

Existing pressure-sensitive adhesive sheets cause significant exfoliation of the stratum corneum when peeled off from the skin, leading to skin damage.

Innovation Solution

A pressure-sensitive adhesive composition comprising a (meth)acrylic polymer with specific alkyl ester constituents, a nonionic emulsifier, and an organic liquid component, which reduces stratum corneum exfoliation upon peeling.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If a conventional pressure-sensitive adhesive composition is used, then the adhesive sheet can be attached to skin, but significant stratum corneum exfoliation occurs when peeled off

Engineering Contradiction:
Improveadhesiveness to skinVSAvoidstratum corneum exfoliation
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The patent applies parameter changes by carefully controlling the glass transition temperature (Tg) of the polymer within -50°C to 0°C and adjusting the molecular weight to 10,000 to 1,000,000. These parameter optimizations modify the adhesive's physical properties to reduce stratum corneum exfoliation while maintaining skin adhesiveness. The specific Tg range ensures the adhesive remains flexible and compliant with skin movement without being too weak to adhere properly.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining a polymer with specific constituent units (U1, U2, U3) in defined proportions. The polymer contains units derived from acrylic acid alkyl esters with specific carbon chain lengths, carboxyl group-containing monomers, and other functional monomers. This composite structure creates an adhesive that balances strong adhesion with reduced skin damage upon removal.

Inventive Principle:
Principle #40Composite materials

2Strength

If the adhesive strength is increased to ensure proper fixation, then the sheet adheres better to skin, but more stratum corneum is exfoliated during peeling

Engineering Contradiction:
Improveadhesive strengthVSAvoidstratum corneum exfoliation
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent resolves this contradiction by changing the physical parameters of the adhesive, specifically controlling the glass transition temperature to -50°C to 0°C and molecular weight to 10,000 to 1,000,000. These parameter adjustments create an adhesive that achieves sufficient bond strength through optimized molecular flexibility and intermolecular forces, rather than through excessive bonding that would cause skin damage during removal.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies dynamics by ensuring the adhesive maintains appropriate viscoelastic properties through controlled polymer composition and molecular weight. The adhesive can dynamically adapt to skin movement and deformation, allowing it to maintain strong attachment during wear while enabling cleaner removal with reduced stratum corneum exfoliation when the adhesive is peeled off.

Inventive Principle:
Principle #15Dynamics

Data Source

PatentEP4624544A1Pressure-sensitive adhesive composition and pressure-sensitive adhesive sheet
Publication Date: 2025.10.01 NITTO DENKO CORP
  • EP4624544A1 patent drawingFigure 1~2
  • EP4624544A1 patent drawing
  • EP4624544A1 patent drawing

AI summary

Provided is a pressure-sensitive adhesive composition for producing a pressure-sensitive adhesive sheet suitable for reducing the amount of the stratum corneum exfoliated when the sheet is peeled off from skin. The pressure-sensitive adhesive composition includes: a (meth)acrylic polymer containing a constituent unit U1 derived from a first (meth)acrylic acid alkyl ester having an alkyl group having 1 to 7 carbon atoms, a constituent unit U2 derived from a second (meth)acrylic acid alkyl ester having an alkyl group having 8 to 12 carbon atoms, and a constituent unit U3 derived from a carboxyl group-containing monomer; a nonionic emulsifier; and an organic liquid component containing a carboxylic acid ester.