Adhesive Polymer Composition for Pipe Coating Peel Strength

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Solution Overview

Problem

Existing adhesive compositions for multi-layered structures, such as three-layer metal pipe coatings, fail to meet peel strength requirements under conditions of shorter water cooling times due to sensitivity to faster line speeds and thicker steel pipes, leading to potential delamination and damage.

Innovation Solution

A polymer composition comprising a non-elastomeric polyethylene, an elastomer, and an acid grafting agent, produced through a controlled extrusion process with specific temperature profiles in the extruder's control zones, resulting in a polymer composition with distinct peaks and valleys in the GPC curve and a Z-value of at least -1.0, enhancing adhesion properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional adhesive compositions are used, then good adhesion properties are achieved under normal conditions, but peel strength is insufficient under shorter water cooling times and faster line speeds

Engineering Contradiction:
Improvepeel strengthVSAvoidsensitivity to cooling time conditions
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent changes the molecular weight distribution parameters of the polyethylene component, specifically creating a bimodal distribution with distinct peaks at different molecular weights. This parameter change in the polymer structure enables the adhesive to maintain peel strength under varying cooling conditions without being sensitive to process changes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The adhesive composition uses a composite approach by blending polyethylene with different molecular weight characteristics and incorporating elastomeric components. This composite material strategy creates synergistic effects that improve both adhesion and flexibility, allowing the coating to withstand shorter cooling times while maintaining bond strength

Inventive Principle:
Principle #40Composite materials

2Productivity

If the water cooling time is shortened to increase productivity, then faster line speeds are achieved, but the peel strength of the coating decreases

Engineering Contradiction:
Improveline speedVSAvoidpeel strength
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent modifies the molecular weight distribution parameters of the adhesive polymer to create a bimodal distribution. This parameter change allows the material to process faster while maintaining adequate cooling time for bond formation, thus supporting higher line speeds without sacrificing peel strength

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The adhesive composition is pre-formulated with specific molecular weight characteristics and elastomeric additives before application. This preliminary preparation ensures that the adhesive has optimal bonding properties that can develop quickly during the shortened cooling process, enabling faster production rates

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The polymer composition achieves improved peel strength and adhesion, meeting or exceeding ISO 21809-1 standards even under challenging conditions of shorter water cooling times.

Implementation Method 1

independently controlling the temperature of each control zone of the plurality of control zones of the barrel section of the extruder

Methodology Applied
Scientific EffectTemperature control: Heating

Implementation Method 2

grafting component (A) or components (A) and (B) with component (C) during the compounding step

Methodology Applied
Scientific EffectGrafting: Chemical Bonding

Data Source

PatentEP3917750B1Polymer composition
Publication Date: 2025.12.17 BOREALIS AG
  • EP3917750B1 patent drawingFigure 1~2
  • EP3917750B1 patent drawing
  • EP3917750B1 patent drawing

AI summary

Process for producing a polymer composition, a polymer composition obtainable by said process and the use of said polymer composition as adhesive polymer composition and for the production of a multilayer structure, such as a three-layer metal pipe coating, with improved peel strength.