Pressure-Sensitive Adhesive Release Layer Silica Gel Starch

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Solution Overview

Problem

Existing writable pressure-sensitive adhesive products face challenges with universal writability, particularly when exposed to heat and humidity, and are not environmentally friendly, with conventional separating layers affecting inscribability and aging resistance.

Innovation Solution

A pressure-sensitive adhesive product with a release layer comprising silica gel particles and starch, along with a binder and optional additives, where the silica gel particles have an average size of 3-10 µm, providing improved writability and release behavior, including resistance to manual abrasion and moisture, using polyurethane- and/or urea-modified silicones for optimized aging resistance and universal writability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If conventional separating layers are used, then release behavior is achieved, but inscribability and aging resistance deteriorate

Engineering Contradiction:
Improverelease behaviorVSAvoidaging resistance
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The release layer is formulated as a composite material containing silica gel particles (3-10 μm), starch, and a binder, creating a multi-component system that simultaneously provides release behavior and aging resistance. This composite structure allows the layer to function as both a separating agent and an protective coating.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention optimizes the particle size parameter of silica gel to 3-10 μm, which is critical for achieving both good release behavior and improved inscribability. This specific size range allows the particles to provide sufficient separation while maintaining surface properties suitable for writing and printing.

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If conventional separating layers are used, then release behavior is achieved, but universal writability deteriorates

Engineering Contradiction:
Improverelease behaviorVSAvoiduniversal writability
Core Design Contradiction:
Ease of operationVSAdaptability or versatility

Solution Approach 1:

The silica gel particle size is optimized to 3-10 μm to balance release behavior and writability. This size range creates a surface that is sufficiently rough for good release but smooth enough to accept pencil, ink, and inkjet impressions.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The release layer is designed with specific local properties: silica gel particles provide the necessary surface characteristics for both release and writability, while starch and binder components ensure uniform distribution and adhesion to the backing material.

Inventive Principle:
Principle #3Local quality

3Adaptability or versatility

If products are designed for good writability, then inscribability is improved, but resistance to manual abrasion and moisture deteriorates

Engineering Contradiction:
ImprovewritabilityVSAvoidresistance to manual abrasion
Core Design Contradiction:
Adaptability or versatilityVSStrength

Solution Approach 1:

The release layer combines silica gel particles with starch and binder to create a composite structure that is both writable and resistant to abrasion and moisture. The starch component adds structural integrity while the binder ensures strong adhesion to the backing.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The specific particle size range of 3-10 μm for silica gel is critical for achieving the right balance between surface smoothness for writing and surface robustness for resistance to abrasion and moisture.

Inventive Principle:
Principle #35Parameter changes

4Temperature

If products are exposed to heat and humidity, then aging occurs, but performance deterioration is avoided through optimized composition

Engineering Contradiction:
Improveheat resistanceVSAvoidaging resistance
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The combination of silica gel, starch, and binder creates a composite release layer with enhanced thermal and moisture stability. This composite structure resists degradation under elevated temperature and humidity conditions better than conventional separating layers.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The optimized particle size and composition ratios in the release layer contribute to improved aging resistance, allowing the product to maintain its properties after exposure to heat and humidity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The product achieves excellent universal writability, improved aging resistance, and low-noise unwind behavior, even at high peel speeds, with enhanced separation properties and resistance to various writing systems, including pencils and inkjet printing, while maintaining high resistance to manual abrasion and moisture exposure.

Implementation Method 1

a release layer arranged on the back of the backing, which comprises silica gel particles and starch as well as a binder

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

a pressure-sensitive adhesive layer arranged on the front side of the backing

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentEP2556127B1Pressure-sensitive adhesive product that can be written upon
Publication Date: 2018.03.14 TESA SE

AI summary

The invention relates to an adhesive product, comprising a substrate having an adhesive layer disposed on the front side of the substrate and a release layer disposed on the back side of the substrate and comprising silica gel particles and starch and a binding agent and optionally further additives, characterized in that the silica gel particles comprise an average particle size of 3 to 10 µm.