Double-Layered Adhesive Resin for Semiconductor Substrate Separation

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Solution Overview

Problem

Current semiconductor packaging technologies face challenges in achieving high thermal process resistance, easy separation of support, and increased productivity due to limitations in adhesive systems and materials used for three-dimensional semiconductor packages, particularly in FOWLP and TSV-forming processes.

Innovation Solution

A semiconductor device with a double-layered adhesive resin system, comprising a light-decomposable resin layer and a non-silicone-based thermoplastic resin layer with a glass transition temperature of 200°C or higher, which allows for tight bonding and easy separation, enabling improved thermal resistance and productivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a single-layer adhesive resin system is used, then the structure is simple, but thermal process resistance is insufficient and separation control is difficult

Engineering Contradiction:
Improvethermal process resistanceVSAvoidadhesive system structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The adhesive resin system is divided into two functional layers: a first adhesive resin layer containing a thermoplastic resin with Tg of 80°C or higher for thermal process resistance, and a second adhesive resin layer containing a laser-decomposable resin for easy separation. This segmentation allows each layer to perform its specific function independently, resolving the contradiction between thermal resistance and separation ease.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent uses a composite adhesive system combining two different resin materials with complementary properties. The thermoplastic resin provides heat resistance and bonding strength, while the laser-decomposable resin enables controlled separation. This composite approach achieves both thermal process resistance and easy separation without requiring a single complex material.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If a thermoplastic resin with low glass transition temperature is used, then ease of bonding is improved, but thermal process resistance deteriorates

Engineering Contradiction:
Improvebonding process easeVSAvoidthermal process resistance
Core Design Contradiction:
Ease of operationVSTemperature

Solution Approach 1:

The adhesive system is segmented into two layers with different thermal characteristics. The first layer uses a thermoplastic resin with Tg ≥ 80°C to withstand thermal processes, while the second layer uses a laser-decomposable resin that remains soft at low temperatures for easy bonding operations. This segmentation resolves the contradiction between bonding ease and thermal resistance.

Inventive Principle:
Principle #1Segmentation

3Ease of manufacture

If a laser-decomposable resin release layer is used, then easy separation is achieved, but the release layer deforms under high-temperature curing conditions

Engineering Contradiction:
Improvesupport separation easeVSAvoidcuring process stability
Core Design Contradiction:
Ease of manufactureVSTemperature

Solution Approach 1:

The adhesive system is divided into two layers: the first layer (thermoplastic resin with high Tg) provides thermal stability during curing, while the second layer (laser-decomposable resin) provides easy separation functionality. The first layer acts as a thermal barrier protecting the second layer from deformation during high-temperature curing, resolving the contradiction between separation ease and curing stability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The first adhesive resin layer with high thermal resistance is placed beneath the laser-decomposable resin layer to provide thermal protection in advance. This cushioning layer prevents the laser-decomposable resin from deforming during subsequent high-temperature curing processes, while still allowing easy separation when needed.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The semiconductor device achieves enhanced thermal resistance and easy separation of the semiconductor substrate from the support, ensuring tight bonding of layers and improved productivity in semiconductor package production.

Implementation Method 1

a resin layer A containing a resin decomposable by light irradiation

Methodology Applied
Scientific EffectPhoto-decomposition: Photodissociation

Implementation Method 2

a resin layer B containing a non-silicone-based thermoplastic resin, the resin layer B having a glass transition temperature of 200° C. or higher

Methodology Applied
Scientific EffectGlass transition: Phase Change

Data Source

PatentUS10727103B2Semiconductor device, method for producing the same, and laminate
Publication Date: 2020.07.28 SHIN ETSU CHEMICAL CO LTD
  • US10727103B2 patent drawing
  • US10727103B2 patent drawing
  • US10727103B2 patent drawing

AI summary

Disclosed herein is a semiconductor device including: a support; a double-layered adhesive resin layer formed on the support, an insulating layer and a redistribution layer formed on the adhesive resin layer; a chip layer, and a mold resin layer, wherein the adhesive resin layer includes a resin layer A containing a resin decomposable by light irradiation and a resin layer B containing a non-silicone-based thermoplastic resin, the resin layer A and the resin layer B being provided in this order from the support side, the resin decomposable by light irradiation is a resin containing a fused ring in its main chain, and the non-silicone-based thermoplastic resin has a glass transition temperature of 200° C. or higher.