Adhesive Sheet With Ruptured Hollow Microspheres

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Solution Overview

Problem

Conventional thermally conductive adhesives face challenges in achieving high thermal conductivity while maintaining softness and flexibility, with issues such as increased hardness, non-uniform foam cell size and distribution, and poor cohesion due to low molecular weight compounds, which affect bonding area and durability.

Innovation Solution

An adhesive sheet is prepared by dispersing hollow polymeric microspheres in an acrylic polymer, curing the mixture, and then rupturing the microspheres to form hollow parts, which improves flexibility, bonding area, and thermal conductivity, while allowing for controlled size and distribution of foam cells.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If hollow polymeric microspheres are dispersed in a crosslinked adhesive sheet, then restorative power upon compression is improved, but hardness of the adhesive sheet increases

Engineering Contradiction:
Improverestorative powerVSAvoidhardness
Core Design Contradiction:
StrengthVSStress or pressure

Solution Approach 1:

The patent changes the physical state of the hollow microspheres from intact to ruptured. By rupturing the hollow microspheres after curing, the adhesive sheet transforms from having discrete spherical cavities to having expanded foam-like structures, which fundamentally alters the mechanical response from elastic recovery to energy absorption through deformation

Inventive Principle:
Principle #35Parameter changes

2Stress or pressure

If foam structure is introduced to soften adhesive sheet, then hardness is reduced, but noise and vibration reduction capability is improved

Engineering Contradiction:
ImprovehardnessVSAvoidnoise and vibration
Core Design Contradiction:
Stress or pressureVSObject-affected harmful factors

Solution Approach 1:

The patent introduces a porous foam structure by rupturing hollow microspheres within the adhesive matrix. This porous structure reduces hardness by creating void spaces that decrease material density and stiffness, while simultaneously providing noise and vibration reduction through sound absorption and damping mechanisms inherent to foam structures

Inventive Principle:
Principle #31Porous materials

3Productivity

If thermal treatment is used to cure and foam adhesive simultaneously, then size and distribution of foam cells become non-uniform, but production efficiency is improved

Engineering Contradiction:
Improveproduction efficiencyVSAvoiduniformity of foam cell size and distribution
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent separates the curing process from the foaming process. Curing is completed first to establish the adhesive matrix, then hollow microspheres are ruptured in a subsequent step to create uniform foam cells. This sequential approach allows each process to be optimized independently, ensuring uniform foam cell distribution while maintaining production efficiency

Inventive Principle:
Principle #10Preliminary action

4Productivity

If bonding area is increased to improve heat transfer, then efficiency of heat transfer is improved, but irregular loci between electronic parts and adhesive create air layers that reduce bonding area

Engineering Contradiction:
Improveheat transfer efficiencyVSAvoidbonding area
Core Design Contradiction:
ProductivityVSArea of stationary object

Solution Approach 1:

The patent creates a dynamic foam structure that can deform and flow to fill irregular spaces between electronic parts and substrates. The ruptured hollow microspheres create a compliant adhesive that adapts to surface irregularities, eliminating air pockets and maximizing actual bonding area while maintaining high heat transfer efficiency

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting adhesive sheet exhibits enhanced flexibility, increased bonding area, improved adhesive force, and durability at high temperatures, with improved thermal conductivity and noise reduction, making it suitable for electronic components.

Implementation Method 1

hollow parts formed by rupturing hollow microspheres in cured resins

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 2

thermally conductive adhesives function to transfer the heat generated from electronic parts to a heat sink for discharging heat

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Data Source

PatentUS8067475B2Adhesive sheet comprising hollow parts and method for preparing the same
Publication Date: 2011.11.29 LG CHEM LTD

AI summary

Disclosed herein are an adhesive sheet comprising a cured acrylic polymer, hollow polymeric microspheres dispersed and ruptured in the cured acrylic polymer, and hollow parts formed by rupturing the hollow polymeric microspheres dispersed in the cured acrylic polymer, and a preparation method thereof.